Structure and properties of Fe-Cr-Mo-C bulk metallic glasses obtained by die casting method

• Autorzy: Pilarczyk W. , Nowosielski R. , Januszka A.
• Języki publikacji: EN

Abstrakty

EN

Purpose: The goal of this work is to investigate structure and properties of Fe54Cr16Mo12C18 alloy rods with different diameters obtained by the pressure die casting method. Design/methodology/approach: Master alloy ingot with compositions of Fe54Cr16Mo12C18 was prepared by induction melting of pure Fe, Cr, Mo, C elements in argon atmosphere. The investigated material were cast in form of rods with different diameters. Glassy and crystalline structures were examined by X-ray diffraction. The microscopic observation of the fracture morphology was carried out by the SEM with different magnification. The thermal properties of the studied alloy were examined by DTA and DSC method. Findings: These materials exhibit high glass-forming ability, excellent mechanical properties and corrosion resistance. Research limitations/implications: It is difficult to obtain a metallic glass of Fe54Cr16Mo12C18 alloy. The investigations carried out on the different samples of Fe54Cr16Mo12C18 bulk metallic alloy allowed to state that the studied ribbon was amorphous whereas rods were amorphous – crystalline. Originality/value: The formation and investigation of the casted Fe-Cr-Mo-C bulk materials and the study of glass-forming ability of this alloy.

Słowa kluczowe

EN

metallic glass; bulk metallic glasses; glass-forming ability; Fe-based alloy; thermal properties

PL

szkła metaliczne; formowalność szkła; właściwości termiczne; stop żelaza

• Wydawca: International OCSCO World Press
• Czasopismo: Journal of Achievements in Materials and Manufacturing Engineering
• Rocznik: 2010
• Tom: Vol. 42, nr 1-2
• Strony: 80--87
• Opis fizyczny: Bibliogr. 34 poz., rys., tabl.

Twórcy

autor

Pilarczyk W.

autor

Nowosielski R.

autor

Januszka A.

• Division of Nanocrystalline and Functional Materials and Sustainable Pro-ecological Technologies, Institute of Engineering Materials and Biomaterials, Silesian University of Technology,ul. Konarskiego 18a, 44-100 Gliwice, Poland,

Bibliografia

• [1]Q. Chen, J. Shen, D. Zhang, H. Fan, J. Sun, D.G. McCartney, A new criterion for evaluating the glass-forming ability of bulk metallic glasses, Materials Science and Engineering A 433 (2006) 155-160.
• [2]A. Inoue, Bulk amorphous and nanocrystalline alloys with high functional properties, Materials Science and Engineering A 304-306 (2001) 1-10.
• [3]A. Inoue, B.L. Shen, C.T. Chang, Fe- and Co-based bulk glassy alloys with ultrahigh strength of over 4000 MPa, Intermetallics 14 (2006) 936-944.
• [4]A.I. Salimon, M.F. Ashby, Y. Bréchet, A.L. Greer, Bulk metallic glasses, Intermetallics 11 (2003) 529-540.
• [5]J. Basu, S. Ranganathans, Bulk metallic glasses: A new class of engineering materials, Sathana 28, Parts 3 and 4 (2003) 783-798.
• [6]C. Suryanarayana, I. Seki, A. Inoue, A critical analysis of the glass-forming ability of alloys, Journal of Non-Crystalline Solids (2009) (article in press)
• [7]J. Rasek, Some diffusion phenomena in crystalline and amorphous metals, Silesian University Press, Katowice, 2000 (in Polish).
• [8]R. Nowosielski, R. Babilas, Preparation, structure and properties of Fe-based bulk metallic glasses, Journal of Achievements in Materials and Manufacturing Engineering 40/2 (2010) 123-130.
• [9]J.F. Löffler, Bulk metallic glasses, Intermetallics 11 (2003) 529-540.
• [10]W. Pilarczyk, R. Nowosielski, R. Babilas, A production attempt of selected metallic glasses with Fe and Ni matrix, Archives of Materials Science and Engineering 41/1 (2010) 5-12.
• [11]A. Inoue, Bulk amorphous and nanocrystalline alloys with high functional properties, Materials Science and Engineering A 304-306 (2001) 1-10.
• [12]R. Nowosielski, R. Babilas, S. Griner, G. Dercz, A. Hanc, Crystallization of Fe72B20Si4Nb4 metallic glasses ribbons, Journal of Achievements in Materials and Manufacturing Engineering 34/1 (2009) 15-22.
• [13]A. Inoue, Stabilization of metallic supercooled liquid and bulk amorphous alloys, Acta Materiala 48 (2000) 279-346.
• [14]I. Akihisa, Bulk amorphous and nanocrystalline alloys with high functional properties, Materials Science and Engineering A 304-306 (2001) 1-10.
• [15]R. Nowosielski, R. Babilas, S. Griner, Z. Stok..osa, Structure and soft magnetic properties of Fe72B20Si4Nb4 bulk metallic glasses, Archives of Materials Science and Engineering 35/1 (2009) 13-20.
• [16]S. Lesz, P. Kwapuli..ski, R. Nowosielski, Formation and physical properties of Fe-based bulk metallic glasses with Ni addition, Journal of Achievements in Materials and Manufacturing Engineering 31/1 (2008) 35-40.
• [17]S. Lesz, Z. Stok..osa, R. Nowosielski, Influence of copper addition on properties of (Fe36Co36B19Si5Nb4)100-xCux metallic glasses, Archives of Materials Science and Engineering 38/1 (2009) 12-18.
• [18]Y. Kawamura, T. Shoji, Y. Ohno, Welding technologies of bulk metallic glasses, Journal of Non-Crystalline Solids 317 (2003) 152-157.
• [19]D. Szewieczek, J. Tyrlik-Held, S. Lesz, Structure and mechanical properties of amorphous Fe84Nb7B9 alloy during crystallization, Journal of Achievements in Materials and Manufacturing Engineering 24/1 (2007) 87-90.
• [20] S. Lesz, D. Szewieczek, J. Tyrlik-Held, Correlation between fracture morphology and mechanical properties of NANOPERM alloys, Archives of Materials Science and Engineering 29/2 (2008) 73-80.
• [21] J.M. Park, J.S. Park, J.H. Na, D.H. Kima, D.H. Kim, Effect of Y addition on thermal stability and the glass forming ability in Fe-Nb-B-Si glassy alloys, Materials Science and Engineering A 435-436 (2006) 425-428.
• [22] W.H. Wand, Roles of minor additions in formation and properties of bulk metallic glasses, Progress in Materials Science 52 (2007) 540-596.
• [23] T. Zhang, A. Inoue, New Bulk Glassy Ni-Based Alloys with High Strength of 3000 MPa, Material Transformations 43/4 (2002) 708-711.
• [24] J.T. Guo, K.W. Huai, H.T. Li, Significant Improvement of mechanical properties in NiAl-Cr(Mo)/Hf alloy by suction casting and subsequent hot isostatic pressing, Metallurgical and Materials Transactions A 38/1 (2007) 35-43.
• [25] Q. Jing, Y. Zhang, Y. Li, Composition optimization of the NiZrYAl glass forming alloys, Journal of Alloys and Compounds 424 (2006) 307-310.
• [26] T. Kulik, Formation and magnetic properties of Co- Fe-based bulk metallic glasses with supercooled liquid region, Journal of Magnetism and Magnetic Materials 299 (2006) 492-495.
• [27] D. Szewieczek, T. Raszka, J. Olszewski, Optimisation the magnetic properties of the (Fe1-xCox)73.5Cu1Nb3Si13.5B9 (x=10; 30; 40) alloys, Journal of Achievements in Materials and Manufacturing Engineering 20 (2007) 31-36.
• [28] P. Kwapuliński, J. Rasek, Z. Stokłosa, G. Badura, B. Kostrubiec, G. Haneczok, Magnetic and mechanical properties in FeXSiB (X=Cu, Zr, Co) amorphous alloys, Archives of Materials Science and Engineering 31/1 (2008) 25-28.
• [29] G. Badura, J. Rasek, Z. Stokłosa, P. Kwapuliński, G. Haneczok, J. Lelątko, L. Pająk, Soft magnetic properties enhancement effect and crystallization processes in Fe78-xNbxSi13B9 (x = 0, 2, 4) amorphous alloys, Journal of Alloys and Compounds 436 (2007) 43-50.
• [30] B. Shen, Ch. Chang, A. Inoue, Formation, ductile deformation behavior and soft-magnetic properties of (Fe,Co,Ni)-B-Si-Nb bulk glassy alloys, Intermetallics 15 (2007) 9-16.
• [31] Ch. Chang, B. Shen, A. Inoue, Synthesis of bulk glassy alloys in the (Fe,Co,Ni)-B-Si-Nb system, Materials Science and Engineering A 449-451 (2007) 239-242.
• [32] S.J. Pang, T. Zhang, K. Asami, A. Inoue, Bulk glassy Fe-Cr-Mo-C-B alloys with high corrosion resistance, Corrosion Science 44 (2002) 1847-1856.
• [33] S.J. Pang, T. Zhang, K. Asami, A. Inoue, Synthesis of Fe-Cr-Mo-C-B-P bulk metallic glasses with high corrosion resistance, Acta Materialia 50 (2002) 489-497.
• [34] Y.H. Zhao, C.Y. Luo, X.K. Xi, D.Q. Zhao, M.X. Pan, W.H. Wang, Synthesis and elastic properties of amorphous steels with high Fe content, Intermetallics 14 (2006) 1107-1111.