Composition and source of polycyclic aromatic compounds in deposited dust from selected sites around the Upper Silesia, Poland

Marynowski, L.; Pięta, M.; Janeczek, J.

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Tytuł artykułu

Composition and source of polycyclic aromatic compounds in deposited dust from selected sites around the Upper Silesia, Poland

Autorzy

Marynowski L. , Pięta M. , Janeczek J.

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Abstrakty

About 300 polycyclic aromatic compounds were identified using the GC-MSmethod in deposited dust collected in sites located outside the industrial belt of the Upper Silesia agglomeration. Concentrations of selected polycyclic aromatic hydrocarbons (PAH) range from 6.8 mg/g dust for anthracene to 142 mg/g dust for fluoranthene. Concentrations of highly carcinogenic PAH e.g. benzo(a)pyrene, benzofluoranthenes and benzo(a)anthracene range from 49 to 145.5 mg/g of dust. Significant concentrations (up to 35 mg/g of dust) of carcinogenic C22H14 PAHs (m/z 278) and C24H14 PAHs (m/z 302) were determined in all samples. Aromatic ketones and quinones as well as aromatic nitrogen and sulphur compounds with concentrations ranging from 2 to 45 mg/g of dust, were found in the polar NSO fraction. Molecular composition of hydrocarbons in the deposited dust is characteristic of the terrestrial organicmatter, as suggested by the presence of long chain n-alkanes with odd carbon skeleton predominance. However, relatively high concentrations of steranes and distribution of homohopanes different from terrestrial organic matter suggest that part of extractable organic mattermay be from diesel engine exhausts and/or paved road dust. The origin of the organic compounds adsorbed on the deposited dust is related to not complete coal combustion and possibly to other sources, such as automobile exhaust. The occurrence of phenyl-polyaromatic hydrocarbons and polyphenyls such as terphenyls, phenylnaphthalenes and their methyl derivatives, phenylphenanthrenes, phenylfluoranthenes and/or phenylpyrenes results from the free radical phenylation of aromatics during organic matter combustion.

Słowa kluczowe

deposited dust polycyclic aromatic hydrocarbons oxygen derivatives of PAH phenyl-polyaromatic hydrocarbons polyphenyls

Wydawca

Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy

Czasopismo

Geological Quarterly

Rocznik

2004

Tom

Vol. 48, No 2

Strony

169--180

Opis fizyczny

Bibliogr. 60 poz., rys., tab.

Twórcy

autor

Marynowski L.

University of Silesia, Faculty of Earth Sciences, Będzińska 60, 41-200 Sosnowiec, Poland

autor

Pięta M.

University of Silesia, Faculty of Earth Sciences, Będzińska 60, 41-200 Sosnowiec, Poland

autor

Janeczek J.

University of Silesia, Faculty of Earth Sciences, Będzińska 60, 41-200 Sosnowiec, Poland

Bibliografia

1. ALEXANDER R., NGO S. H. and KAGI R. I. (1991) - Identification and analysis of trimethy lbiphenyls inpetroleum. J. Chrom. A., 538: 424-430.
2. ALLEN J. O., DURANT J. L., DOOKERAN N. M., TAKHIZADEH K., LAFLEUR A. L., SMITH K. A. and SAROFIM A. F. (1997) - Measurement of oxygenated polycyclic aromatic hydrocarbons associated with a size-segregated urban aerosol. Environ. Sc. Technol., 31: 2064-2070.
3. ALLEN J. O., DOOKERAN N. M., TAKHIZADEH K., PLUMER E. F., LAFLEUR A. L., SAROFIM A. F. and SMITH K. A. (1998) - Measurement of C24H14 polycyclic aromatic hydrocarbons associated with a size-segregated urban aerosol. Environ. Sc. Technol., 32: 1928-1932.
4. BAKELA. J. and PHILPR. P. (1990) – The distribution and quantitation of organonitrogen compounds in crude oils and rock pyrolysates. In: Advances in Organic Geochemistry 1989 (eds. B. Durand and F. Behar). Org. Geochem., 16: 353-367.
5. BLEEKER E. A. J., Van Der GEEST H. G., KRAAK M. H. S., De VOOGT P. and ADMIRAL W. (1998) - Comparative ecotoxicity of NPAHsto larve of the midge. Aquatic Toxicol., 41: 51-62.
6. BLEEKER E. A. J., Van Der GEEST H. G., KLAMER H. J. C., De VOOGT P., WIND E. and KRAAK M.H.S. (1999) - Toxic and geonotoxic effects of azaarenes: Isomers and metabolites. Polycyc. Arom. Comp., 13: 191-203.
7. BODZEK D., TYRPIEŃ K. and WARZECHA L. (1993) - Identification of oxygen derivatives of polycyclic aromatic hydrocarbons in airborne particulate matter of Upper Silesia (Poland). Int. J. Environ. Anal. Chem., 52:75-85.
8. BODZEK D., JANOSZKA J., DOBOSZ C., WARZECHA L. and BODZEK M. (1997) - Determination of polycyclic aromatic compounds and heavy metals in sludges from biological sewage treatment plants. J. Chromatograph. A, 774: 177-192.
9. BODZEK D., LUKS-BETLEJ K. and JANOSZKA B. (1998) - Occurence of PAHs in various elements of environment in Zabrze (Upper Silesia, Poland). Water, Air and Soil Pollution, 103: 91-100.
10. BOJAKOWSKA I. and SOKOŁOWSKA G. (2001) - Polycyclic aromatic hydrocarbons in crude oils from Poland. Geol. Quart., 45: 81-86.
11. BRANDYS J. (1990) - Chemiczne substancje toksyczne w środowisku - wielopierścieniowe węglowodory aromatyczne. Oddział PAN w Krakowie: 163-176.
12. BRIKER Y., RING Z., IACCHELLI A., MCLEAN N., RAHIMI P. M. and FAIRBRIDGE C. (2001) - Diesel fuel analysis by GC-FIMS: aromatics, n-paraffins and isoparafins. Energy and Fuels, 15: 23-37.
13. CLEGG H., WILKES H. and HORSFIELD B. (1997) - Carbazole distributions in carbonate and clastic source rocks. Geochim. Cosmochim. Acta, 61: 5335-5345.
14. DOBROSIEWICZ K., LUKS-BETLEJ K. and BODZEK D. (2000) - Concentration of polycyclic aromatic hydrocarbons and base cations in the air and drinking water of the Silesian Rehabilitation Centre, Poland. Water, Air and Soil Pollution, 118: 101-113.
15. FRASER M. P., CASS G. R. and SIMONEIT B.R.T. (1999) - Particulate organic compounds emitted from motor vehicle exhaust and in the urban atmosphere. Atmos. Environ., 33: 2715-2724.
16. GRIMMER G., JAKOB J., DETTBARN G. and NAUJACK K. W. (1985) - Determination of polycyclic aromatic hydrocarbons, azaarenes, and thiaarenes emitted from coal fired residential furnaces by gas chromatography/mas spectrometry. Fresenius’ Z. Anal. Chem., 332: 595-602.
17. GROCHOWALSKI A. and CHRZĄSZCZ R. (1997) - PCDDs/Fs in suspended particulate matter in ambient air from Krakow City, Poland. Organohal. Comp., 32: 76-80.
18. JABŁOŃSKAM. (1999) - Phase composition of atmospheric dust in selected cities of the Upper Silesia Industrial Region. Ph.D. Thesis, University of Silesia, Faculty of Earth Sciences.
19. JABŁOŃSKA M., RIETMEIJER F. J. M. and JANECZEK J. (2001) - Fine-grained barite in coal fly ash from the Upper Silesian Industrial Region. Environ. Geol., 40: 941-948.
20. KANG J., CAO C. and LIZ.(1998) - Quantitative structure-retention relationship studies for predicting the gas chromatography retention indices of polycyclic aromatic hydrocarbons. Quasi-length of carbon chain and pseudo-conjugated system surface. J. Chrom. A., 799: 361-367.
21. KILLOPS S. D. and MASSOUD M. S. (1992) - Polycyclic aromatic hydrocarbons of pyrolytic origin in ancient sediments: evidence for Jurassic vegetation fires. Org. Geochem., 18: 1-7.
22. KÖSTER J., Van KAAM-PETERS H. M. E., KOOPMANS M. P., De LEEUW J. W. and SINNINGHE DAMSTÉ J. S. (1997) - Sulphurisation of homohopanoids: effects on carbon number distribution, speciation, and 22S/22R epimer ratios. Geochim. Cosmochim. Acta, 61: 2431-2452.
23. LANG V. (1992) - Polichlorinated biphenyls in the environment. J. Chrom. A., 585: 1-43.
24. LEE M. L., VASSILAROS D. L., WHITE C. M. and NOVOTNY M. (1979) - Retention indices for programmed-temperature capillary-column gas chromatography of polycyclic aromatic hydrocarbons. Anal. Chem., 51: 768-773.
25. LUKS-BETLEJ K. and BODZEK D. (2000) - Determination of tri-, tetrachloromethanes and trichloroethane by using microextraction with GC-ECD detection. Chem. Anal. (Warsaw), 45: 45-51.
26. MANECKI A. (1976) - Aeromineralogy-mineralogy of atmospheric dust. Miner. Polon., 7: 91-97.
27. MARDRIGNAC J., BEHAR F., ALBRECHT P., BRIOT P. and VANDERBRUCKE M.(1998) - Quantitative extraction of nitrogen compounds in oils: atomic balance and molecular composition. Ener. Fuel, 12: 1342-1355.
28. MARYNOWSKI L., NARKIEWICZ M. and GRELOWSKI C. (2000) - Biomarkers as environmental indicators in a carbonate complex, example from the Middle to Upper Devonian, Holy Cross Mts., Poland. Sediment. Geol., 137 (3-4): 187-212.
29. MARYNOWSKI L., CZECHOWSKI F. and SIMONEITB. R. T. (2001) - Phenylnaphthalenes and polyphenyls in Palaezoic source rocks of the Holy Cross Mountains. Poland. Org. Geochem., 32: 69-85.
30. MARYNOWSKI L., ROSPONDEK M. J., MEYER ZU RECKENDORF R. and SIMONEIT B. R. T. (2002) - Phenyldibenzofurans and phenyldibenzothiophenes in marine sedimentary rocks and hydrothermal petroleum. Org. Geochem., 33: 701-714.
31. MEYER ZU RECKENDORF R. (1997) - Identification of phenyl-substituted polycyclic aromatic compounds in ring furnace gases using GC-MS and GC-AED. Chromatographia, 45: 173-182.
32. MEYER ZU RECKENDORF R. (2000) - Phenyl-substituted polycyclic aromatc compounds as intermediate products during pyrolytic reactions involving coal tars, pitches and related materials. Chromatographia, 52: 67-76.
33. MOTOHASHIN., MEYER R., MOLNÁR J., PÁRKÁNYIC. and FANG X. (1995) - Chromatographic determination of benz[c]acidines and related compounds in airborne carcinogens. J. Chrom. A., 710: 117-128.
34. MÖSSNER S. G. and WISE S. A. (1999) - Determination of polycyclic aromatic sulfur heterocycles in fossil fuel-related samples. Anal. Chem., 71: 58-69.
35. OROS D. R. and SIMONEIT B. R. T. (2000) - Identificationand emission rates of molecular tracers in coal smoke particulate matter. Fuel, 79: 515-536.
36. PETERS K. E. and MOLDOWAN J. M. (1993) - The biomarker guide. Interpreting Molecular Fossils in Petroleum and Ancient Sediments. Englewood Cliffs, New Jersey, Prentice Hall.
37. PICKERING R. W. (1999) - A toxicological review of polycyclic aromatic hydrocarbons. J. Toxicol. Cut and Ocular, 18: 101-135.
38. PICKERING R. W. (2000) - Toxicity of polyaromatic hydrocarbons other than Benzo(a)pyrene. AReview; J. Toxicol. Cut and Ocular, 19: 55-67.
39. RADKE M., WILLSCH H., LEYTHAEUSER D. and TEICHMÜLLER M. (1982) - Aromatic components in coal: relation of distribution pattern to rank. Geochim. Cosmochim. Acta, 46: 1831-1848.
40. RADKE M., WELTE D. H. and WILLSCH H. (1986) - Maturity parameters based on aromatic hydrocarbons: influence of the organic matter type. In: Advances in Organic Geochemistry. 1985 (eds. D. Leythaeuser and J. Rullkötter). Org. Geochem., 10: 51-63.
41. RADKE M., GARRIGUES P. and WILLSCH H. (1990) - Methylated dicyclic and tricyclic aromatic hydrocarbons in crude oils from the Handil field, Indonesia. Org. Geochem., 15: 17-34.
42. RADKE M., VRIEND S. P. and RAMANAMPISOA L. R. (2000) - Alkyldibenzofurans in terrestrial rocks: Influence of organic facies and maturation. Geochim. Cosmochim. Acta, 64: 275-286.
43. RIETMEIJER F. J. M. and JANECZEK J. (1997) - An analytical electron microscope study of airborne industrial particles in Sosnowiec, Poland. Atmos. Environ., 31: 1941-1951.
44. SCHAUER J. J., ROGGE W. F., HILDEMANN L. M., MAZUREK M. A., CASS G. R. and SIMONEIT B. R. T. (1996) - Source apportionment of airborne particulate matter using organic compounds as tracers. Atmos. Environ., 30: 3837-3855.
45. SIMONEIT B.R.T. (1993) - Hydrothermal alteration of organic matter in marine and terrestrial systems. In: Organic Geochemistry. Principles andApplications (eds. M. H. Engel and S. A. Macko): 397-418. Plenum Press, New York.
46. SIMONEIT B. R. T. (2002) - Biomass burning - a review of organic tracers for smoke from incomplete combustion. App. Geochem., 17: 129-162.
47. SIMONEIT B. R. T. and FETZER J. C. (1996) - High molecular weight polycyclic aromatic hydrocarbons in hydrothermal petroleums from the Gulf of California and Northeast Pacific Ocean. Org. Geochem., 24:1065-1077.
48. SPITZER T. and TAKEUCHI T. (1995) - Determination of benzanthrone in environmental samples. J. Chrom. A., 710: 109-116.
49. STRACHAN M. G., ALEXANDER R. and KAGI R. I. (1988) - Trimethylnaphthalenes in crude oils and sediments: effects of source and maturity. Geochim. Cosmochim. Acta, 52: 1255-1264.
50. TAKADA H., ONDA T. and OGURA N. (1990) - Determination of polycyclic aromatic hydrocarbons in urban street dusts and their source materials by capillary gas chromatography. Environmental Sc. Tech., 24: 1179-1186.
51. TISSOT B. P. and WELTE D. H. (1984) - Petroleum Formation and Occurrence. 2nd edn. Springer Verlag, Berlin.
52. TROLIO R., GRICE K., FISHER J. S., ALEXANDER R. and KAGI R. I. (1999) - Alkylbiphenyls and alkyldiphenylmethanes as indicators of petroleum biodegradation. Org. Geochem., 30: 1241-1253.
53. Van AARSSENB. G. K., BASTOW T. P., ALEXANDER R. and KAGI R. I (1999)-Distributions of methylated naphthalenes in crude oils: indicators of maturity, biodegradation and mixing. Org. Geochem., 30: 1213-1227.
54. WARZECHA L. (1993) - Separation and analysis of azaarenes from Upper Silesia airborne particulate matter. Chem. Anal. (Warsaw), 38: 571-583.
55. WAWROS A., TALIK E. and PASTUSZKA J. S. (2001) - Investigations of aerosols from Swietochlowice, Pszczyna and Kielce by XPS method. J. All. Comp., 328: 171-174.
56. WHITE C. M. and LEE M. L. (1980) - Identification and geochemical significance of some aromatic components of coal. Geochim. Cosmochim. Acta, 44: 1825-1832.
57. WILKES H., CLEGG H., DISKO U., WILLSCH H. and HORSFIELD B. (1998a) - Fluoren-9-ones and carbazoles in the Posidonia Shale, Hils Syncline, Northwest Germany. Fuel, 77: 657-668.
58. WILKES H., DISKO U. and HORSFIELD B. (19986) - Aromatic aldehydes and ketones in the Posidonia Shale, Hils Syncline, Germany. Org. Geochem., 29: 107-117.
59. WISE S. A., BENNER B. A., CHESLER S. N., HILPERT L. R., VOGT C. R. and MAY W. E. (1986) - Characterization of the polycyclic aromatic hydrocarbons from two standard reference material air particulate samples. Anal. Chem., 58: 3067-3077.
60. WISE S. A., BENNER B. A., BYRD G. D., CHESLER S. N., REBBERT R. E. and SCHANTZ M. M. (1988) - Determination of polycyclic aromatic hydrocarbons in a coal tar standard reference material. Anal. Chem., 60: 887-894.

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