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Seasonal and diurnal variations of δ13C and concentration of atmospheric CO2 at Parma, Italy

Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
Stable isotope records of environmental change. European Society for Isotope Research. VII Isotope Workshop, Graz 2004
Języki publikacji
EN
Abstrakty
EN
The δ13C of atmospheric CO2 from discrete air samples collected at the University campus, Parma, Italy, was measured at time intervals of about five days over a period of 18 months. Some day and night samples were measured along with three daily time series to evaluate the daily variations of δ13C values and CO2 concentrations. The following patterns were revealed: (1) the least negative δ13C values show a seasonal evolution with slightly more negativevalues during winter and less negative values during summer. Home heating systems probably contribute to this behaviour; (2) four samples collected in down town Parma show more negative values than those collected at the same time at the University campus, probably be cause of car engine pollution; (3) occasionally, quite negative δ13C values were obtained at the campus. The expansion of polluted air masses from down town to the suburban area may be responsible for these negative events; (4) one sample showed a δ13C of -17.67‰. The nearby fields had been extensively manured and the contribution from organic matter fermentation may explain the exceptionally negative result; (5) the diurnal changes in δ13C are relatively low from January to May; (6) in July and September the major daily changes take place in the late evening and in the early morning and are very fast. During the night the CO2 concentration in creases by no more than some 50-60%, this behaviour differing from observations by other authors in different areas; (7) the set of daily samples collected in August shows a different behaviour, clearly related to the heavy rain that lasted for several hours during the night.
Rocznik
Strony
127--134
Opis fizyczny
Bibliogr. 15 poz., tab., wykr.
Twórcy
  • Department of Earth Sciences, University of Parma, Parco Area delle Scienze 157 A, 43100 Parma, Italy
autor
  • Department of Earth Sciences, University of Parma, Parco Area delle Scienze 157 A, 43100 Parma, Italy
Bibliografia
  • 1. CIAIS P., TANS P. P., TROLIER M., WHITE J. W. C. and FRANCEY R. J. (1995) - A large northern hemisphere terrestrial CO2 sink indicated by the 13C/12C ratio of atmospheric CO2. Science, 269: 1098-1102.
  • 2. CRAIG H. (1954) - Carbon-13 in plants and the relationship between car- bon-13 and carbon-14 variations in nature. J. Geol., 62: 115-149.
  • 3. DEMÉNY A. and HASZPRA L. (2002) - Stable isotope composition of CO2 in background air and at polluted sites in Hungary. Rapid Comm. Mass Spectrom., 16: 797-804.
  • 4. DENNING A. S., FUNG I. Y. and RANDALL D. (1995) - Latitudinal gradient of atmospheric CO2 due to seasonal exchange with land biota. Nature, 376: 240-243.
  • 5. FLANAGAN L. B. and EHLERINGER A. R. (1998) - Ecosystem-atmosphere CO2 exchange: interpreting signals of change using stable isotope ratios. Trends Ecol. Evol., 13: 10-14.
  • 6. INOUE H. and SUGIMURA Y. (1984) - Diurnal change in S13C of atmospheric CO2 at Tsukuba, Japan. Geochem. J., 18: 315-320.
  • 7. KEELING C. D. (1958) - The concentration and isotopic abundances of carbon dioxide in rural areas. Geochim. Cosmochim. Acta, 13: 322-334.
  • 8. KEELING C. D. (1961) - The concentration and isotopic abundances of carbon dioxide in rural and marine air. Geochim. Cosmochim. Acta, 24:277-298.
  • 9. KEELING C. D., CHIN E. L. S. and WHORF T. P. (1996) - Increased activity of northern vegetation inferred from atmospheric CO2 measurements. Nature, 382: 666-670.
  • 10. KEELING C. D., WHORF T. P., WAHLEN M. and VAN DER PLICHT J. (1995) - Interannual extremes in the rate of rise of atmospheric carbon dioxide since 1980. Nature, 375: 666-670.
  • 11. PARK R. and EPSTEIN S. (1960) - Carbon isotope fractionation during photosynthesis. Geochim. Cosmochim. Acta, 21: 110-126.
  • 12. SZARAN J. (1998) - Seasonal variations of S13C values and CO2 concentration in the air during vegetation growth. Isot. Environ. Health Stud., 34: 341-348.
  • 13. SZARAN J., DUDZIAK A., TREMBACZOWSKI A., NIEZGODA H. and HALAS S. (2004) - Diurnal variations of 5I3C and concentrations of atmospheric and soil carbon dioxide in a meadow site. ESIR VII Abstracts: 137-140.
  • 14. SZARAN J., NIEZGODA H. and TREMBACZOWSKI A. (2002) - Respiration and assimilation processes reflected in the carbon isotopic composition of atmospheric carbon di oxide. Nukleonika, 47 (1): S59-S61.
  • 15. ZIMNOCH M., FLORKOWSKI T., NECKI J. and NEUBERT R. E. M. (2004) - Diurnal variability of S13C and S18O of atmospheric CO2 in the urban atmosphere of Kraków, Poland. Isot. Environ. Health Stud., 40 (2): 129-143.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT3-0023-0007
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