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Purpose: The purpose of this paper is to discuss some problems concerning the extremely high values of the nitride layer hardness and the features of so called S-phase which are formed after low-temperature ion nitriding of high-alloyed austenitic (austenitic-ferritic) steels. Design/methodology/approach: The investigations are performed mainly by using of ray diffraction method after ion nitrided 316 (AISI) steel. Findings: As a result of the work some data, concerning the structure and substructure, the phase composition of the S-phase, crystal lattice, the broadening of diffraction reflexes, mechanism of transformation of gamma'- phase into S-phase, its high hardness etc. of the nitrided layer are obtained. It could be concluded that S-phase could be classified as a modified gamma'-phase. The extremely high values of the hardness could be explained by the high nitrogen concentration in the solid solution and by the presence of increased density of the defects in the austenitic volume, which is transformed in the new S-phase. Research limitations/implications: The potencionstatic investigations of the electrochemical properties of the nitriding probes, performed by us, confirmed the data, obtained by the literature, but this problem will be discussed in some of the next publications. Originality/value: The high micro- and macro-deformations of the lattice of S-phase could be explained by the considerable registered expansions and the angle replacements of the slope (psi) on the ray diffraction maxima. The registered macro deformations could reach immense values, in the range of (1.4 - 2.1)x10-2, which corresponds to macro deformations around 1900 - 2300 MPa (if we accept, for the austenite, the usual module of elasticity of 2.1x105 MPa). For such final decision it is necessary to obtain also some other confirmation facts.
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Rocznik
Tom
Strony
71--74
Opis fizyczny
Bibliogr. 16 poz., rys.
Twórcy
autor
autor
autor
autor
- Department of Material Science and Technology of Materials, Technical University of Sofia, 8 Kl. Ohridski, 1000-Sofia, Bulgaria, vtoshkov@tu-sofia.bg
Bibliografia
- [1] T. Spalvins, Advances and Directions of Ion Nitriding/Carburizing, Proceedings of the 2nd International Ion Nitriding/Carburizing Conference, Cincinnati, 1989, 1-4.
- [2] T. Christiansen, M.A.J. Somers, Characterisation of low temperature surface hardened stainless steel, Struers Journal of Materialography 9 (2006) 2-17.
- [3] J. Baranowska, Characteristic of the nitride layers on the stainless steel at low temperature, Surface and Coatings Technology 180-181 (2004) 145-149.
- [4] B. Podgornik, J. Vižintin, H. Ronkainen, K. Holmberg, Friction and wear properties of DLC-coated plasma nitrided steel in unidirectional and reciprocating sliding, Thin Solid Films 377-378 (2000) 254-260.
- [5] B. Podgornik, J. Vižintin, O. Wänstrand, M. Larsson, S. Hogmark, H. Ronkainen, K. Holmberg, Tribological properties of plasma nitrided and hard coated AISI 4140 Steel, Wear 249 (2001) 254-259.
- [6] G.R.C. Silva, L.C. Casteletti, G.F. Tremiliosi, C.A.S. Bento, Characterization of hardened layers in martensitic and duplex stainless steels modified using plasma nitriding, Acta Microscopica 12C (2003) 169-170.
- [7] X.Y. Li, Low Temperature plasma nitriding of 316 stainless steel - nature of S-phase and its thermal stability, Surface Engineering 17/2 (2001) 147-152.
- [8] J. Bielawski, J. Baranowska, K. Szczecinski, Protective Nitrided Layers on Ferrite-Austenite Chromium Steel, Materials Science 11/3 (2005) 221-225.
- [9] P.A. Dearnley, A. Namvar, G.G.A. Hibberd, T.Bell, Some observations on plasma nitriding austenitic stainless steel, Proceedings of the 1st International Conference on Plasma Surface Engineering, Garmisch - Partenkirchen, 1988, 219-226
- [10] K. Marchev, C.V. Cooper, J.T. Blucher, B.C. Giessen, Conditions for the formation of a martensitic single-phase compound layer in ion-nitrided 316L austenitic stainless steel, Surface and Coatings Technology 99 (1998) 225-228.
- [11] K. Marchev, R. Hidalgo, M. Landis, R. Vallerio. CV. Cooper, B.C. Giessen, The metastabile m-phase layer on ion-nitrided austenitic stainless steels, Part 2: Cristal Structure and Observation of Its Two-Directional Orientational Anisotropy, Surface and Coatings Technology 112 (1999) 67-70.
- [12] K. Marchev, M. Landis, R. Vallerio, CV. Cooper. B.C. Giessen, The m-phase layer on ion-nitrided austenitic stainless steel (III): An epitaxial relationship between the m-phase and the γ parent phase and a review of structural identifications of this phase, Surface and Coatings Technology 116-119 (1999) 184-188.
- [13] Y. Sun, X. Li, T. Bel, Structural characteristics of low temperature plasma carburised austenitic stainless steel, Materials Science and Technology 15 (1999) 1171-1178.
- [14] V. Toshkov, T. Madjarov, M. Jordanov, D. Dimitrov, On the nitriding in low temperature plasma of austenitic steels, Proceedings of 7th International Conference on "Advanced Manufacturing Processes" AMO'2006", Sozopol, Bulgaria. 2006, 158-163.
- [15] K. Ichii, K. Fujimura, T. Takase, Structure of the ion-nitrided layer of 18-8 stainless steel, Technology Reports of the Kansai University 27 (1986) 135-144.
- [16] Y. Sun, L.Y. Chin, Residual stress evolution and relaxation in carbon S-phase layers on AISI 316 austenitic stainless steel, Surface Engineering 18/6 (2002) 443-446.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS5-0021-0046