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5-Aminotetrazoles and Silver-based Primary Explosives

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Several silver nitrate and perchlorate salts with 5-aminotetrazole-based ligands have been synthesized and characterized by elemental analysis, mass spectrometry, IR, Raman and multinuclear NMR spectroscopy. In addition, several of the new compounds were characterized by X-ray structure analysis. The energetic properties of the materials were assessed by differential scanning calorimetry (DSC) analysis in combination with standard impact and friction BAM tests. The compounds synthesized have good thermal stabilities above 225 C and in some instances the high sensitivities of the materials towards impact and friction make them fall under the category of primary explosives. Some of the compounds might present prospective use in initiation devices for civil and military applications.
Słowa kluczowe
Rocznik
Strony
197--216
Opis fizyczny
Bibliogr. 21 poz.
Twórcy
autor
  • Laboratoire Hydrazines et Procédés, UMR 5179 CNRS-UCBL, Université Claude Bernard Lyon 1, Batiment Berthollet, 22 Av. Gaston Berger, F-69622 Villeurbanne Cedex, France, carlos.miro-sabate@univ-lyon1.fr
Bibliografia
  • [1] a) Fedoroff B.T., Sheffield O.E., Encyclopedia of Explosives and Related Items, Vol. 7, Dover NJ, Picatinny Arsenal, 1978, I105; b) Huynh M.H.V., Hiskey M.A., Meyer T.J., Wetzler M., Green primaries: environmentally friendly energetic complexes, Proc. Natl. Acad. Sci. U.S.A., 2006, 103, 5409-5412.
  • [2] Huynh M.H.V., Coburn M.D., Meyer T.J., Wetzler M., Green Primary Explosives: 5-Nitrotetrazolato-N2-ferrate Hierarchies, Proc. Natl. Acad. Sci. U.S.A., 2006, 103(27), 10322-10327.
  • [3] Klapötke T.M., Miró Sabaté C., Welch J.M., Alkali Metal 5-Nitrotetrazolate Salts: Prospective Replacements for Service Lead(II)azide in Explosive Initiators, Dalton Trans., 2008, 6372-6380.
  • [4] Karaghiosoff K., Klapötke T.M., Mayer P., Miró Sabaté C., Penger A., Welch J.M., Salts of Methylated 5-Aminotetrazoles with Energetic Anions, Inorg. Chem., 2008, 47, 1007-1019.
  • [5] Klapötke T.M., Miró Sabaté C., Penger A., Rusan M., Welch J.M., Energetic Salts of Low Symmetry Methylated 5-Aminotetrazoles, Eur. J. Inorg. Chem., 2009, 880-896.
  • [6] Smirnov A.V., Ilyushin M.A., Tselinsky I.V., 3rd Autumn Sem. Propell. Explos. Pyrotech., Chengdu, China, October 5th-8th, 1999, 5-9.
  • [7] a) Konkova T.S., Matyushin Y.N., Vorobev A., Sinditskii V.P., Dutov M.D., Fogelzang A.E., 36th Int. Ann. Conf. ICT − Energ. Mater., 2005, 93, 1-13; b) Konkova T.S., Matyushin Y.N., Vorobev A.B., Sinditskii V.P., Dutov M.D., 35th Int. Ann. Conf. ICT − Energ. Mater., 2004, 96, 1-13.
  • [8] Zhou X., Jpn. Kokai Tokkyo Koho, JP 2000297078, 2000.
  • [9] a) Kizhnyaev V.N., Kruglova V.A., Complexation of Vinyltetrazoles and Their Polymers with Metal(II) Chlorides, Zh. Prikl. Khim., 1992, 65, 1879-1884; b) Sorenson J.R.J., Copper Chelates as Possible Active Forms of the Antiarthritic Agents, J. Med. Chem., 1976, 19, 135-148.
  • [10] Henry R.A., Finnegan W.G., Lieber E., 1,4-Dialkyl-5-iminotetrazoles, J. Am. Chem. Soc., 1954, 76, 2894-2898.
  • [11] Rittenhause C.T., Bi-Silver Aminotetrazole Perchlorate, US 3663553, 1972.
  • [12] a) Williamson K., Li P., Devlin J.P., Vibrational Spectra and Structures of Ionic Liquids. II. The Pure Alkali Metal Nitrates, J. Chem. Phys., 1968, 48, 3891-3896; b) Fernandes J.R., Ganguly S., Rao C.N.R., Infrared Spectroscopic Study of the Phase Transitions in Cesium Nitrate, Rubidium Nitrate and Ammonium Nitrate, Spectrochim. Acta A, 1979, 35, 1013-1020.
  • [13] a) Cohn H., Infrared Spectrum of Crystalline Potassium Perchlorate. Reassignment of the Lower Fundamental Frequencies of the Perchlorate Ion, J. Chem. Soc., 1952, 4282-4284; b) Redlich O., Holt E.K., Biegeleisen J., The Ionization of Strong Electrolytes. II. Ionizations, Raman Spectrum and Vibrations of HClO4, J. Am. Chem. Soc., 1944, 66, 13-16.
  • [14] von Denffer M., Klapötke T.M., Kramer G., Spieß G., Welch J.M., Heeb G., Improved Synthesis and X-Ray Structure of 5-Aminotetrazolium Nitrate, Propellants, Explos., Pyrotech., 2005, 30, 191-195.
  • [15] Klapötke T.M., Miró Sabaté C., Stierstorfer J., Hydrogen-bonding Stabilization in Energetic Perchlorate Salts: 5-Amino-1H-tetrazolium Perchlorate and its Adduct with 5-Amino-1H-tetrazole, Z. Anorg. Allg. Chem., 2008, 11, 1867-1874.
  • [16] Sheldrick G.M., Programs for Crystal Structure Analysis (Release 97– 2), University of Göttingen, Göttingen (Germany), 1998.
  • [17] Altomare A., Burla M. C., Camalli M., Cascarano G.L., Giacovazzo C., Guagliardi A., Moliterni A.G.G., Polidori G, Spagna R., SIR97: a New Tool for Crystal Structure Determination and Refinement, J. Appl. Crystallogr., 1999, 32, 115-119.
  • [18] Köhler J., Meyer R., Explosivstoffe, 9th ed., Wiley-VCH, Weinheim, Germany, 1998.
  • [19] Impact: Insensitive > 40 J, less sensitive = 35 J, sensitive = 4 J, very sensitive = 3 J; friction: Insensitive > 360 N, less sensitive = 360 N, sensitive < 360 N a.> 80 N, very sensitive = 80 N, extremely sensitive = 10 N. According to the UN Recommendations on the Transport of Dangerous Goods (+) indicates not safe for transport.
  • [20] http://www.bam.de.
  • [21] Klapötke T.M., Rienäcker C.M., Drophammer Test Investigations on Some Inorganic and Organic Azides, Propellants, Explos., Pyrotech., 2001, 26, 43-47
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT6-0014-0002
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