Use of micellar anionic surfactant solutions with added carbohydrates as mobile phases in thin-layer chromatography of heavy metal cations. Separation of mixtures of aluminium(III), manganese(II), and chromium(VI)

• Autorzy: Mohammad A. , Shahab H.
• Języki publikacji: EN

Abstrakty

EN

A new thin-layer chromatographic system comprising silica gel "G" as stationary phase and a micellar solution of sodium dodecyl sulphate (0.01 M) with added maltose (0.5 M) in 7:3 (v/v) ratio has been identified as most favourable for identification and separation of mixtures of alumi-nium(III), manganese(II), and chromium(VI). The presence of the carbo-hydrate enhances the separation efficiency of micellar solution of anionic surfactant (i.e. SDS). The experimental conditions were optimized to achieve separation of aluminium, manganese, and hexavalent chromium under dif-ferent experimental conditions of sample pH, layer material composition, presence of foreign substances in the sample, nature of the polar head group of the surfactant, and the nature of the carbohydrate in the micellar mobile phase. The limits of detection and semiquantitative determination of the separated metal cations were also determined.

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2005
• Tom: No. 15
• Strony: 192--205
• Opis fizyczny: Bibliogr. 26 poz., rys., tab.

Twórcy

autor

Mohammad A.

• Analytical Research Laboratory, Department of Applied Chemistry, Z.H. College of Engineering and Technology, Aligarh Muslim University, Aligarh-202002, India

autor

Shahab H.

• Analytical Research Laboratory, Department of Applied Chemistry, Z.H. College of Engineering and Technology, Aligarh Muslim University, Aligarh-202002, India

Bibliografia

• [1] H. Nishi, N. Tsumagari, and S. Terabe, Anal. Chem., 61, 2434 (1989)
• [2] A. Berthod, I. Girard, and C. Gonnet, Anal Chem., 58, 1362 (1986)
• [3] M.F. Borgerding, R.L. Williams Jr, W.L. Hinze, and F.H. Quina, J. Liq. Chromatogr., 12, 1367 (1989)
• [4] T. Okada, Anal. Chem., 60, 1511 (1988)
• [5] M.G. Khaledi, J.K. Strasters, A.H. Rodgers, and E.D. Breyer, Anal. Chem., 62, 130 (1990)
• [6] J.G. Dorsey, M.T. Deechegaray, and J.S. Landy, Anal. Chem., 55, 924 (1983)
• [7] A. Berthod and A. Roussel, J. Chromatogr., 449, 349 (1988)
• [8] T. Okada, J. Chromatogr. A, 780, 343 (1997)
• [9] A.T. Florence, F. Madsen, and F. Puesieux, J. Pharm. Pharmacol., 27, 385 (1975)
• [10] V.A. Volkov and L.F. Komova, Koll. Zh., 40, 337 (1978)
• [11] A. Mohammad, Y.H. Sirwal, and S. Hena, Chromatography, 24, 135 (2003)
• [12] K. Yoshimura, T. Horita, and K. Hozumi, Polym. J. (Tokyo), 28, 261 (1996)
• [13] S.C. Petrovic, D.F. King, and H.D. Dewald, Electroanalysis, 10, 393 (1998)
• [14] U.A. Th. Brinkman, G. de. Vries and R. Kuroda, J. Chromatogr., 85, 187 (1973)
• [15] A. Mohammad, M. Ajmal, S. Anwar, and E. Iraqi, J. Planar. Chromatogr., 9, 318 (1996)
• [16] A. Mohammad, S. Tiwari, R. Yusuf, and J.P.S. Chahar, Chem. Environ. Res., 7, 3 (1998)
• [17] J. Sharma, Anal. Chem., 72, 9R (2000)
• [18] J. Sharma, Anal. Chem., 76, 3251 (2004)
• [19] R. Kuroda and M.P. Volynets, in: M.A. Quraishi (ed.) CRC Handbook of Chromatography: Inorganic, Vol. 9, CRC Press, Boca Raton, Florida, 1987
• [20] A. Mohammad, in: J. Sherma and B. Fried (eds) Handbook of Thin-Layer Chromatography, Marcel Dekker, New York, p. 607, 2003
• [21] J.K. Różyło, D. Gwis-Chomicz, and I. Malinowska, Chem. Anal. (Warsaw), 36, 279 (1991)
• [22] E. Adamek, Acta Chromatogr., 11, 96 (2001)
• [23] A. Mohammad and I.A. Khan, Indian J. Chem. Technol., 8, 244 (2001)
• [24] T. Okada, Anal. Chem., 64, 589 (1992)
• [25] A. Mohammad and V. Agarwal, J. Planar Chromatogr., 13, 210 (2000)
• [26] A. Mohammad, E. Iraqi, and I.A. Khan, J. Surfactants Deterg., 2, 523 (1999)