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Thermomechanical processing of CuTi4 alloy

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: One of the reasons behind the interest in copper titanium alloys was development of new materials to substitute copper beryllium alloys. The reason for selecting that material for studies was that in the early stages of decomposition of CuTi4 alloy a spinodal transformation takes place and ordering processes begin. Proper selection of heat treatment and plastic working conditions provides possibilities to produce very wide range of sets of properties by formation of the required alloy microstructure. Therefore the main objective of the study was to capture the changes in precipitation kinetics, especially in the relations between supersaturation and ageing or between supersaturaion, cold deformation and ageing in connection to the changes in microstructure and functional properties (mainly changes in hardness and electrical conductivity). Design/methodology/approach: Melting of the charge material was conducted in medium-frequency induction furnace, in a graphite crucible. The melted material after bath preparation was poured into a cast iron ingot mould (with graphite grease applied on the inside) of dimensions 35 x 120 x 250 mm. The ingots after casting were peeled. The treated ingots were heated in resistance furnace at 900şC for 1.5 hour and rolled down on a reversible two-high mill. Findings: Decomposition of supersaturated solid solution in that alloy is similar to the alloys produced in laboratory scale. The observed differences in microstructure after supersaturation were related to the presence of undissolved Ti particles and increased segregation of titanium distribution in copper matrix including microareas of individual grains. The mentioned factors influence the mechanism and kinetics of precipitation and subsequently the produced wide ranges of functional properties of the alloy. Research limitations/implications: Cold deformation (50% reduction) of the alloy after supersaturation changes the mechanism and kinetics of precipitation and provides possibilities for production of broader sets of functional properties. It is expected that widening of the cold deformation range should result in more complete characteristics of material properties, suitable for the foreseen applications. Similar effects can be expected after application of cold deformation after ageing. Practical implications: The elaborated research results present some utilitarian qualities since they can be used in development of process conditions for industrial scale production of strips from CuTi4 alloy of defined properties and operating qualities. Originality/value: The mentioned factors influence the mechanism and kinetics of precipitation and subsequently the produced wide ranges of functional properties of the Cu-Ti alloys.
Rocznik
Strony
9--25
Opis fizyczny
Bibliogr. 21 poz., rys., tabl.
Twórcy
autor
autor
autor
Bibliografia
  • 1. E. Hornbogen, Hundred years of precipitation hardening, Journal of Light Metals 1 (2001) 127-132.
  • 2. Z. Kędzierski, Phase transformation in condensed systems, AGH Publishing House, Cracow, 2003.
  • 3. T.B. Massalski, Binary Alloy Phase Diagrams, Seventh Edition, ASM International, 1990.
  • 4. Z. Rdzawski, Low alloyed copper, Silesian University of Technology Publishing House, Gliwice, 2009.
  • 5. J. Dutkiewicz, Mechanism of spinodal and dicscountinous decomposition and ordering processes in aged alloys with A1 structure, Metallurgy and Foundry 80 (1977).
  • 6. J. Dutkiewicz, L. Lityńska, Rusing of elektron diffraction for investigation of spinodal decomposition in Cu-Ti and Al.-Zn alloys, Proceedings of the 5th Conference "Electron Microscopy of Solids", Warszawa - Jadwisin, 1978, 149-154.
  • 7. J. Dutkiewicz, Spinodal decomposition, ordering, and discontinuous precipitation in deformed and aged copper- titanium alloys, Metals Technology October (1978) 333-340.
  • 8. J. Dutkiewicz, L. Lityńska, Ordering within precipitates in copper-nickel-titanium alloys, Journal of Materials Science 15 (1980) 2307-2310.
  • 9. S. Bzowski, S. Gorczyca, Phase transformation in Cu-Ti alloys, Metallurgy 29 (1981) 79-113.
  • 10. A.A. Hameda, L. Błaż, Structural aspects of dynamic precipitation in hot deformed Cu-3,46 wt.% Ti alloy, Proceedings of the 9th Conference "Electron Microscopy of Solids", Kraków - Zakopane, 1996, 247-250.
  • 11. L. Błaż, A.A. Hameda, Precipitation in Cu-Ti alloys during deformation at high temperature, Proceedings of the 3rd International Scientific Conference "Nonferrous Metals'97" Kraków, 1997, 283-291.
  • 12. A.A. Hameda, L. Błaż, Microstructure of hot-deformed Cu- 3,45 wt % Ti alloy, Materials Science and Engineering A 254 (1998) 83-89.
  • 13. A.A. Hameda, L. Błaż, The effect of flow localization on shear bands development on the structure and mechanical behavior of Cu-4.98 wt % Ti alloy, Proceedings of the Conference "Euromech-Mecamat", Magdeburg-Germany, 1998, 182-188.
  • 14. A.A. Hameda, L. Błaż, Structural Aspects of Dynamic Precipitation in Hot Deformed Cu-3.46%Ti Alloy, Proceedings of the 9th Conference "Electron Microscopy of Solids", Kraków - Zakopane, 1996, 247-250.
  • 15. A.A. Hameda, L. Błaż, Flow Softening During Hot Compression of Cu-3.45wt.%Ti Alloy, Scripta Materialia 37 (1997) 1987-1993.
  • 16. L. Błaż, Structural and Mechanical Aspects of Dynamic Precipitation in Some Precipitation Hardenable Alloys, Proceedings of the 15th Physical Metallurgy and Materials Science Conference "Advanced Materials and Technologies" AMT'98, Kraków - Krynica, 1998, 447-454.
  • 17. Dziadoń, J. Maurer, Structural Aspect of Over ageing in CuTi Alloys, Archives of Metallurgy 43 (1998) 363
  • 18. Dziadoń, Plastic Flow of CuTi Alloys at Elevated Temperatures, Archives of Metallurgy 46 (2001) 361.
  • 19. Dziadoń, M. Konieczny, Propertiees of layer type composite copper- copper-titanium intermatalic phases, Materials Engineering 6 (2003) 639-644.
  • 20. M. Konieczny, A. Dziadoń, Plastic deformation of layer type composite copper- intermatalic phases, Materials Engineering 3 (2006) 761-764.
  • 21. Dziadoń, M. Konieczny, Structural transformations at the Cu-Ti interface during synthesis of copper-intermetallics layered composite, Metallic Materials 42 (2004) 42-50.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS2-0023-0004
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