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Elektrochemiczne osadzanie gradientowych powłok stopowych Ni-P

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EN
Electrochemical deposition of Ni-P alloy gradient coatings
Języki publikacji
PL
Abstrakty
PL
W artykule przedstawiono wyniki badań mających na celu optymalizację warunków procesu nakładania powłok Ni-P z kąpieli o różnym składzie. Podstawowymi parametrami wpływającymi na przebieg procesu były: zawartość soli niklu, gęstość prądu katodowego, temperatura i pH kąpieli, mieszanie roztworu (500 obr/ min) lub brak mieszania oraz zawartość dodatków. Badano wpływ tych czynników na wydajność procesu elektroosadzania i jakość uzyskanych powłok. Wyselekcjonowane kąpiele wykorzystano do nakładania gradientowych powłok Ni-P. Wykonano analizę chemiczną zawartości fosforu w powłokach oraz badania przyczepności, odporności korozyjnej, mikrotwardości i mikrostruktury otrzymanych powłok gradientowych.
EN
Electrodeposition of Ni-P coatings has important advantages: permits to control the plating speed and chemical composition of the deposit. Several electrolytes were investigated in order to optimize parameters of electrodeposition Ni-P alloy coatings (current density, temperature, electrolyte's pH, content of additives).The influence of these parameters on electrodeposition process efficiency and properties of obtained coatings were examined. Two electrolytes were selected for plating gradient (multilayer) coatings. The content of phosphor in Ni-P alloy was analytically evaluated. Also, the adherence, microhardness, microstructure and corrosion resistance of gradient coatings were investigated. All these parameters were the same or better than for coatings obtained during chemical deposition. After thermal treatment at 400° C the microhardness of gradient coatings increased to the level typical for chromium coatings. Ni-P gradient coatings can replace chromium finishing which is based on hazardous chemicals and has to be limited because of environment protection.
Rocznik
Strony
47--62
Opis fizyczny
Bibliogr. 24 poz., rys., wykr.
Twórcy
autor
autor
autor
Bibliografia
  • [1] Wang L., Gao Y., Xue Q., Liu H., Xu T.: A novel electrodeposited Ni-P gradient deposit for replacement of conventional hard chromium, Surf. Coat. Technol., 200, (2006), 3719-3726
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  • [3] Peeters P.: Properties of electroless and electroplated Ni-P and its application in microgalvanics, Electrochim. Ada, 47, (2001), 161-169
  • [4] Hu Ch., Bai A.: Composition control of electroplated nickel phosphorus deposits, Surf. Coat. Technol., 137, (2001), 181-187
  • [5] Brenner A.: Electrodepositon of alloys, 1, Academic Press, NY, 1963, 84
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  • [7] Morikawa T.: Electrodeposition of Ni-P alloys from Ni-citrate baths, Electrochim. Acta, 42, (1997), 115
  • [8] Zeng Y., Zhou S.: In situ surface Raman study of the phosphorus incorporation mechanism during electrodeposition of Ni-P alloys, J. Electroanal. Chem., 469, (1999), 79-83
  • [9] Harris T.M., Dang Q. D.: The mechanism of phosphorus incorporation during the electrodeposition of nickel-phosphorus alloys, J. Electrochem. Soc., 140 (1) January, 1993, 81-83
  • [10] Mehta S.C., Smith D.A., Erb U.: Study of grain growth in electrodeposited nanocrystalline nickel - 1,2 wt. % phosphorus alloy, Mater. Sci. Eng. A, 204, (1995), 227-232
  • [11] Ordine A.P.: Electrochemical study on Ni-P electrodeposition, Electrochim. Acta, 51, (2006), 1480-1486
  • [12] Lewis D.B., Marshall G.W.: Investigation into the structure of electrodeposited nickel - phosphorus alloy deposits, Surf. Coat. Technol, 78, (1996), 150-156
  • [13] Li Y.: Novel application of nanocrystalline nickel electrodeposit: making good diamond tools easily, efficiently and economically, Surf. Coat. Technol., 201, (2007), 5925-5930
  • [14] Mahalingam T.: Electrochemical deposition and characterization of Ni-P alloy thin films, Mater. Characterization, 58, (2007), 800-804
  • [15] Kobayashi S.: Effect of interphase boundary connectivity on fracture behavior of ultrafine-grained Ni-4,4 mass % P alloy, Scripta Mater., 49, (2003), 99-104
  • [16] Encyklopedia Techniki - Chemia, WNT, Warszawa 1966
  • [17] Bai A., Chuang P., Hu Ch.: The corrosion behavior of Ni-P deposits with high phosphorous contents in brine media, Mater. Chem. Phys., 82, (2003), 93-100
  • [18] Zhao Q., Liu Y: Comparisons of corrosion rates of Ni-P based composite coatings in HCl and NaCl solutions, Corrosion Sci., 47, (2005), 2807-2815
  • [19] Wang L., GaoY, Xu T, Xue Q: Corrosion resistance and lubricated sliding wear behaviour of novel Ni-P graded alloys as an alternative to hard Cr deposits, Appl. Surf. Sci., 252, (2006), 7361-7372
  • [20] PN-EN ISO 6507-1. Metale. Pomiar twardości sposobem Vickersa. Cz. 1: Metoda badań, PKN, 2007
  • [21] Hu Ch., Bai A.: Influences of the phosphorus content on physicochemical properties of nickel-phosphorus deposits, Mater. Chem. Phys., 77, (2002), 215-225
  • [22] Bai A., Hu Ch.: Effects of annealing temperatures on the physicochemical properties of nickel-phosphorus deposits, Mater. Chem. Phys., 79, (2003), 49-57
  • [23] Kobayashi S., Kashikura Y: Grain growth and mechanical properties of electrodeposited nanocrystalline nickel-4,4 mass % phosphorus alloy, Mater. Sci. Eng. A, 358, (2003), 76-83
  • [24] Jeong D.H., Erb U., Aust K.T., Palumbo G.: The relationship between hardness and abrasive wear resistance of electrodeposited nanocrystalline Ni-P coatings, Scripta Mater., 48, (2003), 1067-1072
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT5-0033-0008
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