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Inhibitowanie korozji w farbach antykorozyjnych i rola pigmentu inhibitującego

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Warianty tytułu
EN
Corrosion inhibition in anti-corrosive coatings and the role of the inhibitive pigment
Języki publikacji
PL
Abstrakty
PL
Spektroskopia impedancyjna jest techniką szeroko stosowaną w badaniach inhibitorów i powłok. W artykule po krótkim omówieniu roli pigmentów antykorozyjnych (inhibitujących) w powłokach oraz wpływu samej powłoki na inhibitowanie korozji wyprowadzono model elektrochemiczny w celu obliczenia przewidywanej elektrochemicznej impedancji powłoki zawierającej inhibitor. Przedyskutowano wpływ inhibicji anodowej i katodowej na obserwowane widma impedancyjne, prawdopodobieństwo rejestrowania takiego inhibitowania przez system powłokowy za pomocą spektroskopii impedancyjnej oraz, w konsekwencji, warunków, w których takie inhibitowanie może pomóc w zmniejszaniu postępu korozji. W oparciu o te zasady przedstawiono nową technologię inhibitora nie zawierającego cynku i jego charakterystykę.
EN
Impedance spectroscopy has been a widely used technique in the study of inhibitors and coatings (8-13). Following a brief survey on the role of inhibitive pigments in coatings and the influence of the coating itself on inhibition, the present paper will briefl y introduce an electrochemical model for purposes of calculating the expected electrochemical impedance of a coating containing an inhibitor. The influence of anodic and cathodic inhibition on observed impedance spectra, the likelihood of observing such inhibition from within a coating environment by means of impedance spectroscopy and as a consequence, the conditions under which such inhibition can aid in reducing the extent of corrosion will then be discussed. On this basis, approaches to newer zinc-free inhibitor technology will be introduced and some of its characteristics described.
Rocznik
Tom
Strony
213--222
Opis fizyczny
Bibliogr. 38 poz., il.
Twórcy
autor
  • Grace Gmbh & Co. KG, Niemcy
Bibliografia
  • 1. Salensky G.: in Handbook of Coating Additives,ed. Calbo, L. J; Marcel Dekker, Inc. 1987; Chapter 12, Corrosion Inhibitors.
  • 2. Turgoose S.: in Additives for Water-Based Coatings; Royal Society of Chemistry Spec. Pub. No 76; ed. Karsa, D.A.: 1990. Approaches to the study of corrosion inhibition under water-based coatings.
  • 3. Svoboda M.: Mleziva, J; Prog. Org. Coat. 12, 251-297, 1984; Properties of coatings determined by anti-corrosive pigments.
  • 4. de Wit J.H.W: Corros. Technol (NY), 8, 581-628, 1995; Inorganic and Organic Coatings.
  • 5. Mayne J.E.O: in Corrosion 2nd Edition, Ed. L. Shreir, Newnes-Butterworth, London, Vol 2, 15, 24, 1976; The mechanism of action of anti-corrosive coatings.
  • 6. Braig A.: FATIPEC Congr. Vol III (19th), 401-24; 1988. Organic corrosion inhibitors for paints.
  • 7. Fletcher, T.E; European Coatings Journal. 9, 553-560, 1991; Ion-exchange pigments for anti-corrosive coatings.
  • 8. The use of AC Impedance Spectroscopy for the study of coated metals by J. G. N. Thomas, PRA 1990.
  • 9. Bonaro P.L., Defl orian F., Fedrizzi L.: Electrochim Acta 41(7/8), 1073-1082, 1996; Electrochemical impedance spectroscopy as a tool for investigating underpaint corrosion.
  • 10. Hack, H.P; Scully, J.R; J. Electrochem. Soc. 138(1), 33-40, 1991; Defect area determination of organic coated steels in seawater using the breakpoint frequency method.
  • 11. Kendig M.W, Jeanjaquet S., Lumsden J.: in Electrochemical Impedance: Analysis and Interpretation, ASTM STP 1188, Eds. J. R. Scully, D.C. Silverman and M. W. Kendig; ASTM Philadelphia, 407-427, 1993; Electrochemical impedance of coated metal undergoing loss of adhesion.
  • 12. van Westing E.P.M., Ferrari G.M., de Wit J.H.W.: Corros. Sci. 36(8), 1323-1346, 1994; The determination of coating performance with impedance measurements IV. Protective mechanism of anti-corrosive pigments.
  • 13. Amirudin A., Thierry D.: Br. Corros. J. 30(2), 128-134, 1995; Application of electrochemical impedance spectroscopy to study the efficiency of anti-corrosive pigments in epoxy polyamide resins.
  • 14. Amirudin A., Barreau C., Hellouin R., Thierry D.: Prog. Org. Coat. 25(4), 339-355, 1995; Evaluation of anti-corrosion pigments by pigment extract studies, atmospheric exposure and electrochemical impedance spectroscopy.
  • 15. Mayne J.E.O., Mills D.J: Corrosion Control by Organic Coatings ed. Leidheiser, H, Jr, 12-17, (Publ. NACE), 1981; The inhomogeneous nature of polymer fi lms and its effect on resistance inhibition.
  • 16. Mayne J.E.O., Mills D.J.: J. Oil & Colour Chem. Assoc. 58, 155-159, 1975; The effect of the substrate on the electrical resistance of polymer films.
  • 17. Nyuyen T., Hubbard J.B, Pommersheim J.M.: J. Coat. Technol. 68(855), 45-56, 1996; Unifi ed model for the degradation of organic coatings on steel in a neutral electrolyte.
  • 18. Kendig M., Jeanjaquet S., Cunningham M., Gordon S., Davenport A., Aldykiewicz A.J.Jr.: Proc. Electrochem. Soc. 1993 93-28(Proc. of the symp. on Corros. Protection by Coatings and Surface Modification, 1993) 171-186; Rapid electrochemical screening of non-chromate pigments for paint.
  • 19. Turgoose S.: in Chemical Inhibitors for Corrosion Control; ed. Clubley, B. G; RSC Spec. Pub. No. 71, 72-88; 1990. Mechanisms of corrosion inhibition in neutral environments.
  • 20. Leidheiser H.: Jr. Corrosion (NACE) 39 (5), 189-201, 1983; Towards a better understanding of corrosion beneath organic coatings.
  • 21. Funke W.: J. Oil & Colour Chem. Assoc. 68 (9), 229-32, 1985; The role of adhesion in corrosion protection by organic coatings.
  • 22. Mayne J.E.O., Mills D.J.: Surf. Coat. Int. 77 (4), 154-5, 1994; The diffusion of oxygen through paint and varnish films.
  • 23. Anderton W.A.: J. Oil & Colour Chemists Assoc. 53, 181-191, 1970; Phenomena associated with metal-paint coating interfaces.
  • 24. Knudsen O.O., Steinsmo U.: JCSE 2, Paper 37, 1999. Effect of barrier pigments on cathodic disbonding Part 2. Mechanism of the effect of aluminium pigments.
  • 25. Kresse P.: Anti-Corros. Methods Mater. 26(1), 5-8 1979 and 26(2), 16-20, 1979; Influence of inert pigments on the anti-corrosive propertiesof paint films: Parts 1 and 2.
  • 26. Svoboda M., Kubatova H., Knapek B.; Prazek M.: Farbe Lack 86, 780-783, 1980; On the protective properties of pigments and coatings.
  • 27. Funke W., Reichle P.: Farbe Lack 93(7), 537-538, 1987; The influence of corrosion promoting ions on the protective action of anti-corrosion pigments.
  • 28. Sinko J.: XXVth International Conference in Organic Coatings (Water-Borne, High Solids, Powder Coatings) Vouliagmeni, July 5-9, 257-276, 1999. Challenges of chromate corrosion inhibitor pigments; replacement in organic coatings.
  • 29. Mayne J.E.O.: Golden J.: Brit. Corr. J. 13, 45-49, 1978; Inhibition of the corrosion of mild steel by zinc potassium chromate.
  • 30. Qian Y.J., Turgoose S.: Brit. Corr. J. 22, 268-271, 1987; Inhibition by zinc-molybdate mixtures of corrosion of mild steel.
  • 31. Mercer A. D.: in Corrosion 2nd Edition, Ed. L, L. Shreir, Newnes-Butterworth, London, Vol 2(18.2), 9-33, 1976. Corrosion Inhibition: Principles and Practice.
  • 32. Turgoose S.: Proc. Electrochem. Soc. 1989, 89-13 (Proc. Symp. Adv. Corros. Prot. Org. Coat.); Scantlebury, J. D; Kendig, M (ed). P 468-475.
  • 33. Fletcher T.E.: XXV FATIPEC Congr. Vol III, 2000. A simple electrochemical model to describe the expected behaviour of inhibitive pigments in modern anti-corrosive coatings.
  • 34. Boukamp B.A.: Equivalent Circuit: AC Immittance Data Analysis System; Twente University of Technology, 1989.
  • 35. Haberer C., Wolff C.M., Collin J.P., Leibenguth J.L., Schwing J.P.: Electrochim. Acta 6, 755-762, 1981; Electrochemical studies on the diffusion of oxygen through macromolecular paints in aqueous solutions.
  • 36. Kalendova A., Kalenda P.: Farbe Lack 110(3), 22-24, 26, 28, 2004; Study of anticorrosive pigments based on modified phosphate.
  • 37. Felhosi I., Keresztes ZS., Karman F.H., Mohai M., Bertoti I., Kalman E.: J. Electrochem. Soc. 146, 961-969, 1999. Effects of bivalent cations on corrosion inhibition of steel by 1- hydroxyethane-1,1-diphosphonic acid.
  • 38. Welsh I.D.: Sherwood, P.M.A; Chem. Mater. 4(1), 133-40, 1992; Valence band photoemission studies of corrosion inhibitor action on iron surfaces: effect of etidronate
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPB3-0032-0017
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