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Tytuł artykułu

Preparation of carbonaceous heavy metal adsorbent from palm shell using sulfur impregnation

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
We attempt to prepare a heavy metal adsorbent from palm shell with a simple-two step process using pyrolysis and sulfur impregnation. Palm shell was pyrolyzed with three different methods; rapid pyrolysis, slow pyrolysis, and KOH pyrolysis, and the prepared char with high specific surface area was sulfurized with H2S impregnation to obtain the sulfur-impregnated char with the adsorption ability of heavy metals. The pyrolysis char with high specific surface area can be obtained by KOH pyrolysis, which was pre-treated with KOH solution before slow pyrolysis, and can added sulfur into KOH pyrolysis char using H2S gas. The sulfur content of sulfur-impregnated char increased with increasing the time of H2S treatment, and increased the adsorption amount of Pb2+ from aqueous solution. The sulfur impregnated char was more effective for Pb2+ and Zn2+ adsorption than commercial charcoal.
Rocznik
Tom
Strony
88--98
Opis fizyczny
Bibliogr. 19 poz., rys., tab.
Twórcy
autor
autor
autor
autor
  • Department of Materials-process Engineering and Applied Chemistry for Environments, Faculty of Engineering and Resource Science, Akita University, 1-1, Tegata-Gakuen cho, Akita 010-8502, Japan, wajima@gipc.akita-u.ac.jp
Bibliografia
  • [1] Kagaku Kougaku Binran (5th Ed.), Maruzen, Tokyo, 1978, p.1325.
  • [2] Y. Sanada, M. Suzuki, K. Fujita, Kasseitan-Kiso to Ouyou,Koudansha, Tokyo, 1992.
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  • [8] J. Hayashi, A. Kazehaya, K. Muroyama, A.P. Watkinson, Carbon, 2000, 32, 1873-1878.
  • [9] J. Guo, A. C. Lua, Mater. Lett., 2000, 55, 334-339.
  • [10] J. Guo, A. C. Lua, J. Colloid Interface Sci., 2002, 254, 227-233.
  • [11] J. Guo, A. C. Lua, Mater.Chem. Phys., 2003, 80, 114-119.
  • [12] N. Adhoum, L. Monser, Chem. Eng. Process., 2002, 41, 17-21.
  • [13] P.N. Cheremisinoff, F. Ellerbusch, Carbon Adsorption Handbook, Ann Arbor Science, Arbor 1980
  • [14] R. G. Pearson, J. Am. Chem.Soc., 1963, 85, 3533-3539.
  • [15] R. G. Pearson, J. Chem. Educ., 1987, 64, 561-567.
  • [16] T. Sugawara, K. Sugawara, Y. Nishiyama, M. A. Sholes Fuel, 1991, 70, 1091-1097.
  • [17] R.C. Bansal, J.B. Donnet, F. Stoeckli, Active Carbon, Marcel Dekker, New York 1992.
  • [18] J. Guo, Y. Luo. A.C. Lua, R. Chi, Y. Chen, X. Bao, S. Xiang, Carbon, 2007, 45, 330-336.
  • [19] A. Macías-Garacía, C. Valenzuela-Calahorro, V. Gómez-Serrano, A. Espínosa-Mansilla, Carbon, 1993, 31, 1249-1255.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BATA-0007-0053
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