Non-equilibrium statistical mechanics formulation of thermal transport properties for binary and ternary gas mixtures

• Autorzy: Avsec J. , Naterer G. , Marcic M.
• Języki publikacji: EN

Abstrakty

EN

The paper develops a new statistical formulation to calculate the thermal diffusivity, binary diffusion coefficient, thermal diffusion factor, viscosity and thermal conductivity of gas mixtures with non-equilibrium statistical mechanics. For the analytical calculation of transport properties, the models of Kihara and Chapman-Cowling (up to the third order) have been used. Thermal transport properties for mixtures involving carbon monoxide, helium, argon, xenon and krypton have been computed with the new formulation in this paper. New mixing rules for the calculation of transport properties for mixtures are developed. Close agreement is obtained between the analytical results (based on statistical mechanics) and experimental data. The results exhibit comparable or better accuracy than previous methods, while providing new insight regarding the detailed statistical mechanisms of intermolecular interactions, as they contribute to the transport property variations with temperature.

Słowa kluczowe

EN

diffusion coefficients; statistical mechanics; transport properties

PL

mechanika statystyczna; własności transportowe; współczynnik dyfuzji

• Wydawca: Wydawnictwo Instytutu Maszyn Przepływowych PAN ; Komitet Termodynamiki i Spalania PAN
• Czasopismo: Archives of Thermodynamics
• Rocznik: 2008
• Tom: Vol. 29, no. 2
• Strony: 21--46
• Opis fizyczny: Bibliogr. 35 poz.,tabl., wykr., wz.,

Twórcy

autor

Avsec J.

autor

Naterer G.

autor

Marcic M.

• University of Maribor, Faculty of Mechanical Engineering, Maribor, Slovenia

Bibliografia

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