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Zircon pigments are crystal, synthetic coloured compounds with crystal lattice of zirconium silicate. These pigments are produced when zirconia is combined with silica in the temperature of about 1500 degrees centigrade, in the presence of chromophores (e.g. vanadium, praseodymium, iron, cobalt) that are built into ZrSiO4 lattice. The product of this process are blue, yellow, pink and grey pigments. The process of production of zircon pigments is a solid-state reaction. Besides breaking and producing chemical bonds, there are also taking place crystallographic changes. The reaction starts in points of intergranular contacts. The speed of reaction is a function of contacts' quantity. The contacts depend on quantitative composition and properties of reaction mixture. In this article were presented effects of influence of reactants' properties on the colour of chosen zirconium pigments.
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Tom
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2--9
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autor
autor
autor
autor
- Instytut Szkła i Ceramiki, Warszawa
Bibliografia
- [1] DCMA Classiffication and Chemical Description of the Mixed-Metal Inorganic Colored Pigments, 2-ed, dry Color Manufacturers Assoc., Alexandria, Va, 1982.
- [2] Trojan M.: Synthesis of Yellow Pigments from Zircon Mineral. Dyes and Pigments 13, (1990), 281-287
- [3] Solc Z., Trojan M.: Principy pripravy keramickych pigmentu. Sklar a Keramik nr 39, 1989, s. 16-22
- [4] Rubio-Puzzo L., Caracoche M. C, Cervera M. M., Rivas P. C, Ferrari A. M., Bondioli F.: Hyperfine characterization of Pure and Doped Zircons. Journ. of Solid State Chem. 150, (2000), 14-18.
- [5] Kato E.: Untersuchungen an Keramischen Farbstoffen. Keramische Zeitschrift, 1961, 11, s. 617-622.
- [6] Barthane Bologh A., Leventene K.: Cirkonbazisu szintestech vizsgalate. Epitoanyng XXXV, 8, (1983), 293-296.
- [7] Eppler Richard A.: Zirconia - Based Colors for Ceramic Glazes. Am.Ceram. Soc. Bull. Vol. 56, No 2, (1977), 213-218.
- [8] Trojan M.: Synthesis of a Blue-Green Pigment from the Mineral Zircon. Ceramics International 16, 1990, s. 135-141.
- [9] Shoyama M., Hashimoto K., Hashimoto T., Nasu H., Kaniya K.: Iron-Zircon Pigments Prepared by the Sol-Gel Method. Journ. of the Ceram. Soc. of Jap. 107, [6], (1999), 534-540.
- [10] Trojan M., Solc Z.: Priprava modreho keramickeho pigmentu typu Zr1-xVxSi04. Silikaty 3, (1984), 223-235.
- [11] Trojan M.: Synthesis of a Blue-Green Pigment Zirconium Silicate Pigment. Dyes and Pigments 14, (1990), 9-22.
- [12] Trojan M.: Synthesis of a Pink Zircon Pigment. Dyes and Pigments 9,(1988), 329-342.
- [13] Llusar M., Badenes J. A., Calbo J., Tena M. A., Monrós G.: Environmental and colour optimisation of mineraliser addition in synthesis of iron zircon ceramic pigment. British Ceramic Transactions, Volume 99, Number 1, January 2000, pp. 14-22 (9).
- [14] Batchelor R. W.: Modern Inorganic Pigments. Trans. Journ. Brit. Ceram. Soc. Vol. 53, 8, (1970), 297-301.
- [15] Becherescu D., Ivan E., Winter F., Menessy I., Gagea L.: Noi pigmenti in sistemul Zr02-Si02. Materiale de Constructi vol. XIII, 1, (1983), 32-35.
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BOS5-0011-0028