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Abstrakty
This paper presents a theoretical approach to Li+ ions diffusion in polymeric solid electrolytes. The following parameters were calculated and then compared with the experimental results: the mobility of lithium ions, diffusion coefficient and recombination probability. Ionic conductivity of the electrolyte was also calculated.
Czasopismo
Rocznik
Tom
Strony
97--105
Opis fizyczny
Bibliogr. 9 poz., rys., wykr.
Twórcy
autor
- Bialystok Technical University Institute of Mathematics and Physics
autor
- Bialystok Technical University Institute of Mathematics and Physics
autor
- Military University of Technology Institute of Applied Physics
Bibliografia
- 1. K.C. KAO, HWANG WEI, Electrical transport in solids, Pergamon Press, New York 1984.
- 2. A. MADAM, M.P. SHAW, Amorphous semiconductors, Academic Press, New York 1991.
- 3. M. STROMME-MATTSON, G.A. NIKLASSON, G.G. GRANQVIST, Li diffiusion in Ti oxyfluoride films: thermal activation energy and jump length derived from impedance spectroscopy, J. Appl. Phys., 80, 4, 2169-2174, 1996.
- 4. O.L. ANDERSON, D.A. STUART, Calculation of activation energy of ionic conductivity in silica glasses by classical methods, J. Am. Ceram. Soc., 37, p.573, 1954.
- 5. I.K. KIKOIN [Ed.], Tablicy fizyczeskich wieliczin, Atomizdat, p. 303, Moskva 1976.
- 6. C. KITTEL, Introduction to solid state physics, PWN, p. 90, Warszawa 1999.
- 7. C.H. BAMFORD [Ed.], Chemical kinetics, Vol. 25, Amsterdam 1985.
- 8. W.M. BARTCZAK, K. WOLF, A. HUMMEL, Computer simulation of recombination of ions in multi ion-pair ensambles. I. Diffusion-controlled processes, Computer &; Chemistry, 22, 1, 71-78, 1998.
- 9. K.M. HONG, J. NEOLANDI, Solution of the Smoluchowski equation with a coulomb potential I. General results, 3. Chem. Phys., 68, 11, 5163-5171, 1978.
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BAT5-0006-0024