Thermodynamic significance of the retention - boiling point - molar volume amd the retention - boiling point - molar refraction correlations for congeneric sets of solutes in GC

• Autorzy: Kowalska T.
• Języki publikacji: EN

Abstrakty

EN

Two relationships correlating the retention factor (lnk(i)) of the ith solute of a given set of congeners either with its boiling point (TB(i)) and molar volume (Vm(i)), or alternatively with its boiling point and molar refraction (Rm(i)) have been interpreted thermodynamically. These two relationships were considered applicable to partition gas chromatography and their validity was thoroughly confirmed by GC of selected oxygenated compounds (aliphatic aldehydes and ketones) as congeneric sets of solutes. The results of this GC experiment are presented elsewhere.

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2001
• Tom: No. 11
• Strony: 7--11
• Opis fizyczny: Bibliogr. 20 poz.

Twórcy

autor

Kowalska T.

• Institute of Chemistry, Silesian University, 9 Szkolna Street, 40-006 Katowice, Poland