The study of photocatalytic degradation of sulfonamides applied to municipal wastewater

• Autorzy: Ziemiańska J. , Adamek E. , Sobczak A. , Lipska L. , Makowski A. , Baran W.
• Języki publikacji: EN

Abstrakty

EN

A photocatalytic process of degradation of the selected sulfonamides (sulfathiazole, sulfamethoxazole and sulfadiazine) added to real wastewater was studied in this work. The process was initiated by UV-a irradiation and TiO2-P25, FeCl3 and mixtures of TiO2-P25 with FeCl3 were used as photocatalysts. The effect of pre-treatment of wastewater and the influence of process parameters on the efficiency of sulfonamides removal were also determined. It was found that the highest efficiency of degradation was achieved in the process carried out in the presence of TiO2-P25/FeCl3 mixture, in full scale effluent wastewater treatment plant..

Słowa kluczowe

EN

sulfonamides; photocatalysis; wastewater treatment; TiO2; FeCl3

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2010
• Tom: Vol. 45
• Strony: 127--140
• Opis fizyczny: Bibliogr. 32 poz.

Twórcy

autor

Ziemiańska J.

autor

Adamek E.

autor

Sobczak A.

autor

Lipska L.

autor

Makowski A.

autor

Baran W.

• Medical University of Silesia, Faculty of Pharmacy Chemistry, 4 Jagiellońska Str.,41-200 Sosnowiec,

Bibliografia

• [1] KÜMMERER K. ed., Pharmaceuticals in the environment. Sources, fate, effects and risks. Heidelberg: Springer-Verlag 2001.
• [2] TERNES T.A. (project co-ordinator), JANEX-HABIBI M.L., KNACKER T., KREUZINGER N., SIEGRIST H., 2004, Assesment of Technologies for the Removal of Pharmaceuticals and Personal Care Products in Sewage and Drinking Water Facilities to Improve the Indirect Potable Water Reuse. Project POSEIDON, Contract No. EVK1-CT-2000-00047,
• [3] Eintrag von Arzneimitteln und deren Verhalten und Verbleib in der Umwelt Literaturstudie Fachbericht 2, Landesamt für Natur, Umwelt und Verbraucherschutz Nordrhein-Westfalen, Recklinghausen 2007.
• [4] Environmentally Classified Pharmaceuticals 2009, Stockholm County Council, http://www.janusinfo.org/imcms/servlet/GetDoc?meta_id=10205
• [5] SUKUL P., SPITTELER M., 2006, Sulfonamides in the environment as veterinary drugs, Environ. Contam. Toxicol., 187, 67-101.
• [6] KÜMMERER K., 2009, Antibiotics in the aquatic environment – A review – Part I, Chemosphere,75, 417-434.
• [7] KOT-WASIK A., DĘBSKA A., NAMIEŚNIK J., Przemiany, stężenia i oznaczanie pozostałości środków farmaceutycznych w środowisku: Nowe horyzonty i wyzwania w analityce i monitoringu środowiskowym (34), Gdańsk: CEEAM 2003.
• [8] Knowledge and Need Assessment on Pharmaceutical Products in Environmental Waters, 2007, Project acronym: KNAPPE, Proposal N° 036864.
• [9] SARMAH A.K., MEYER M.T., BOXALL A.B.A., 2006, A global perspective on the use, sales, exposure pathways, occurrence, fate and effects of veterinary antibiotics (Vas) in the environment, Chemosphere, 65, 725–759.
• [10] KEMPER N., 2008, Veterinary antibiotics in the aquatic and terrestrial environment, Ecol. Ind., 8, 1–13.
• [11] BATT A.L., KIM S., AGA D.S., 2007, Comparison of the occurrence of antibiotics in four fullscale wastewater treatment plants with varying designs and operations, Chemosphere, 68, 428-435.
• [12] TURKDOGAN F.I., YETILMEZSOY K., 2009, Appraisal of potential environmental risks associated with human antibiotic consumption in Turkey, J. Hazard. Mater., 166, 297–308.
• [13] KLAVARIOTI M., MANTZAVINOS D., KASSINOS D., 2009, Removal of residua pharmaceuticals from aqueous systems by advanced oxidation processes. Environ. Int. 35, 402–417.
• [14] BELTRAN F.J., AGUINACO A., GARCIA-ARAYA J.F., OROPESA A., 2009, Ozone and photocatalytic processes to remove the antibiotic sulfamethoxazole from water, Water Res., 43, 1359-1369.
• [15] KANIOU S., PITARAKIS K., BARLAGIANNI I., POULIOS I., 2005, Photocatalytic oxidation of sulfamethazine, Chemosphere, 60, 372–380.
• [16] HU L., FLANDERS P.M., MILLER P.L., STRATHMANN T.J., 2007, Oxidation of Sulfamethoxazole and Related Antimicrobial Agents by TiO2 Photocatalysis., Water Res., 41, 2612 – 2626.
• [17] CALZA P., MEDANA C., M. PAZZI, BAIOCCHI C., PELIZZETTI E., 2004, Photocatalytic transformation of sulphonamides on titanium dioxide, App. Catal. B-Environ., 53, 63-69.
• [18] ABELLAN M.N., GIMENEZ J., ESPLUGAS S., 2009, Photocatalytic degradation of antibiotics: The case of sulfamethoxazole and trimethoprim, Catal. Today 144, 131–136.
• [19] BARAN W., ADAMEK E., SOBCZAK A., SOCHACKA J., 2009, The comparison of photocatalytic activity of Fe-salts, TiO2 and TiO2/FeCl3 during the sulfanilamide degradation process. Catal. Comm., 10, 811-814.
• [20] BARAN W., ADAMEK E., SOBCZAK A., MAKOWSKI A., 2009, Photocatalytic degradation of sulfa drugs with TiO2, Fe salts and TiO2/FeCl3 in aquatic environment—Kinetics and degradation pathway, Appl. Catal. B: Environ., 90, 516-525.
• [21] BARAN W., SOCHACKA J., WARDAS W., 2006, Toxicity and biodegradability of sulfonamides and products of their photocatalytic degradation in aqueous solutions, Chemosphere, 65, 1295-1299.
• [22] ADAMEK E., BARAN W., SOBCZAK A., MAKOWSKI A., 2009, The photocatalytic decoloration of wastewater containing azo-dyes. – Pol. J. Environ. Stud., 18-2B, 80-82.
• [23] WU F., DENG N., 2000, Photochemistry of hydrolytic iron (III) species and photoinduced degradation of organic compounds. A minireview, Chemosphere 40, 389-394.
• [24] CATASTINI C., SARAKHA M., MAILHOT G., BOLTE M., 2002, Iron (III) aquacomplexes as effective photocatalysts for the degradation of pesticides in homogeneous aqueous solutions, Sci. Total Environ., 298, 219-228.
• [25] ANDREOZZI R., CANTERINO M., MAROTTA R., 2006, Fe(III) homogeneous photocatalysis for the removal of 1,2-dichlorobenzene in aqueous solution by means UV lamp and solar light, Water Res., 40, 3785 – 3792.
• [26] MESTANKOVA H., MAILHOT G., JIRKOVSKY J., KRYSA J., BOLTE M., 2005, Mechanistic approach of the combined (iron–TiO2) photocatalytic system for the degradation of pollutants In aqueous solution: an attempt of rationalisation, Appl. Catal. B Environ., 57, 257–265.
• [27] BOREEN A.L., ARNOLD W.A., MC NEILL K., 2004, Photochemical fate of sulfa drugs in the aquatic environment: sulfa drugs containing five-membered heterocyclic groups, Environ. Sci. Technol., 38, 3933-3940.
• [28] BOREEN A.L., ARNOLD W.A., MC NEILL K., 2005, Triplet-sensitized photodegradation of sulfa-drugs containing six-membered heterocyclic groups: Identification of an SO2 extrusion photoproduct, Environ. Sci. Technol., 39, 3630-3638.
• [29] ISO 9887:1992(E) Water quality - Evaluation of the aerobic biodegradability of organic compounds in an aqueous medium -Semi-continuous activated sludge method (SCAS)
• [30] HATCHARD C., PARKER C., 1956, A new sensitive chemical actinometer. II. Potassium ferrioxalate as a standard chemical actinometer, Proc. Roy. Soc. A 235, 518-36.
• [31] BARAN W., MAKOWSKI A., WARDAS W., 2005, The separation of catalyst after photocatalytic reaction conducted in the presence of TiO2/FeCl3/UV, Chemosphere 59, 853-859.
• [32] FUJISHIMA A., ZANG X., TRYK D.A., 2008, TiO2 photocatalysis and related surface phenomena, Surf. Sci. Rep., 63, 515-582.