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Mechanical behaviour characterizing and simulation of polyacrylate rubber

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: of this paper is to investigate the influence of EB radiation on the mechanical behaviour of UV curing polyacrylate rubber (ACM) and to simulate its behaviour. Design/methodology/approach: The material was irradiated by two different EB doses, 100 kGy and 250 kGy, its mechanical behaviour was investigated with the help of uniaxial, equibiaxial and planar shear experiments. The results were applied to the Ogden’s Model (1972) in order to obtain the parameters to simulate the material behaviour by finite element method (FEM) and to compare experimental and FEM curves. The structure molecular changes caused by EB were investigated with the help of infrared spectroscopy. Findings: In most cases the experimental results showed an increase in the strength at rupture and a decrease in the elongation at the rupture with increasing of radiation dose. Equibiaxial and planar shear tests presented similar behaviour like uniaxial results, in terms of elongation decrease and strength increase, with some deviations. Ogden’s Model third order provided simulated curves with similar behaviour in comparison to experimental curves. The infrared spectroscopy showed different chemical group contents in the analyzed regions, surface and middle region. Research limitations/implications: Two doses of EB radiation were applied; higher or lower doses were not investigated. Practical implications: Improved behaviour of UV curing ACM can extend the range of industrial applications, or improve its performance in known applications. Originality/value: Usually EB radiation has been used to modify polymeric structure and to improve thermal and mechanical polymers behaviour. Regarding like rubber materials EB is usually applied as an alternative form of vulcanization. UV is a new type of curing for polyacrylate rubbers, which are usually cured by thermal processes.
Rocznik
Strony
33--40
Opis fizyczny
Bibliogr. 16 poz., rys., tabl.
Twórcy
  • Mechanical Engineering Department, University of Săo Paulo, Av. Prof. Mello Moraes, 2231, Cidade Universitária, Săo Paulo, 05508-970, Brazil, demetrio.santos@poli.usp.br
Bibliografia
  • [1] D. Manas, M. Manas, M. Stanek, M. Danek, Improvement of Plastic Properties, Archives of Materials Science and Engineering 32/2 (2008) 69-76.
  • [2] R. Segunpta, V. K. Tikku, A. W. Somani, T. K. Chaku, A. K. Bhowmick, Electron beam irradiated polyamide 6-6 films – I: characterization wide angle X-Ray Scattering and Infrared spectroscopy, Radiation Physics and Chemistry 72 (2005) 625-633.
  • [3] Z. P. Zagórsky, EB – Crosslinking of elastomers, how does it compare with radiation cross linking of other polymers, Radiation Physics and Chemistry 71 (2004) 261-265.
  • [4] V. Vijayabaskar, S. Bhattacharya, V. K. Tikku, A. K. Bhowmick, Electron beam initiated modification of acrylic elastomer in presence of polyfunctional monomers, Radiation Physics and Chemistry 71 (2004) 1045-1058.
  • [5] I Banik, A. K. Bhowmick, Effect of electron beam irradiation on the properties of cross linked rubbers, Radiation Physics and Chemistry 58 (2000) 293-298.
  • [6] B. A. Bernardi, M. W. Langley, P. E. Mangley, An Introduction to Polyacrylate Elastomers, In: Rubber Division Meeting of the American Chemical Society, (1999), Chicago, Paper nr PA0910.1.
  • [7] J. Bik, W. Gluszewski, W. M. Rzymski, Z. K. Zagórski, EB radiation cross linking of elastomer, Radiation Physics and Chemistry 67 (2003) 421-423.
  • [8] M. Sasso, G. Palmieri, G. Chiappini, D. Amodio, Characterization of hyperelastic rubber-like materials by biaxial and uniaxial stretching tests based on optical methods, Polymer Testing 27 (2008) 995-1004.
  • [9] A. L. Gent, Engineering with Rubber: How to Design Rubber Components, Oxford Univ. Press, New York, 1992.
  • [10] R. W. Ogden, Non-Linear Elastic Deformations, Dover Publications, New York, 1997.
  • [11] R. S. Rivlin, Large Elastic Deformation, In: Rheology: Theory and Applications, Academic Press Inc., New York, 1956.
  • [12] D. W. Haines, W. D. Wilson, Strain-Energy Density Functions for Rubber- Like Materials, Journal of the Mechanics and Physics of Solids 27 (1979) 345-360.
  • [13] K. Miller, Testing Elastomers for Hyperelastic Material Models in Finite Element Analysis, Testing and Analysis, 2001.
  • [14] J. Day, K. Miller, Equibiaxial Stretching of Elastomeric Sheets, An Analytical Verification of Experimental Technique, Testing and Analysis, Michigan, 2000.
  • [15] E. M. Arruda, M. C. A. Boyce, Three dimensional constitutive model for large stretch behaviour of rubber elastic materials, Journal of the Mechanics and Physics of Solids 41 (1993) 389-412.
  • [16] V. Placek, T. Kohout, V. Hnat, B. Bartonicek, Assessment of EPDM seal lifetime on nuclear power plants, Polymer Testing 28 (2009) 209-214.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS2-0022-0012
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