Adsorption of rare earth metal ions on novel tripodal broom methylcarbamoylmethoxy-acetic acid impregnated resin

• Autorzy: Ohto K. , Oshima T. , Inoue K.
• Języki publikacji: EN

Abstrakty

EN

The novel broom methylcarbamoylmethoxy-acetic acid impregnated resin has been prepared to investigate the adsorption behavior of nine rare earth metals. The present resin demonstrates adsorption ability for rare earth metal ions. The selectivity order for rare earth series is as follows: Ho>Er>Gd>Y>Eu> Sm>>Nd>Pr>>La. This order is different from those of general carboxylic acid extractants. Maximum adsorption capacity of holmium is found to be 0.21 mol kg-1. From the comparison of the reagent amount impregnated in the resin and the maximum adsorption capacity, the adsorption stoichiometry is found to be 1:2 (Ho : reagent).

Słowa kluczowe

EN

tripodal broom compound; impregnated resin; adsorption; rare earth metals; methylcarbamoylmethoxy-acetic acid

• Wydawca: Faculty of Chemical Technology and Engineering, University of Technology and Life Sciences, Bydgoszcz
• Czasopismo: Ars Separatoria Acta
• Rocznik: 2006
• Tom: No. 4
• Strony: 27--36
• Opis fizyczny: Bibliogr. 19 poz., rys., tab.

Twórcy

autor

Ohto K.

autor

Oshima T.

autor

Inoue K.

• Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, 1-Honjo, Saga 840-8502, Japan,

Bibliografia

• [1] E. Shchori, J.J. Grodzinski, J. Appl. Polym. Sci., 1976, 20 (3), 773-788.
• [2] M. Cinouini, S. Colonna, H. Molinari, F. Montanari, P. Tundo, J. Chem. Soc., Chem. Commun., 1976, (11), 394-396.
• [3] K. Ohto, Y. Senba, N. Eguchi, T. Shinohara, K. Inoue, Solv. Extr. Res. Dev., Jpn., 1999, 6, 101-112.
• [4] Y. Wakui, H. Matsunaga, T.M. Suzuki, Anal. Sci., 1988, 4, 325.
• [5] J. Shibata, S. Matsumoto, H. Yamamoto, Solv. Extr. Res. Dev., Jpn., 2000, 7, 167-175.
• [6] W.J. Kasowski, J.C. Bailar, Jr., J. Am.Chem, Soc., 1969, 91, 3212-3218.
• [7] R. McCrindle, A.J. McAless, J. Chem. Soc., Perkin, 1981, 741-745.
• [8] R. Viguier, G. Serratrice, A. Dupraz, C. Duppy, Eur. J. Inorg. Chem., 2001, 1789-1795.
• [9] R. Kataky, D. Parker, A. Teasdale, Anal. Chim. Acta, 1993, 276, 353-360.
• [10] H.J. Lu, Y.T. Fan, Y.J. Wu, M.C. Yin, Polyhedron, 2001, 20, 3281-3286.
• [11] M.M. Meijler, R.A. Yellin, Z. loav Cabantchik, A. Shanzer, J. Am. Chem. Soc., 2002, 124, 12666-12667.
• [12] J.S. Li, Y.Y. Chen, X.R. Lu, Eur. J. Org. Chem., 2000, 485-490.
• [13] M.M. Reinoso-Garcia, A. Dijkman, W. Verboom, D.N. Reinhoudt, E. Malinowska, D. Wojciechowska, M. Pietrzak, P. Selucky, Eur. J. Org. Chem., 2005, 2131-2138.
• [14] G. Zuijun, N. Yanning, Z. Weiguang, T. Minyu, J. Radioanal. Nucl. Chem., 2003, 262(2), 331-337.
• [15] K. Ohto, H. Nakagawa, H. Furutsuka, T. Shinohara, T. Nakamura, T. Oshima, K. Inoue, Solv. Extr. Res. Dev., Jpn., 2004, 11, 121-134.
• [16] O.C. Demer, P.W. Solomon, J. Am. Chem. Soc., 1954, 76, 1697-1699.
• [17] E.B. Fleischer, A.E. Gebala, A. Levey, P.A. Tasker, J. Org. Chem., 1971, 36, 3042-3044.
• [18] J.W. Lee, J.Y. Lu, P.S. Low, P.L. Fuchs, Bioorg. Med. Chem., 2002, 10, 2397-2414.
• [19] A.C. du Preez, J.S. Preston, Solv. Extr. Ion. Exch., 1992, 10 (2), 207-230.