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The sulphur and oxygen isotopic composition of Lower Cambrian anhydrites in East Siberia

Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
Stable isotope records of environmental change. European Society for Isotope Research. VII Isotope Workshop, Graz 2004
Języki publikacji
EN
Abstrakty
EN
Published sulphur and oxygen isotope age curves for the late Neoproterozoic-Early Cambrian time interval have been based on studies of sulphate intervals of the East Siberian salt giant. We report here on sulphur and oxygen measurements for sulphate dispersed in, or forming laminae in, the rock salt deposits in all Lower Cambrian basins of East Siberia. Sulphur isotope data for 26 samples of Lower Cambrian anhydrites from East Siberia range from +22.6 to +34.5‰. No difference was observed between different suites and between samples taken from anhydrite intercalations in rock salt and from water-insoluble residue in rock salt. Oxygen isotope data for 25 anhydrite samples range from +12.4 to +17.8‰, and thus δ18 O values have a smaller range of variation (5.5‰) than δ34 S (11.8‰) over the entire set of Lower Cambrian anhydrites. The great δ34 S variability observed in the Lower Cambrian of Siberia seems to reflect mixing of sulphates coming from the ocean and due to the riverine input. The lowest δ18 O values may indicate the input values from both the sources, whilst the highest value may result from isotope exchange between SO4 2- and water. Our results combined with data provided by previous workers could indicate a clear stratigraphic trend in δ34 S values, with a remarkable fall of ca. 9‰ in δ34 S value during the earliest Cambrian and then a slight rise in δ34 S values in the younger part of Early Cambrian. However, if only the highest values are taken, the measured values are compatible with seawater δ34 S 3 30‰ during the entire Early Cambrian. Sulphur isotopic composition of sulphate minerals did not be come heavier from the sulphate stage to ward the chloride stage.
Rocznik
Strony
235--242
Opis fizyczny
Bibliogr. 28 poz., rys., tab., wykr.
Twórcy
autor
  • Polish Geological Institute, Rakowiecka 4, PL-00-975 Warszawa, Poland
autor
  • Institute of Physics, Maria Curie-Sklodowska University, PL-20-031 Lublin, Poland
  • Polish Geological Institute, Rakowiecka 4, PL-00-975 Warszawa, Poland
  • Institute of Geology and Geochemistry, National Academy of Sciences of Ukraine, Naukova 3a, 79053 Lviv, Ukraine
  • Institute of Geology and Geochemistry, National Academy of Sciences of Ukraine, Naukova 3a, 79053 Lviv, Ukraine
  • VNIIG Stock Co., Sankt Petersburg, Russia
Bibliografia
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  • 4. HALAS S. and SZARAN J. (2001) - Improved thermal decomposition of sulfates to SO2 and mass spectromeric determination of IAEA SO-5, IAEA SO-6 and NBS-127 sulfate standards. Rapid Comm. Mass Spectrom., 15: 1618-1620.
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  • 8. KOVALEVICH V. M., PERYT T. M. and PETRICHENKO O. I. (1998) - Secular variation in seawater chemistry during the Phanerozoic as indicated by brine inclusions in halite. J. Geol., 106: 695-712.
  • 9. KOVALEVYCH V. M., PERYT T. M. and DZHINORIDZE N. M. (2003) Chemical characteristics of seawater in the Early Cambrian: results of a fluid-inclusion study of halite from the Tyret’ deposit (East Siberia). In: Mineral Exploration and Sustainable Development (eds. D. G. Eliopoulos et al.) 2: 693-695. Millpress, Rotterdam.
  • 10. KUSAKABE M. and ROBINSON B. W. (1977) - Oxygen and sulfur isotope equilibria in the BaSO4-HSO4--H2O system from 110 to 350°C and applications. Geochim. Cosmochim. Acta, 41: 1033-1040.
  • 11. KUZNETSOV V. G., ILYUKHIN L. N., POSTNIKOVA O. V., BAKINA V. V., GORINA A. B., DMITRIYEVSKIY S. A., SKOBOLEVA N. M., TIKHOMIROVA G. I., SUKHY V. and FOMICHEVA L. N. (2000) - Drevniye karbonatnyye tolshchi Vostochnoy Sibiri i ikh neftegazonosnost. Nauchnyi Mir, Moskva.
  • 12. LU F. H., MEYERS W. J. and SCHOONEN M. A. (2001) - S and O (SO4) isotopes, simultaneous modelling, and environmental significance of the Nijar Messinian gypsum, Spain. Geochim. Cosmochim. Acta, 65: 3081-3092.
  • 13. MAKHNACH A., MIKHAJLOV N., KOLOSOV I., GULIS L., SHIMANOVICH V. and DEMENEVA O. (2000) - Comparative analysis of sulfur isotope behaviour in the basins with evaporites of chloride and sulfate types. Sediment. Geol., 134: 343-360.
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  • 15. PETRICHENKO O. I. (1988) - Fiziko-khimicheskiye uslovia osadkoobrazovania v drevnikh solerodnykh basseynakh. Nauk. Dumka, Kiev.
  • 16. PETRYCHENKO O. Y. and PERYT T. M. (2004) - Geochemical conditions of deposition in the Upper Devonian Prypiac’ and Dnipro-Donets evaporite basins (Belarus and Ukraine). J. Geol., 112: 577-592.
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  • 18. PISARCHIK Y. K. and GOLUBCHINA M. N. (1975) - Ob izotopnom sostave sery kembriyskikh sulfatov kaltsia Sibirskoy platformy. Geokhimia, 8: 1258-1261.
  • 19. PISARCHIK Y. K., GOLUBCHINA M. N. and TOKSYBAEV A. I. (1977) Izotopnyi sostav sery sulfatov kaltsia verkhnelenkoy svity kembriya Sibirskoy platformy. Geokhimia, 4: 623-626.
  • 20. PUSTYLNIKOV A. M. (1976) - Geokhimicheskaya model kembriyskogo galogeneza Sibirskoy platformy. In: Modelirovanie i fiziko-khimia litogeneza (eds. Y. P. Kazanskiy and G. N. Perozio): 57-63. AN SSSR, Sibirskoye otdelenie, Novosibirsk.
  • 21. SHIELDS G. A., STRAUSS H., HOWE S. S. and SIEGMUND H. (1999) Sulphur isotope composition of sedimentary phosphorites from the basal Cambrian of China: implications for Neoproterozoic-Cambrian biochemical cycling. J. Geol. Soc. London, 156: 943-956.
  • 22. SHIELDS G., KIMURA H., YANG J. and GAMMON P. (2004) - Sulphur isotopic evolution of Neoproterozoic-Cambrian seawater: new francolite-bound sulphate 534S data and a critical appraisal of the existing record. Chem. Geol., 204: 163-182.
  • 23. SOLOMON M., RAFTER T. A. and DUNHAM K. C. (1971) - Sulphur and oxygen isotope studies in the northern Pennines in relation to ore genesis. Trans. Inst.f Mining Metall., B259-B275.
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  • 25. VINOGRADOV V. I., POKROVSKIY B. G., PUSTYLNIKOV A. M., MURAVYEV V. I., SHATSKIY G. V., BUYAKAYTE M. I. and LUKANIN A. O. (1994) - Isotopno-geokhimicheskie osobennosti i vozrast verkhnedokembriyskikh otlozheniy zapada Sibirskoy platformy. Litol. Polezn. Iskop., 4: 49-76.
  • 26. WESTEG. (1994) -Northern territory geological survey petroleum basin study: Amadeus Basin update, Eastern Amadeus Basin stratigraphy and hydrocarbon shows, Enclosure No. 3. Government Printer of the Northern Territory.
  • 27. ZHARKOV M. A. (1981) - History of Paleozoic Salt Accumulation. Springer, Berlin.
  • 28. ZHARKOV M. A. (1984) - Paleozoic Salt Bearting Formations of the World. Springer, Berlin.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT3-0023-0017
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