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Parametry charakteryzujące pulsacyjny przepływ układów tworzących piany przez złoże reaktora. Część 1, Prędkość pulsów
Języki publikacji
Abstrakty
The subject of the research are the parameters characterising pulsing flow through a TBR bed of a specific class of systems, namely, the systems forming foams of various stability. The investigations have been carried out for the systems in which argon, nitrogen and helium were the gas phases and water solutions of methylene, ethylene and isopropylene alcohols were the liquid phases. The way of determining as well as the results of measurements of the velocity of liquid pulses travelling along the bed have been presented. In the experiments, the physicochemical properties of both phases were varied in order to establish the influence of the gas density as well the viscosity, density and surface tension of the liquid phase on the measured values. It is shown that the real velocity of the gas phase is the most important parameter influencing the pulse velocity. A relationship has been elaborated, which correlates the results of experiments for all the systems investigated with an average relative error 7%.
Przedmiotem badań są parametry charakteryzujące pulsacyjny przepływ przez złoże reaktora typu TBR układów tworzących piany o różnej trwałości. Badania wykonano dla układów, w których fazą gazową były: argon, azot i hel, fazą ciekłą natomiast wodne roztwory alkoholi: metanolu, etanolu, izopropanolu. W niniejszej, pierwszej części opracowania przedstawiono sposób pomiaru oraz wyniki eksperymentów, w których określano prędkość pulsów cieczy wędrujących wzdłuż złoża. W eksperymentach zmieniano właściwości fizykochemiczne obu faz w celu określania wpływu gęstości gazu oraz lepkości, gęstości i napięcia powierzchniowego fazy ciekłej na mierzoną wielkość. Wykazano, że parametrem mającym największy wpływ na prędkość pulsów jest rzeczywista prędkość fazy gazowej. Opracowano zależność, która koreluje wyniki eksperymentów ze średnim błędem względnym nie przekraczającym 7%.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
151--164
Opis fizyczny
Bibliogr. 25 poz.
Twórcy
autor
- Institute of Chemical Engieering, Polish Academy of Science, Bałtycka St. 5, 44-100 Gliwice, Poland
autor
- Institute of Chemical Engieering, Polish Academy of Science, Bałtycka St. 5, 44-100 Gliwice, Poland
autor
- Department of Process Engineering, University of Opole, Dmowskiego St. 7-9, 45-365 Opole, Poland
Bibliografia
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- [2] SCHRAMM L.L., Foams: Fundamentals and Applications in the Petroleum Industry, American Chemical Society, Washington, 1994.
- [3] PUGH R.J., Foaming, foam films, antifoaming and defoaming, Adv. Colloid Interface Sci., 1996, 64, 67.
- [4] BARTELMUS G., JANECKI D., Hydrodynamics of the cocurrent downflow of a gas and a foaming liquid through a packed bed. Part I. Estimation of the transition boundary between the hydrodynamic regimes from the gas continuous flow to the pulsing flow in a packed bed, Chem. Eng. Process., 2003 (to be published).
- [5] CHOU T.S., WORLEY F.L., Luss D., Transition to pulsed flow in mixed phase cocurrent downflow through a fixed bed, Ind. Eng. Chem. Process Des. Dev., 1977, 16, 424.
- [6] BARTELMUS G., JANECKI D., Hydrodynamics of the cocurrent downflow of a gas and a foaming liquid through a packed bed. Part II. Liquid holdup and gas flow resistance through packing, Chem. Eng. Process., 2003 (to be published).
- [7] CHARPENTIER J.C., FAVIER M., Some liquid holdup experimental data in trickle-bed reactors for foaming and nonfoaming hydrocarbons, AIChE J., 1975, 21, 1213.
- [8] LARACHI F., LAURENT A., WILD G., MIDOUX N., Some experimental liquid saturation results in fixed-bed reactors operated under elevated pressure in cocurrent upflow and downflow of the gas and liquid, Ind. Eng. Chem. Res., 1991, 30, 2404.
- [9] MIDOUX N., FAVIER M„ CHARPENTIER J.C., Flow pattern, pressure loss and liquid holdup data in gas-liquid downflow packed beds with foaming and nonfoaming hydrocarbons, J. Chem. Eng. Japan, 1976, 9, 350.
- [10] SPECCHIA V., BALDI G., Pressure drop and liquid hold-up for two phase concurrent flow in packed beds, Chem. Eng. Sci., 1977, 32, 515.
- [11] SAI P.S.T., VARMA Y.B.G., Flow pattern of the phases and liquid saturation in gas-liquid cocurrent downflow through packed beds, Canad. J. Chem. Eng., 1988, 66, 353.
- [12] WEEKMAN V.W., MYERS J.E., Fluid-flow characteristics of cocurrent gas-liquid flow in packed beds, AIChE J., 1964,10, 951.
- [13] Beimesh W.E., Kessler D.P., Liquid-gas distribution measurements in the pulsing regime of two-phase cocurrent flow in packed beds, AIChE J., 1971, 17, 1160.
- [14] SATO Y., HIROSET., TAKAHASHI F., TODA M., HASHIGUCHI Y., Flow pattern and pulsation properties of cocurrent gas-liquid down-flow in packed beds, J. Chem. Eng. Japan, 1973, 6, 315.
- [15] RAO V.G., DRINKENBURG A.A.H., Rressure drop and hydrodynamic properties of pulses in two-phase gas-liquid downflow through packed columns. Can. J. Chem. Eng., 1983, 61, 158.
- [16] BLOK J.R., VARKEVISSER J., DRINKENBURG A.A.H., Transition to pulsing flow, holdup and pressure drop in packed columns with cocurrent gas-liquid downflow, Chem. Eng. Sci., 1983, 38, 687.
- [17] BLOK J.R., DRINKENBURG A.A.H., Hydrodynamic properties of pulses in two-phase downflow operated packed columns, Chem. Eng. J., 1982, 25, 89.
- [18] TSOCHATZIDIS N.A., KARABELAS A.J., Properties of pulsing flow in a trickle bed, AIChE J., 1995, 41,2371.
- [19] TSOCHATZIDIS N.A., NTAMPEGLIOTIS K. J., KARABELAS A.J., Effect of viscosity on hydrodynamic properties of pulsing flow in trickle beds, Chem. Eng. Comm., 1998,166, 137.
- [20] BARTELMUS G., GANCARCZYK A., STASIAK M., Hydrodynamics of cocurrent fixed-bed three-phase reactors. The effect of physicochemical properties of the liquid on pulse velocity, Chem. Eng. Process., 1998, 37, 331.
- [21] BURGHARDT A., BARTELMUS G, GANCARCZYK A., Hydrodynamics of pulsing flow in three-phase chemical reactors, Chem. Eng. Process., 1999, 38, 411.
- [22] SZLEMP A., BARTELMUS G., JANECKI D., Hydrodynamics of a co-current three-phase solid-bed reactor for foaming systems, Chem. Eng. Sci., 2001, 56, 1111.
- [23] HELWICK J. A., DILLON P. O., MCREADY M. J., Time varying behavior of cocurrent gas-liquid flows in packed beds, Chem. Eng. Sci., 1992, 47, 3249.
- [24] REINECKE N., MEWES D., Investigation of the two-phase flow in trickle-bed reactors using capacitance tomography, Chem. Eng, Sci., 1997, 52, 2111.
- [25] CHRISTENSEN G., MCGOVERN S.J., SUNDARESAN S., Cocurrent downflow of air and water in a two-dimensional packed column, AIChE J., 1986, 32, 1677.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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