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Purpose: The aim of this paper is to show influence of technological parameters (temperature and gas stream intensity) of low-temperature chemical vapour deposition (LCVD) on optical properties and morphology of polyazomethine thin films. Design/methodology/approach: Thin layers of poly (1,4-phenylene-methylenenitrilo-1,4-phenylenenitrilo-methylene) (PPI) were prepared by low temperature LCVD method with use of argon as a transport agent. The UV-Vis spectroscopy and AFM microscopy measurements on PPI thin films were performed. Findings: The LCVD parameters, like temperature and argon stream intensity, influence growth rate, morphology and optical properties of polyazomethine thin films. Optimalization of technical parameters allows for thin films with desired properties to be prepared. Research limitations/implications: Optimalization of technical LCVD parameters leads to preparing PPI thin films having desired morphology and optical properties suitable for optoelectronic applications. Practical implications: PPI polyazomethine is good material for potential applications as the active layer in optoelectronic or photonic structure (diods or photovoltaic cells). Originality/value: LCVD with use of argon is relatively new method for preparing of thin polymer films. Recognizing of optimal technical parameters will make possible getting of thin films with required properties.
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Tom
Strony
41--48
Opis fizyczny
Bibliogr. 19 poz., rys., tabl.
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autor
autor
autor
- Division of Materials Processing Technology, Management and Computer Techniques in Materials Science, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, b.hajduk@cmpw-pan.edu.pl
Bibliografia
- [1] A. Kubono, N. Okui, Polymer thin films prepared by vapour deposition, Progress Polymer Science 19 (1994) 389-438.
- [2] J. Mc Elvain, S. Tatsuura, F. Wudl, A. J. Heeger, Linear and nonlinear optical spectra of polyazomethines fabricated by chemical vapour deposition, Synthetic Metals 95 (1998) 101-105.
- [3] W. R. Salaneck, R. H. Friend, J. L. Bredas, Electronic structure of conjugated polymers: consequences of electron-lattice coupling, Physics Reports 319 (1999) 231-251.
- [4] M. S. Weaver, D. D. C. Bradley, Organic elektroluminescence devices fabricated with chemical vapour deposited polyazomethine films, Synthetic Metals 61-66 (1996) 83.
- [5] L. A. Dobrzański, Engineering materials and materials design. Fundamentals of materials science and physical metallurgy, WNT, Warsaw-Gliwice, 2006 (in Polish).
- [6] L. A. Dobrzański, D. Pakuła, Comparison of the structure and properties of the PVD and CVD coatings deposited on nitride tool ceramics, Proceedings of the 13th Scientific International Conference „Achievements in Mechanical and Materials Engineering” AMME’2005, Gliwice–Wisła, 2005 (CD-ROM).
- [7] W. Kwaśny, D. Pakuła, M. Woźniak , L. A. Dobrzański, Fractal and multifractal characteristics of CVD coatings onto the nitride tool ceramics, Journal of Achievements in Materials and Manufacturing Engineering 20 (2007) 371-374.
- [8] K. G. Basava Kumar, P.G. Mukunda, M. Chakraborty,Influence of melt treatments and polished CVD diamond-coated insert on cutting force and surface integrity in turning of Al-12Si and Al-12Si-3Cu cast alloys, International Journal of Manufacturing Research 2 (2007) 117-137.
- [9] A. Jarząbek, J. Weszka, M. Domański, J. Cisowski, Optical properties of amorphous polyazomethine thin films, Journal of Non-Crystalline Solids 352 (2006) 1660-1662.
- [10] B. Jarząbek, J. Weszka, M. Domański, J. Jurusik, J. Cisowski, Optical studies of aromatic polyazomethine thin films, Journal of Non-Crystalline Solids 354 (2008) 856-862.
- [11] B.Hajduk, J.Weszka, B.Jarząbek, J.Jurusik, M.Domański, Physical properties of polyazomethine thin films doped with iodine, Jounal of Achievements in Materials and Manufacturing Engineering 24/1 (2007) 67-70.
- [12] J. Jaglarz, J. Cisowski, H. Czternastek, W. Odsterczył, J. Jurusik, M. Domański, Diffuse scatering in polyazomethine thin films, Polymers 54/1 (2009) 15-18.
- [13] F. Rohlfing, D. D. C. Bradley, Non linear Starc effect in polyazomethine and poly (p-phenylene-vinylene): The interconnections of chemical and electronic structure, Chemical Physics 227 (1998) 133-151.
- [14] Y. Shimoi, S. Abe, Theory on electroabsorption in poly(p-phenylene vinylene), Synthetic Metals 91 (1997) 363-365.
- [15] A. Borgesi, G. Tallarida, G. Amore, F. Cazzaniga, F. Queirolo, M. Alessandri, A. Sassela, Influence of roughness and grain dimension on the optical functions of polycrystalline silicon films, Thin Solid Films 313-314 (1998) 243-247.
- [16] B. Walker, A. Kambili, S. J. Martin, Electrical transport modelling in organic electroluminescent devices, Journal of Physics: Condensed Matter 14 (2002) 9825-9876.
- [17] W. R. Salaneck, R. H. Friend, J. L. Bredas, Electronic structure of conjugated polymers: Consequences of electron – lattice coupling, Physics Reports 319 (1999) 231-251.
- [18] A. Schouwink, A. H. Schafer, C. Seidel, H. Fuchs, The influence of molecular aggregation on the device properties of organic light emitting diodes, Thin Solid Films 372 (2000) 163-168.
- [19] D. D. C. Bradley, M. Grell, A. Grice, A. R. Tajbakhsh, D. F. O’Brien, A. Bleyer, Polymer light emission: control of properties through chemical structure and morphology, Optical Materials 9 (1998) 1-11.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BOS2-0020-0085