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Development of alumina forming coatings for titanium aluminides.

Identyfikatory
Warianty tytułu
EN
Rozwój pokryć z tlenkiem glinu do aluminidków tytanu.
Konferencja
XVIth Physical Metallurgy and Materials Science Conference on Advanced Materials and Technologies AMT'2001, Gdańsk-Jurata, 16-20 September 2001
Języki publikacji
PL
Abstrakty
EN
One important hindrance for the use of gamma-TiAl alloys at high temperatures is their relatively poor oxidation resistance and the sensitivity against environmentally induced embrittlement. The latter effect is also of major concern during elevated temperature application of Ti-based alloys. These problems can principally be avoided by the application of oxidation resistant, alumina forming coatings. In the present paper the possibility of using a Ag-containing TiAl alloy as a coating material for Ti and high-strength gamma-TiAl-alloys is being studied. First, oxidation tests in different environments were carried out, to compare the isothermal and cyclic oxidation resitance of a selected Ag containing coating alloy with that of two, new generation, high strength gamma-titanium aluminides. Subsequently, magnetron sputtering was used to apply the TiAl-Ag coating to a gamma-TiAl alloy (Ti-45Al-8Nb-0.2C) and to pure titanium. The coated materials were tested at 800 degrees centigrade in case of the gamma-TiAl substrate, and at 600 degrees centigrade in case of the Ti substrate. The results illustrate, that the coatings in all studied cases formed a protective alumina surface scale even up to the longest studied test times of 1000 hours. The interdiffusion processes between coating and base material, which eventually determine the coating life, were studied by SEM/EDX investigation after different exposure times.
Rocznik
Strony
829--833
Opis fizyczny
Bibliogr. 18 poz., rys.
Twórcy
  • Forschungszentrum Juelich, Germany
autor
  • University of Mining and Metallurgy, Kraków, Poland
autor
  • Forschungszentrum Juelich, Germany
autor
  • University of Mining and Metallurgy, Kraków, Poland
  • Forschungszentrum Juelich, Germany
  • Forschungszentrum Juelich, Germany
Bibliografia
  • [1] D. M, Dimiduk.: Gamma titanium aluminide alloys-an assessment within the competition of aerospace structural materials. Materials Science and Engineering, 263 (1999), p.281-288.
  • [2] F. Appel, U. Brossmann, U. Christoph, S. Eggert, P. Janschek, U. Lorenz, J. Müllauer, M. Oehring, J. D. H. Paul.: Recent Progress in the Development of Gamma Titanium Aluminide Alloys, Advanced , Engineering Materials, 2 (2000), p.699-720.
  • [3] R.Rahmel, W.J. Quadakkers and M. Schütze.: Fundamentals of TiAl oxidation – A critical review”, Materials and Corrosion, 46 (1995), p. 271-285
  • [4] J. Mendez.: On the effects of temperature and environment on fatigue damage processes in Ti alloys and in stainless steel, Materials Science and Engineering, 263 (1999), p. 187-192.
  • [5] Y. Shida, H. Anada.: The effect of various ternary additives on the oxidation behaviour of TiAl in high-temperature air, Oxidation of Metals, 2 (1996), p. 197-219.
  • [6] M. P. Brady, J, L. Smialek, J. Smith and D.L. Humphrey.: The role of Cr in promoting protective alumina scale formation by y-based Ti-Al-Cr alloys-l. Compatibility with alumina and oxidation behaviour in oxygen, Acta Materialia, 45 (1997), p.2357-2369.
  • [7] Brady, J. L. Smialek, J. Smith and D. L. Humphrey: The role of Cr in promoting protective alumina scale formation by [-based Ti-Al-Cr alloys-ll. Oxidation behaviour in air, Acta Materialia, 45 (1997), p. 2371- 2382
  • [8] V. Shemet, A. K. Tyagi, J. S, Becker, P. Lersch, L. Singheiser, W. J. Quadakkers.: The formation of protective alumina-based scales during high-temperature air oxidation of y-TiAl alloys, Oxidation of Metals, 53 (2000), P. 211-235.
  • [9] V. Shemet, L. Niewolak, p. J. Ennis, W. J. Quadakkers, L. Singheiser.: Oxidation resistant y-TiAl based alloys for advanced gas turbine components and coating systems, Parsons 2000, ed. A. Strang, W.M. Banks, R.D. Conroy, G.M. McColvin, J.C. Neal & S.Simpson (The University Press, Cambridge, 2000), p.874-884.
  • [10] H. Clemens, H. Kestler.: Processing and applications of intermetallic y-TiAl-based alloys, Advanced Engineering Materials, 2 (2000), P. 551-570
  • [11] N. Zheng, W. Fischer, H. Grübmeier, V. Shemet, W.J. Quadakkers.: The significance of sub-surface depletion layer composition for the oxidation behawior of y-titanium aluminides, Script. Metall. et Mater, 33 (1995), 47-53
  • [12] E. Copland,B. Gleeson, D. J. Young, “Formation of Z-Ti50Al30Q20, in the sub-oxide zones of y-TiAl-based alloys during oxidation at 1000°C“ Acta Materialia, 47 (1999), p. 2937-2949.
  • [13] V. Shemet, p. Karduck, H. Hoven, B. Grushko, W. Fischer and W. J. Quadakkers.: Synthesis of the cubic Z-phase in the Ti-Al-O system by a powder metallurgical method, Intermetallics, 5 (1977), p. 271-280.
  • [14] C. Lang, M. Schütze.: TEM studies of the mechanism of the early stages of TiAl oxidation, „Microscopy of Oxidation 3”, ed. S. B. Newcomb, J. A. Little, (The Institute of Materials, London, 1997), p.265-276.
  • [15] B.A. Pint, J.R. Martin and L.W. Hobbs.: The oxidation mechanism of θ- Al₂O3 scales, Solid States Ionics, 250 (1997), 99-107.
  • [16] M. W. Brumm, H. J. Grabke.: The oxidation behavior of NiAl-I. phase transformation in the alumina scale during oxidation of NiAl and NiAl-Cr alloys, Corrosion Science, 33 (1992), P.1667-1690
  • [17] S. Taniguchi, N. Hongawara, T. Shibata.: Influence of gaseous species on the oxidation behavior of TiAl at high temperatures, Gamma titanium aluminides 1999, ed. Young-Won Kim, D. M. Dimiduk, M. H. Loretto, (Warrendale, PA: The Minerals, Metals & Materials Society, 1999), p. 811-816.
  • [18] H-P. Martinz, H. Clemens, W. Knabl.: Oxidation protective coatings for y-TiAl based alloys, Gamma titanium aluminides 1999, ed. Young-Won Kim, D. M. Dimiduk, M. H. Loretto, (Warrendale, PA: The Minerals, Metals & Materials Society, 1999), p.829-836.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS5-0003-0042
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