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Tytuł artykułu
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Warianty tytułu
Języki publikacji
Abstrakty
Free-radical addition of thiols (l-dodecanthiol, 2-hydroxy-l-ethanethiol) to vinyl groups of a multiacrylate - poly(2-acryIoyloxyethyl methacrylate) were investigated. The addition process was carried out in dioxane with the excess of thiols within the temperature range 60-80°C. Pseudo-first-order rate constants for free-radical addition and the activation energy were determined. The resultant comb-like products were characterized by FTIR, H-NMR, C-NMR and DSC.
Czasopismo
Rocznik
Tom
Strony
31--36
Opis fizyczny
Bibliogr. 10 poz.
Twórcy
autor
autor
- Department of Physical Chemistry of Polymers, Technical University of Łódź, Żeromskiego 116, 90-924 Łódź, Poland;, rojan@p.lodz.pl
Bibliografia
- [1] Marvel, C.S., Kotch, A., J. Am. Chem. Soc., 1951, 70, 993.
- [2] Walling, Ch., J .Am. Chem. Soc., 1959, 81, 1144.
- [3] Pryor, W.A., Coco, J.H., Daby W.H., Houk K.N., J. Am. Chem. Soc., 1974, 96, 5591.
- [4] Nuyken, O., Reuschel, G., Siebzenhnriibl, F., Makromol. Chem., Makromol. Symp., 1989, 26, 313.
- [5] Nuyken, O., Siebzenhnriibl, F., Makromol. Chem., 1988, 189, 541.
- [6] Romani, F., Passaglia, E., Aglietto, M., Ruggeri, G., Macromol. Chem. Phys., 1999, 200, 524.
- [7] Herczyńska, L., Lestel, L., Boileau, S., Chojnowski, J., Polowiński, S., Eur. Polym. J., 1990, 35, 1115.
- [8] Saikia, P.J., Baruah, S.D., J. Appl. Polym. Sci., 2007, 104, 1226.
- [9] Jantas, R., J. Polym. Sci., Part A: Polym. Chem., 1990, 28, 1973.
- [10] Jantas, R, Szumilewicz, J., Strobin, G., Połowiński, S., J. Polym. Sci., Part A: Polym. Chem., 1994, 32,295.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPC2-0006-0005