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Proton - ionizable lariat ethers in ion flotation process - effect of alkali metal cations

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Języki publikacji
EN
Abstrakty
EN
An experimental investigation is presented on flotation of Cs+, Sr2+ and Ba2+ cation metals from dilute aqueous solutions using lariat ethers with a novel protonionizable group in the presence of foaming agent. The influence of concentration of Li+, Na+, K+ (as source of foreign cations) on kinetic rate constant and maximal percent removal was studied. The addition of Li+, Na+, K+ cations (over 1.0ź10-3 mol/dm3) depressed the removal of Cs+, Sr2+ and Ba2+ remarkably, and the removal of floated cations was very low (at the concentration of alkali metal cations – 1.0ź10-2 mol/dm3). The influence of foreign cations on flotation depression increases in the order: K+ < Li+ < Na+. Authors propose the correlation between the maximal percent removal of Cs+, Sr2+ or Ba2+ and concentration of Li+, Na+ or K+ cations in aqueous solution.
Słowa kluczowe
Rocznik
Tom
Strony
53--60
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
autor
  • Department of Metal Extraction and Recirculation, Częstochowa University of Technology, 42-200 Częstochowa, Armii Krajowej 19, Poland, ulewicz@mim.pcz.czest.pl
Bibliografia
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  • [12] Bond H., Dietz M.L., Rogers R.D., 1999. Metal-Ion Separation and Preconcentration, Progress and Opportunities, ACS Symposium Series 716, Washington, DC.
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  • [15] Ulewicz M., Lesinska U., Bochenska M., Walkowiak W., 2007. Facilitated transport of Zn(II), Cd(II) and Pb(II) ions through polymer inclusion membranes with calix[4]-crown-6 derivatives, Sep. Purif. Technol. 54, 299-306.
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  • [18] Robak W., Apostoluk W., Maciejewski P., 2006. Analysis of liquid-liquid distribution constants of nonionizable crown ethers and their derivatives, P. Anal. Chim. Acta 569, 119-131.
  • [19] Walkowiak W., Kang S.I., Stewart L.E., Ndip G., Bartsch R.A., 1990. Effect of structural variations within lipophilic dibenzocrown ether carboxylic acids on the selectivity and efficiency of competitive alkali metal cation solvent extraction into chloroform Anal. Chem. 62, 2018-2020.
  • [20] Talanova G.G., Elkarim N.S.A., Hanes J.R.R.E., Hwang H.S., Rogers R.D., Bartsch R.A., 1999. Extraction selectivities of crown ethers for alkali metal cations: differences between single species and competitive solvent extractions, Anal. Chem. 71, 672-677.
  • [21] Deng Y., Sachleben R.A., Moyer B.A., 1995. Equilibrium and ring size aspects of the extraction of CsNO3 by Dicyclohexano-21-crown-7, Dibenzo-21-crown-7, and Bis-[tert-alkylbenzo]21-crown-7, J. Chem. Soc., Faraday Trans. 91, 4215-4222.
  • [22] Koide Y., Terasaki H., Sato S., Shosenji H., Yamada K., Bull K., 1996. Flotation of uranium from seawater with phosphate esters of C-undecylcalix[4]resorcinarene, Chem. Soc. Jpn. 69, 785-790.
  • [23] Koide Y., Oka T., Imamura A., Shosenji H., Yamada K., Bull K., 1993. Studies of collectors. XIII. The flotation of cesium ion with resorcinol-type calix[4]arenes with alkyl side chains, Chem. Soc. Jpn. 66, 2137-2132.
  • [24] Schulz C., Warr G.G., 1998. Selective flotation of ions by macrocyclic complexation Ind. Eng. Chem. Res. 37, 2807-2809.
  • [25] Charewicz W., Grabowska J., Bartsch R.A., 2001. Flotation of Co(II), Sr(II), and Cs(I) cations with proton-ionizable lariat ethers, Sep. Sci. Technol. 36, 1479-1494.
  • [26] Ulewicz M., Walkowiak W., Jang Y., Kim J.S., Bartsch R.A., 2003. Ion flotation of cadmium(II) and zinc(II) in the presence of proton-ionizable lariat ethers, Anal. Chem. 75, 2276-2279.
  • [27] Ulewicz M., Walkowiak W., Bartsch R.A., 2006. Ion Flotation of Zinc(II) and Cadmium(II) with Proton-Ionizable Lariat Ethers – The effect of Cavity Size, Sep. Purif. Technol. 48, 264-269.
  • [28] Maciejewski P., Walkowiak W., 2004. Selective removal of cesium(I), strontium(II) and barium(II) cations with proton-ionizable lariat ethers in the ion flotation process, Physicochem. Probl. Mineral Process. 38, 139-146.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BATA-0011-0034
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