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Calculation of transport coefficients of R-32 and R-125 with the methods of statistical thermodynamics and kinetic theories of gas

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Języki publikacji
EN
Abstrakty
EN
The paper features theoretical model of computing (based on methods of statistical thermodynamics and kinetic theories of gas) viscosity and thermal conductivity in the liquid and gas domain for pure components. To calculate the viscosity of real fluid, the models developed on the basis of Lennard-Jones intermolecular potential are applied. Heat capacities are calculated by use of statistical thermodynamics. The paper features all important contributions (translation, rotation, internal rotation, vibration, intermolecular potential energy and influence of electron and nuclei excitation). The analytical results obtained by statistical thermodynamics are compared with the REFPROP model and show relatively good agreement.
Rocznik
Strony
69--82
Opis fizyczny
Bibliogr. 19 poz.,Rys., tab.`,
Twórcy
autor
  • University of Maribor, Faculty of Mechanical Engineering, Maribor, Slovenia
Bibliografia
  • [1] MILLAT J., DYMOND J.H., NIETO DE CASTRO C.A.: Transport Properties of Fluids, Cambridge, University Press, 1996.
  • [2] FERZIGER J.H., KAPER H.G.: Mathematical Theory of Transport Processes in Gases, North-Holland Publishing Company, London 1972.
  • [3] MCCOURT F.R.W., BEENAKKER J.J., KÖHLER W.E., KUSCER I.: Nonequilibrium Phenomena in Polyatomic Gases, Clarendon Press, London 1990.
  • [4] CHAPMAN S., COWLING T.G.: The Mathematical Theory of Non-Uniform Gases, Third Edition, Cambridge, University Press; 1970.
  • [5] NEUFELD P.D., JANZEN A.R., Aziz R.A.: Empirical equations to calculate 16 of the transport collision integrals for the Lennard-Jones (12-6) potential, J. of Chem. Physics, Vol. 57, No.2 (1976), 1100-1102.
  • [6] KISELEV S.B., PERKINS R.A., HUBER M.L.: Transport properties of refrigerants R32, R125, R134a, and R125+R32 mixtures in and beyond the critical region, Int. J. of Refrigeration, Vol. 22, (1999), 509-520.
  • [7] KISELEV S.B., HUBER M.L.: Transport properties of carbon dioxide+ethane and methane+ethane mixtures in the extended critical region, Fluid Phase Equilibria, Vol. 142 (1998), 253-280.
  • [8] ASSAEL M.J., DALAOUTI N.K., GIALOU K.E.: Viscosity and thermal conductivity of methane, ethane and propane halogenated refrigerants, Int. J. of Thermophysics, Vol. 5, No. 1, (2000), 367-371.
  • [9] ASSAEL M.J., DALAOUTI N.K., DYMOND J.H., FELEKI E.P.: Correlation for vis- cosity and thermal conductivity of liquid halogenated ethane refrigerants, Vol. 21, No. 2, (2000), 367-376.
  • [10] DYMOND J.H.: Second virial coefficients and liquid transport properties at saturated vapour pressure of haloalkanes, Fluid Phase Equilibria, Vol. 174, No.1, (2000), 13-32.
  • [11] ASSAEL M.J., DYMOND J.H., PAPADAKI M., PATTERSON P.M.: Correlation and prediction of dense fluid transport coefficients, Fluid Phase Equilibria, Vol. 75, No.1 (1992), 245-255.
  • [12] KIHARA T., Intermolecular Forces, University of Tokyo, John Wiley & Sons, Chichster , New York, Brisbane, Toronto 1976.
  • [13] RIGBY M., SMITH E.B., WAKEHAM W.A., MAITHLAND G.C.: The Forces between Molecules, Clarendon Press, Oxford 1986.
  • [14] CHUNG T.-H., LEE L.L., STARLING K.E.: Applications of kinetic gas theories and multiparameter correlation for prediction of dillute gas viscosity and thermal coductivity, Ind. Eng. Chem. Res., Vol. 27, (1988), No. 4, 671-659.
  • [15] CHUNG T.-H., AJLAN M., LEE L.L., STARLING K.E.: Generalized multiparameter correlation for nonpolar and polar fluid transport properties, Ind. Eng. Chem. Fundam., Vol. 23, (1984), No. 1, 8-13.
  • [16] XIANG W.,H.: The new simple extended corresponding-states_principle: complex molecular transport properties in dilute gas state, Fluid Phase Equilibria, Vol. 187- 188, No.1-2, (2001), 221-231.
  • [17] HOLLAND P.M., HANLEY H.J.M.: A correlation of the viscosity and thermal conductivity data of gaseous and liquid propane, J. Phys. Chem. Ref. Data, No.8, (1979), 859-873.
  • [18] MASON E.A, MONCHICK L.: Heat conductivity of polyatomic and polar gases, J. Chem. Phys., Vol. 8, (1962), No.6, 1622-1639
  • [19] CUKROWSKI A.S.: Transport processes in gases composed of nearly spherical rotating molecules, Acta Phys. Polon., A47 (1975), 135-153.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BGPK-0638-2792
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