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Investigations of the structure of composites of PP/GF by means of X-ray methods

Wybrane pełne teksty z tego czasopisma
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: This work aimed to identify the crystalline phases which appear in polymeric matrix as well as to determine the degree of crystallinity for composites based on the matrix of polypropylene reinforced with glass fibre. Moreover, the value of Lp (large period) of supermolecular structure in lamellar polypropylene has also been determined. Design/methodology/approach: X-ray structural investigations of composites based on polypropylene matrix reinforced by glass fibre have been performed by means of X-ray diffraction (XRD) and small angle X-ray scattering (SAXS). Findings: For investigated composites the presence of several types of polymorphous polypropylene has been found. The crystalline part of the matrix for the investigated composites is composed of alpha phase which crystallizes in monoclinic lattice and beta phase which crystallizes in hexagonal system. Moreover, it has been found that amorphous phase in the investigated composites is made of strongly oriented smectic phase of polypropylene. Research limitations/implications: Continuation of the investigations by means of X-ray methods will enable an in-depth analysis and recognition of the structure of polymeric composites on the molecular and supermolecular level. Originality/value: The work identified crystalline phases of polypropylene which made up the matrix for the investigated composites and the value of large period for supermolecular lamellar structure of polypropylene.
Rocznik
Strony
55--58
Opis fizyczny
Bibliogr. 15 poz., rys., tab.
Twórcy
autor
  • Institute of Materials Engineering, Częstochowa University of Technology, Al. Armii Krajowej 19, 42-200 Częstochowa, Poland, reni@mim.pcz.czest
Bibliografia
  • [1] W. Dziadur, A.Tabor, The effect of wood filler behaviour on structure and fracture of polyethylene, Journal of Achievements in Materials and Manufacturing Engineering 17 (2006) 53-56.
  • [2] A. Gnatowski, O. Suberlak, P. Postawa, Functional materials based on PA6/PVP blends, Journal of Achievements in Materials and Manufacturing Engineering 18 (2006) 91-94.
  • [3] J. Koszkul, D. Kwiatkowski, The influence of annealing on dynamical mechanical properties of polyamide 6/fiber glass composites, Journal of Achievements in Materials and Manufacturing Engineering 19/2 (2006) 16-20.
  • [4] J. Myalski, J. Śleziona, Influence of preparing of GFR recyclates on the properties of polyester matrix composites, Journal of Achievements in Materials and Manufacturing Engineering 18 (2006) 163-166.
  • [5] S. M. Zebarjad, S.A. Sajjadi, M. Tahani, A. Lazzeri, A study on thermal behaviour of HDPE/CaC03 nanocomposites, Journal of Achievements in Materials and Manufacturing Engineering 17 (2006) 173-176.
  • [6] M. Arroyo, M.A. Lopez-Manchado, F. Avalos, Crystallization kinetics of polypropylene: Effect of the addition of short glass fibres, Polymer 38/22 (1997) 5587-5593.
  • [7] E. Mader, H.J. Jacobasch, K. Grundke, T. Gietzeld, Influence of an optimized interphase on the properties of polypropylene/glass fibre composites, Composites Part –A 27A (1996) 907-912.
  • [8] G. Bogoceva-Gaceva, A. Janevski, E. Mader, Nucleation activity of glass fibres towards iPP evaluated by DSC and polarizing light microscopy, Polymer 42 (2001) 4409-4416.
  • [9] Z. Nitkiewicz, R. Sobczak, J. Koszkul, Microstructure and X-ray diffraction of polypropylene and polypropylene with glass fibre, Composites 2 (2001) 127-129 (in Polish).
  • [10] R. Sobczak, Z. Nitkiewicz, J. Koszkul, Supermolecular structure and thermal properties of polypropylene composites reinforced glass fibre, Composites 8 (2002) 343-348 (in Polish).
  • [11] K. Suchocka-Gałaś, C. Ślusarczyk, A. Włochowicz, The state of ion aggregation in ionomers based on copolymers of styrene and acrylic acid, 1. Small- angle X-ray scattering studies, European Polymer Journal 36 (2000) 2167-2174.
  • [12] R. Sobczak, Examinations of the supermolecular structure of polypropylene composites reinforced glass fibres with using saxs method, Polymer materials and their manufacturing, Częstochowa University Press, Częstochowa 2004, (in Polish).
  • [13] F. Auriemma, O.D. De Ballesteros, C. De Rosa, P. Corradini, Structural disorder in the α form of isotactic polypropylene, Macromolecules 33 (2000) 8764-8774.
  • [14] M. Naiki, T. Kikkawa, Y. Endo, K. Nozaki, T. Yamamoto, T. Hara, Crystal ordering of α phase isotactic polypropylene, Polymer 42 (2000) 5471-5477.
  • [15] M. Ijima, G. Strobl, Isothermal crystallization and melting of isotactic polypropylene analyzed by time and temperature dependent small - angle X - ray scattering experiments, Macromolecules 33 (2000) 5204-5214.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS5-0019-0062
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