Wpływ właściwości rozpuszczalnika na kinetykę fotodegradacji 3-chlorofenolu

• Autorzy: Czaplicka M.

Warianty tytułu

EN

Effect of solvent properties on the kinetics of 3-chlorophenol photodegradation

• Języki publikacji: PL

Abstrakty

PL

Przedstawiono wyniki badań fotodegradacji 3-chlorofenolu pod działaniem promieniowania UV w rozpuszczalnikach polarnych i cykloheksanie. Badano wpływ właściwości rozpuszczalnika na szybkość reakcji. Zidentyfikowano trwałe produkty pośrednie reakcji rodnikowych oraz opisano krzywe kinetyczne ich powstawania. Wyznaczono stałe szybkości reakcji pierwszorzędowych.

EN

Experimental results of the investigations on the photodegradation of 3-chlorophenol by UV radiation in polar solvents and cyclohexane were present. Influence of solvents properties on reaction rate was studied. The intermediate reaction products of radical reactions were identified. The kinetic curves for formation these products were described. The reaction rate constants for first order reactions were determined.

Słowa kluczowe

PL

chlorofenol; fotodegradacja; promieniowanie UV

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Inżynieria Chemiczna i Procesowa
• Rocznik: 2004
• Tom: T. 25, z. 2
• Strony: 481--494
• Opis fizyczny: Bibliogr. 25 poz.

Twórcy

autor

Czaplicka M.

• Instytut Metali Nieżelaznych, ul. Sowińskiego 5, 44-100 Gliwice

Bibliografia

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