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Determination of Ignition Sensitivity of Selected Heat Powders

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EN
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EN
Ignition sensitivity is one of the factors defning the characteristics of high calorifc mixture with low emission of gaseous product. It was found that Zr-BaCrO4 mixture is sensitive to ignition by electric spark energy of 0.82 J, whereas activation of Fe-KClO4 mixture depends on the iron powder employed and the composition of its surface oxide layers. Energy required for the activation of high calorifc mixture in form of powder designated as FeK, FeR or FeE is equal to 0.08, 0.59 and 1.1 J, while in the form of pellet 6.92, 10.2 and 14.1 J. Activation of Fe-KClO4 mixture with a strip of heat paper as well as with the electric spark has revealed that the mixture containing iron powder obtained by atomization method (FeA) is not active.
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3--13
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Bibliogr. 15 poz.
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Bibliografia
  • [1] Gillard Ph., Laser Diode Ignition of Pyrotechnic Mixture: Experimental and Numerical Studies, J. Pyrotechnics, 2007, 26, 53-59.
  • [2] Strnad J., Majzlik J., Determination of Electrostatic Spark Sensitivity of Energetic Materials, 4th Seminar “New Trends in Research of Energetic Materials”, University of Pardubice, 2001, Vol. I, 303-307.
  • [3] Opdebeck F., Gillard Ph., Radenac E., Influence of Interface Conditions on Laser Diode Ignitron of Pyrotechnic Mixtures: Application to the Design of an Ignitron Device, Inter. J. Thermal Sci., 2003, 42, 47-56.
  • [4] Strnad J., Majzlik J., Methodology of Test of Sensitivity of Energetic Materials to Electrostatic Discharge, 6th Seminar “New Trends in Research of Energetic Materials”, University of Pardubice, 2003, Vol. I, 212-220.
  • [5] PN-EN 13938-2, Materiały wybuchowe do użytku cywilnego. Materiały miotające i paliwa rakietowe, Cz. 2: Oznaczanie odporności na energię elektrostatyczną. (Explosives for civil uses. Propellants and rocket propellants, Part 2: Determination of resistance to electrostatic energy.)
  • [6] NATO Standardization Agreement STANAG 4490, Explosives, Electrostatic Discharge Sensitivity Test (S).
  • [7] Styczyński S., Czajka B., Sołopa W., Rydzyńska B., Ciszewski A., The Effect of Heating Medium on Electric Parameters of a Thermal Battery with the Electrochemical System Li/LiCl-KCl-RbCl-LiF/FeS2, Pol. J. Chem. Technol., 2006, 8, 80-82.
  • [8] Czajka B., Wachowski L., Łapiński A., Zieliński M., Oxides Layer Study onto Fine-grained Iron Powders, 11th Seminar “New Trends in Research of Energetic Materials”, University of Pardubice, 2008, Vol. II, 485-493.
  • [9] Czajka B., Wachowski L., Zieliński M., Some Properties of the Iron Powders Applied in High Energetic Materials, Oxid. Comm., 2007, 30, 153-164.
  • [10] Czajka B., Tabat S., Styczyński S., Wachowski L., Zieliński M., Pietrowski M., Physicochemical Properties of Iron Powders Used as Reducing Agents in Materials of High Calorific Value, Cent. Eur. J. Energ. Mater, 2004, 1, 75-83.
  • [11] Wachowski L., Czajka B., Textural and Catalytic Properties of the FexOy/Fe-KClO4 System, Thermochim. Acta, 2005, 435, 102-107.
  • [12] Czajka B., Wachowski L., Some Thermochemical Properties of High Calorific Mixture of Fe-KClO4, Cent. Eur. J. Energ. Mater., 2005, 2, 55-68.
  • [13] Agrawal J.P., High Energy Materials Propellants, Explosives, Pyrotechnics, Wiley-VCH Verlag GmbH&Co.KGaA, Weinheim 2010, p. 188, 381.
  • [14] Klasons V., Lamb Ch.M., Thermal Batteries, in: Handbook of Batteries, (David Linden and Thomas B. Reddy, Eds.), McGraw-Hill, Chicago 2002.
  • [15] Kuwahara T., Kohno T., Wang C.H., Static Electric Sensitivity Characteristics of Zr/BaCrO4 Pyrolants, Propellants, Explos., Pyrotech., 2004, 24, 56-62.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT6-0014-0013
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