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Reduction of NO with methane over metal ion-exchanged mordenite

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This article presents the results of research studies on the possibilities of application of natural zeolite-mordenite for the reduction of nitrogen oxide. Various kinds of metal ions were added to the zeolite samples using the ion-exchange method. The effect of metal contents was shown for the mordenite and related to their catalytic properties. The catalytic properties of Cu-, Co-, Ni- were compared for NO reduction with methane. High nitric oxide conversions were observed for copper and cobalt-mordenite, especially in the temperature range between 400 and 500 C degree. Copper- and cobaltmordenite catalysts showed higher activities and selectivities than catalysts composed of nickel-exchanged mordenite.
Rocznik
Tom
Strony
109--119
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
Bibliografia
  • [1] Traa Y., Burger B., Weitcamp J., 1999. Zeolite-based materials for the selective catalytic reduction of NOx with hydrocarbons, Microporous and mezoporous materials 30, 3-41.
  • [2] Gao X., Yu Q., Chen L., 2003. Selective catalytic reduction of NO with methane J. Natural Gas Chem., 12 264-276.
  • [3] Lee T.J., Nam I.S., Ham S.W., Baek Y.S., Shin K.H., 2003. Effect on Pd of the wather tolerance of Co-ferrierite catalysts for NO reduction by CH4, Appl. Catal. B 4, 115-129.
  • [4] Okumara K., Kusakabe T., Niwa M., 2003. Durable and selective activity of Pd loaded on WO3/ZrO2 for NO by CH4 in the presence on water wapor, Appl. Catal. B 41, 137-153.
  • [5] Armor J.N., 1995. Catalytic reduction of nitrogen oxides with methane in the presence of excess oxygen: a review, Catal. Today 26, 147-158.
  • [6] Resini C., Montanari T., Nappi L., Bagnasco G., Turco M., Busea G., Bregani F., Notaro M., Rocchini G., 2003. Selective catalytic reduction of NOx by methane over Co-H-MFI and Co-H-FER zeolite catalysts: characterization and catalytic activity, J. Catal.,214, 179-190.
  • [7] Ren L., Zhang T., Tang J., Zhao J., Li N., Lin N., 2003. Promotional effect of coloidal alumina on the activity on the In/HZSM-5 catalyst for the selective reduction of NO with methane, Appl. Catal. B 41, 129-138.
  • [8] Wang X., Zhang T., Sun X., Guan W., Liang D., Lin L., 2000. Enhanced activity of an In-Fe2O3/HZSM-5 catalyst for NO reduction with methane, Appl. Catal. B 24, 169-183.
  • [9] Ohtsuka H., Tabata I., 2001. Roles palladium and platinum in the selective catalytic reduction of nitrogen oxide by methane on palladium-platinum loaded sulfated zirconia, Appl. Catal. B 29, 177-189.
  • [10] Makoto M., Yoshifumi H., Chikafumi Y., 1997. Reduction of nitrogen oxide by hydrocarbons catalyzed by bifunctional catalysts, Catal. Today 38, 157-162.
  • [11] Ohtsuka H., Tabata I., 2000. Palladium–platinum-loaded sulfated zirconia: a highly durable catalyst for the reduction of nitrogen oxides by methane in the presence of water vapor and SOx, Appl. Catal. B 28 L73-L76.
  • [12] Cordoba L.F., Sachtler W.M., De Correa C.M., 2005. NO reduction by CH4 over of Pd/Co-sulfated zirconia catalysts, Appl. Catal. B 56, 269-181.
  • [13] Djega-Mariadassou G., 2004. From three way to denox catalysis, Catal. Today 94, 27-34.
  • [14] Mokhnachuk O.V., Sloviev S.O., Kapran A.M., 2007. Effect of rare-earth element oxides on the structural and phisico-chemical characteristics of Pd/Al2O3 monolithic catalysts of nitrogen oxide reduction by methane, Catal. Taday 119, 145-151.
  • [15] Labhsetwar N., Minamino H., Mukherjee M., Mitsuhaski T., Rayalu S., Dhakad M., Haneda H., Subrt J., Devotta S., 2007. Journal of Molecular Catalysis A: Chemical, 261, 213-225.
  • [16] Torre-Abreu C., Henriques C., Riberio R.F., Delahay G., Riberio F., 1999. Selective catalytic reduction of NO on copper-exchanged zeolites: the role of the structure of the zeolite in the nature of copper-active sites, Catal. Today 54, 407-418.
  • [17] Kubacka A, Janas J., Wołoch E., Sulikowski B., 2005. Selective catalytic reduction of nitric oxide over zeolite catalysts in the presence of hydrocarbons and the excess of oxygen, Catal. Today 101, 139-145.
  • [18] Amiridis M.D., Zhang T., Farrauto R.J., 1996. Selective catalytic reduction of nitric oxide by hydrocarbons, Appl. Catal., 10, 203-227.
  • [19] Boix A., Mariscal R., Fierro J.L.G., 2000. The SCR of NO with methane over In,H- and Co,In,H-ZSM-5 catalysts: The promotional effect of cobalt, Catal. Lett. 68, 169-182.
  • [20] Gutierrez L., Boix A., Petunchi J., 1999. Effect on Pt on the water resistance of Co-zeolites upon the SCR of Nox with CH4, Catal. Today 54, 451-464.
  • [21] Kubacka A., Janas J., Sulikowski B., 2006. In/Co-ferrierite: A highly active catalyst for the CH4-SCR NO process under presence of steam, Applied Catal B: Environmental, 69, 43-48.
  • [22] Labhsetwar N., Minamino H., Mukherjee M., Mitsuhashi T., Rayalu S., Dhakad M., Haneda H., Subrt J., Devotta S., 2007. Journal of Molecular Catalysis A: Chemical 261, 213-227.
  • [23] Ogura M., Kage S., Shimojo T., Oba J., Hayashi M., Matsukata M., Co Cation Effects on Activity and Stability of Isolated Pd(II) Cations in Zeolite Matrices for Selective Catalytic Reduction of Nitric Oxide with Methane, Journal of catalysis, 211, 75-84.
  • [24] Pieterse J.A.Z., Van den Brink R.W., Booneveld S., De Bruijn F.A., 2003. Influence of zeolite structure on the activity and durability of Pd-Co zeolite catalysts in the reduction of NO with methane, Appl. Catal. B: Environ. 46, 239-245.
  • [25] Chen H.Y., Wang X., Sachtler W.M.H., 2000. Reduction of NOx over various Fe/zeolite catalysts, Applid Catal. A 194, 159-168.
  • [26] De Lucas A., Valverde J.L., Dorado F., Romero A., Asencio I., 2005. Influence of the ion exchanged metal (Cu, Co, Ni and Mn) on the selective catalytic reduction of NOx over mordenite and ZSM-5, Journal of Molecular Catal. A: Chemical 225, 47-58.
  • [27] Kaucky D., Vondrova A., Dedecek J., Wichterlowa B., 2000. Activity of Co ion sites ZSM-5, ferrierite and mordenite in selective catalytic reduction of NO with methane, Journal of Catal., 194, 318-329.
  • [28] Ferriera A.P., Capela S., Costa P., Henriques C., Ribeiro M.F., Ramoa R., 2007. CH4-SCR of NO over Co and Pd ferrierite catalysts: Effect of preoaration on catalytic performance, Catal. Today, 119, 156-165.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BATA-0015-0050
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