Heterogeneous catalytic oligomerization of olefin-containing fractions of hydrocarbons pyrolysis liquid products as a reasonable way of their utilization

• Autorzy: Voronchak T. , Nykulyshyn I. , Urbaniak W. , Pikh Z. , Rypka A.
• Języki publikacji: EN

Abstrakty

EN

The work is devoted to the obtaining of co-oligomers from the byproducts of ethylene production. The above products were obtained using heterogeneous acidic catalysts having the nature of silica-alumina. The specific surface area of the catalysts was defined by methylene blue adsorption method. The yields and properties of the products obtained in the presence of various catalysts were analyzed. The relationship between the structure of the catalyst and its effectiveness in the co-oligomerization process was analyzed.

Słowa kluczowe

EN

liquid pyrolysis products; catalytic oligomerization; heterogeneous catalysts; silica-alumina materials; methylene blue adsorption method

• Wydawca: Faculty of Chemical Technology and Engineering, University of Technology and Life Sciences, Bydgoszcz
• Czasopismo: Ars Separatoria Acta
• Rocznik: 2011
• Tom: No. 8
• Strony: 89--99
• Opis fizyczny: Bibliogr. 13 poz., rys., tab.

Twórcy

autor

Voronchak T.

autor

Nykulyshyn I.

autor

Urbaniak W.

autor

Pikh Z.

autor

Rypka A.

• Lviv Polytechnic National University, Lviv, Ukraine,

Bibliografia

• [1] Dumskyy Yu. V., No B.I., Butov G.M., 1999. Khimiya i tekhnologiya neftepolimernykh smol. Khimiya, Moskva.
• [2] Nykulyshyn I., Rypka A., Pich Z., Urbaniak W., 2011. „Waste management technologies for oil processing” in „Integrated waste management” T. Marcinkowski (ed.) Ed. by PZITS Poznań, Vol. I, pp. 415-425.
• [3] Varma R.S., 2002. Clay and clay-supported reagents in organic synthesis, Tetrahedron, 58, 1235-1255.
• [4] Santamaria J.C., Klein K.A., Wang Y.H., Prencke E., 2002. Specific Surface: Determination and Relevance Canadian, Geochemical Journal, 39, 233-241.
• [5] Yurkselen Y., Kaya A., 2008. Suitability of the Methylene Blue Test for Surface Area, Cation Exchange Capacity and Swell Index-Potential Determination of Clayey Soils, Engineering Geology, 102, 38-45.
• [6] Muhlenov I.P., Dobkina E.I., Deryuzhkyna V.I., Soroko V.E., 1989. Tekhnologiya katalizatorov. Khimiya, Leningrad.
• [7] Steudel A., Batenburg L.F., Fischer H.R., Weidler P.G., Emmerich K., 2009. Alteration of swelling clay minerals by acid activation, Applied Clay Science, 44, 105-115.
• [8] Pushpaletha P., Rugmini S., Lalithambika M., 2005. Correlation between surface properties and catalytic activity of clay catalysts, Applied Clay Science, 30, 141-153.
• [9] Kulprathipanja S., 2010. Zeolites in Industrial Separation and Catalysis, Wiley-VCH Verlag GmbH & Co., KGaA, Weinheim.
• [10] Niwa M., Katada N., Okumura K., 2010. Characterization and Design of Zeolite Catalysts Solid Acidity, Shape Selectivity and Loading Properties. Springer-Verlag, Berlin - Heidelberg.
• [11] Peng Y.X., Liu J.L., Cun L.F., 1996. Microstructure of polymers obtained by cationic polymerization of endo-dicyclopentadiene, J. Polym. Sci., Vol. 34, 17, 3527-3530.
• [12] Qian Y., Dono K., Huang J., Ma H., 2001. Ring-opening metathesis polymerization of dicyclopentadiene catalyzed by titanium tetrachloride adduct complexes with oxygen-containing ligands, J. Appl. Polym. Sci. Vol. 81, 3, 662-666.
• [13] Schaubroeck D., Brughmans S., Vercaemst C., Schaubroeck J., Verpoort F., 2006. Qualitative FT-Raman investigation of the ring opening metathesis polymerization of dicyclopentadiene, Journal of Molecular Catalysis A: Chemical, 254, 180-185.