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In order to avoid large problems regarding peeling of the titania layer coated on the substrate, we developed an epoch-making "strong titania fiber" consisting of photoactive surface layer with a nanometer-scale compositional gradient, which can effectively oxidize any kind of organic materials. An effective water-purification system using this fiber has been also developed. The basis of this technology is to incorporate a selected low-molecular-mass additive (Ti(OC4H9)4) into a precursor polymer from which the ceramic forms. After melt-spinning the resulting precursor polymer, thermal treatment of the spun fiber leads to controlled phase separation ("bleed-out") of the additive; subsequent calcination stabilizes the compositionally changed surface region, generating a functional surface layer. This fiber consists of the silica-based core-structure and the gradient-like surface titania layer, which are strongly sintered. We also developed a water-purifier using this fiber (felt material). Any bacteria (common bacterium, legionera pneumophila, colon bacillus, heterotrophic bacteria, and so forth) and organic chemicals (dioxin, PCB, and so forth) were effectively decomposed into CO2 and H2O passing through the above purifier.
Słowa kluczowe
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Tom
Strony
57--71
Opis fizyczny
Bibliogr. 21 poz.
Twórcy
autor
- Inorganic Specialty Products Research Laboratory, Ube Industries, Ltd., 1978-5 Kogushi, Ube City, Yamaguchi Prefecture, 755-8633, Japan, 24613u@ube-ind.co.jp
Bibliografia
- [1] S. YAJIMA, Y. HASEGAWA, K. OKAMURA, T. MATSUZAWA, “Development of High Tensile Strength Silicon Carbide Fiber Using an Organosilicon Polymer Precursor”, Nature, 273, 525-527 (1978).
- [2] M. TAKEDA, J. SAKAMOTO, A. SAEKI, Y. IMAI, and H. ICHIKAWA, “High Performance Silicon Carbide Fiber Hi-Nicalon for Ceramic Matrix Composites”, Ceram.Eng.Sci.Proc., 16[4], 37-44 (1995).
- [3] T. ISHIKAWA, Y. KOHTOKU, K. KUMAGAWA, T. YAMAMURA & T. NAGASAWA, “High-Strength Alkali-Resistant Sintered SiC Fibre Stable to 2200 oC”, Nature, 391, 773-775 (1998).
- [4] J. LIPOWITZ, J. A. RABE, G. A. ZANK, A. ZANGVIL, Y. XU, “Structure and Prooperties of Sylramic TM Silicon Carbide Fiber – A Polycrystalline, Stoichiometric SiC Composition”, Ceram.Eng.Sci.Proc., 18[3], 147-157 (1997).
- [5] T. ISHIKAWA, S. KAJII, K. MATSUNAGA, T. HOGAMI, Y. KOHTOKU & T. NAGASAWA, “A Tough, Thermally Conductive Silicon Carbide Composite with High Strength up to 1600 0C In Air”, Science, 282, 1295-1297 (1998).
- [6] T. ISHIKAWA, H. YAMAOKA, Y. HARADA, T. FUJII, T. NAGASAWA, “A general process for in situ formation of functional surface layers on ceramics”, Nature, 416, 64-67 (2002).
- [7] T. ISHIKAWA, Y. HARADA, H. HAYASHI, S. KAJII, “Silica-Group Composite Oxide Fiber and Process for the Production”, US Patent 6,541,416 B2 (Foreign Application Priority Date: June 13, 2000).
- [8] I. SOPYAN, S. MURASAWA, K. HASHIMOTO, and A. FUJISHIMA, “Highly Efficient TiO2 Film Photocatalyst, Degradation of Acetaldehyde”, Chemistry Letters (The Chemical Society of Japan), pp.723-726 (1994).
- [9] T. ISHIKAWA, “Ceramic Fiber with Decomposition Ability of Dioxine”, Miraizairyo, 3(2), 26-33 (2003).
- [10] H. KOIKE, Y. OKI, and Y. TAKEUCHI, Mater.Res.Soc.Sym.Proc., 549, 141 (1999).
- [11] A. MATSUDA, Y. KOTANI, T. KOGURE, M. TATSUMISAGO, T. MINAMI, “Transparent Anatase Nanocomposite Films by the Sol-Gel Process at Low Temperatures”, J.Am.Ceram.Soc., 83[1], 229-231 (2000).
- [12] D. R. PARK, J. ZHANG, K. IKEUE, H. YAMASHITA, M. ANPO, “Photocatalytic Oxidation of Ethylene to CO2 and H2O on Ultrafine TiO2 Photocatalysts in the Presence of O2 and H2O”, J.Catal., 185, 114-119 (1999).
- [13] T. ISHIKAWA, “Photocatalytic Fiber with Gradient Surface Produced from a Polycarbosilane and its Applications”, International Journal of Applied Ceramic Technology, 1[1], 49-55 (2004).
- [14] T. ISHIKAWA, “Advances in Inorganic Fibers”, Adv. Polym. Sci., 178, 109-144 (2005).
- [15] N. TAKEDA, M. OHTANI, T. TORIMOTO, S. KUWABATA, H. YONEYAMA, “Evaluation of Diffusibility of Adsorbed Propionaldehyde on Titanium Dioxide-Loaded Adsorbent Photocatalyst Films from Its Photocomposition Rate”, J.Phys.Chem.B, 101, 2644-2649 (1997).
- [16] C. K. CHAN, J. F. PORTER, Y. G. LI, W. GUO, C. M. CHAN, “Effects of Calcination on the Microstructures and Photocatalytic Properties of Nanosized Titanium Dioxide Powders Prepared by Vapor Hydrolysis”, J.Am.Ceram.Soc., 82[3], 566-572 (1999).
- [17] H. KOIKE, Y. OKI, Y. TAKEUCHI, “Preparing Titania fibers and their Photo-catalytic Activity”, Mater.Res.soc.Sym.Proc., 549, 141-146 (1999).
- [18] T. GUNJI, I. SOPYAN, Y. ABE, “Synthesis of Polytitanosiloxanes and their Transformation to SiO2-TiO2 Ceramic Fibers”, J.Polym.Sci., Part A Polym.Chem., 32, 3133-3139 (1991).
- [19] T. ISHIKAWA, “Photocatalytic Fiber with Gradient Surface Structure Produced from a Polycarbosilane and Its Application”, Int.J.Appl.Chem.Technol., 1[1], 49-55 (2004).
- [20] P. I. GOUMA, P. K. DUTTA, M. J. MILLS, “Structural Stability of Titania Thin Films”, Nano Structured Materials, 11(8), 1231-1237 (1999).
- [21] C. ANDERSON, A. J. BARD, “Improved Photocatalytic Activity and Characterization of Mixed TiO2/SiO2 and TiO2/Al2O3”, J.Phys.Chem.B, 101, 2611-2616 (1997).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT6-0013-0030