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Electrolytic extractions obtained from Cu-Zr and Cu-Ce alloys and their X-ray phase analysis

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Konferencja
12th International Scientific Conference CAM3S'2006, 27-30th November 2006, Gliwice-Zakopane
Języki publikacji
EN
Abstrakty
EN
Purpose: The aim of the investigations is the formation of electrolytic extractions from Cu-Zr and Cu-Ce model alloys containing microadditions of Zr and Ce amounting to about 0.1% by weight and their identification by X-ray diffraction analysis. Design/methodology/approach: Electrolytic extractions were obtained by the anodic dissolution of the alloys. In the X-ray analysis the comparative method was applied. Findings: The activity of anodic dissolution of the investigated alloys was determined basing on the mass of the electrolytic extraction and the time of dissolution of the alloy in solutions of the electrolytes with different chemical compositions and a different complexive effect to copper and different pH. Research limitations/implications: The qualitative X-ray phase analysis permits to identify the main intermetallic phases of the investigated alloys in a limited range, mainly due to experimental reasons. Practical implications: The results of these investigations indicate a distinct relation between the mass and the kind of the dissolved phase and the value of the electrochemical potential of the active dissolution of the alloys. Originality/value: The revealing of this relation is of practical importance in regard to the accuracy of the results of the phase and crystal analysis carried out by X-ray diffraction examination.
Rocznik
Strony
171--174
Opis fizyczny
Bibliogr. 15 poz., rys. tab.
Twórcy
autor
autor
  • Division of Constructional and Special Materials Engineering, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18 a, 44-100 Gliwice, Poland, wojciech.ozgowicz@polsl.pl
Bibliografia
  • [1] S. Wagh, N. Ezegbunam, Acta Met., 9(1984) 933.
  • [2] M. Kanno, N. Shimodaira. Trans. J. I. M., 28, 9 (1987) 742.
  • [3] S. Fujiwara, K. Abiko, J. de Phys. IV, 9 (1995) C7-295.
  • [4] W. Ozgowicz, Mechanics Z. 145 Silessian University Press, Gliwice, 2004.
  • [5] M. Colin, Metals Reference Book, (1978).
  • [6] M. Lou, J. Grant, Metal Trans., 8 (1984) 1491.
  • [7] E. Kneller (et. all), Z. Metallkde Bd., 77 (1986) 43.
  • [8] B. Massalski, Binary alloy phase diagrams, ASM, Sec. Ed. (1990).
  • [9] W. Ozgowicz, M. Karolus, Proc. Int. XIX Conf. on Apel. Crystallography, (2003) Cracow, Poland.
  • [10] W. Chrzanowski (et.all.), Proc.of.12 Int.Sci.Conf.AMME, Gliwice-Zakopane, Dec. 07-10 (2003) 911.
  • [11] N. Bagotsky, Fundamentals of Electrochemistry, J. Wiley & Sons, Pennington, N.Jersey (2005).
  • [12] A. Kisza, Electrochemistry Ed. WNT, Warsow, (2001).
  • [13] S.Pawlikowski, The Outline of technical electrochemistry, Ed. WNT, Warsow, (1969).
  • [14] L. Kolditz, The Inorganic chemistry vol.2, Ed. PWN, Warsaw, (1994).
  • [15] A. Cygański, Basis electroanalytical methods, Ed. WNT, Warsaw, (1999).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS5-0018-0032
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