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Tribochemia materiałów ceramicznych.

Identyfikatory
Warianty tytułu
EN
Tribochemical of ceramic materials.
Języki publikacji
PL
Abstrakty
PL
W pracy przedstawiono zjawiska fizyczne przebiegające w procesie tarcia, które mają wpływ na reakcje chemiczne, katalityczne i tribochemiczne. Podano właściwości fizykochemiczne i tribologiczne reprezentatywnych materiałów ceramicznych. Omówiono na przykładach reakcje katalityczne i tribochemiczne zachodzące w czasie tarcia na powierzchniach elementów ceramicznych z udziałem wody, olejów smarowych i niektórych dodatków uszlachetniających.
EN
Chemical interaction with ambient gases and with components of lubricant liquids influence the friction forces and wear rate of ceramics. Physical phenomena occuring in friction affect chemical, tribochemical and catalytic reactions. In the presence of water vapor or hydrocarbon lubricants and lubricating oil additives for example, tribochemical reactions decrease or increase wear, depending on the kind of ceramics. These different types of behaviour can be understood in terms of the surface chemistry of ceramics, which is dominated by charge transfer with ambient gases and components of lubricants through acid-base reactions. Some physicochemical and tribological properties of ceramics are presented. Examples of catalytic and tribochemical reactions in friction, employing water, base oils and some lubricating oil additives for ceramics are discussed.
Rocznik
Strony
7--20
Opis fizyczny
Bibliogr. 24 poz.
Twórcy
autor
  • Uniwersytet Łódzki, Katedra Technologii Chemicznej i Ochrony Środowiska, ul. Pomorska 163, 90-236 Łódź, tel. (42) 635-58-37, fax: (42) 678-70-87
  • Uniwersytet Łódzki, Katedra Technologii Chemicznej i Ochrony Środowiska, ul. Pomorska 163, 90-236 Łódź, tel. (42) 635-58-37, fax: (42) 678-70-87
Bibliografia
  • [1] Hsu S.M., Shen M.C., Klaus E.E., Cheng H.S., Lacey P.J.: Mechano-chemical model: reaction temperatures in a concentrated contact, Wear, 175, (1994), 209-218.
  • [2] Singer J. L., Friction and energy dissipation at the atomic scale - a review, Dissipative Processes in Tribology, D. Dowson et al. (Editors), Elsevier Science В. V. 1994, 3-20.
  • [3] Fischer T.E., Tomizawa H.: Interaction of tribochemistry and microfacture in the friction and wear of silicon nitride, Wear, 105, (1985), 29-45.
  • [4] Fischer T.E., Anderson M.P., Jahanmir S., Salher R.: Friction and wear of tough and brittle zirconia in nitrogen, air, water, hexadecane and hexadecan containing stearic acid, Wear, 124, (1988), 133-142.
  • [5] Tomizawa H., Fischer T.E.: Friction and wear of silicon nitride and silicon carbide in water: hydrodynamic lubrication at low sliding speed obtained by tribochemical wear, ASLE Trans., 30, (1987), 41-46.
  • [6] Sugita T., Ueda K., Kanemura Y.: Material removal mechanisms of silicon nitride during rubbing in water, Wear, 97, (1984), 1-8.
  • [7] Kajdas C.: A novel approach to tribochemical reactions: generalized NIRAM - HSAB action mechanism, Proc. Int. Tribology Conf. Yokohama 1995, 31-35.
  • [8] Volante M., Fubini B., Giamello E., Bolis V.: Reactivity induced by grinding in silicon nitride, J. Mater. Sei. Letters, 8, (1989), 1076-1078.
  • [9] Gates R.S., Hsu S.M., Klaus E.E.: Tribochemical mechanism of alumina with water, Tribology Trans., 32, (1989), 357-363.
  • [10] Kondo H., Aoki M., Seto J.: Tribochemical reactions on the surfaces on thin film magnetic media, Tribology Trans., 36, (1993), 193-200.
  • [11] Kondo H., Aoki M., Seto J.: Lubrication mechanism of phosphite and thiophosphite on magnetic film media, Wear, 160, (1993), 125-130.
  • [12] Gates R.S., Hsu S.M.: Silicon Nitride Boundary Lubrication. Effect of Sulfonate, Phenate and Salicylate Compounds, Tribology Trans., 43, (2000), 269-274.
  • [13] Wei J., Xue Q.: Tribochemical mechanism of Si3N4 with additives, Wear, 162-164, (1993), 1068-1072.
  • [14] Wei J., Xue Q.: Effect of additive interactions on the friction and wear properties of WC coating, Wear, 157, (1992), 163-180.
  • [15] Habeeb J.J., Blahey A.G., Rogers W.N.: Wear and lubrication of ceramics, I. Mech. E., C132/87, (1987), 555-564.
  • [16] Studt P.: Influence of lubricating oil additives on friction of ceramics under conditions of boundary lubrication, Wear, 115, (1987), 185-191.
  • [17] Sasaki S.: The effects of the surrounding atmosphere on the friction and wear of alumina, zirconia, silicon carbide and silicon nitride, Wear, 134, (1989), 185-200.
  • [18] Hibi Y., Enomoto Y.: Lubrication of Si3N4 and A120 3 in water with and without addition of silane coupling agents in the range of 0.05-0.10 mol/1., Tribology Int., 28, (1995), 97-105.
  • [19] Wei J., Fong W., Bogy D.B., Bhatia C.S.: The decomposition mechanisms of a perfluoropolyether at the head/disk interface of hard disk drives, Trib. Lett. 5, (1998), 203-209.
  • [20] Chen C.Y., Bogy D.B., Bhatia C.S.: Effects of backbone and endgroup on the decomposition mechanisms of PFPE lubricants and their tribological performance at the head-disk interface, Journal of Tribology, 123 (2001), 365-367.
  • [21] Kasai P.H.: Perfluoropolyethers: intramolecular disproportionation, Macromolecules, 25 (1992), 63-68.
  • [22] Smart B.E., Dixon D.A.: Heterolytic C-F bond energies and stabilities of poly(perfluoroethers), Journal of Fluorine Chemistry, 57, (1992) 251-258.
  • [23] Przedlacki M., Przemiany chemiczne wybranych fluorowanych substancji smarowych przebiegające w warunkach tarcia granicznego, Praca doktorska, UL, 2004.
  • [24] Zhao X., Bhushan B., Kajdas C.: Lubrication studies of head-disk interfaces in a controlled environment: Part 2: degradation mechanisms of perfluoropolyether lubricants; Proc. Instn. Mech. Engrs. 214 (2000), Part J. 1-13.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS5-0009-0053
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