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Laboratory methods of estimating the retardation factor of migrating mineral nitrogen compounds in shallow groundwater

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EN
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EN
The retardation factor (R) is a measure of the ground's ability to restrain the migration of particular nitrogen species. It shows how many times the migration of the substance is subjected to adsorption slower than the actual speed of water flow in the pore spaces. Analysis of this factor is described for the two main forms of mineral nitrogen in groundwater, nitrate and ammonium ions, in soils typical of the area of the Kurpie outwash, in northeastern Poland. Retardation factor values have been determined by laboratory static methods, for various concentrations of these ions in water. For most soil types, the retardation factor values for nitrates, determined for various concentrations of these ions, show little variation. For soils developed from outwash sands the results obtained fall between 1.98 and 4.74; for outwash sands-1.17- 2.68; for clayey sands-2.75-6.94; and for sandy clays -7.4-26.54. The highest values 16.31-42.53 were obtained for sands enriched in iron oxides and hydroxides. A substantially higher variation in the retardation factor is shown by ammonium ions. The values determined vary between 9.4-41.4 for outwash sands, 37.6-84.8 for sands enriched in ferruginous oxides and hydroxides, 72.5-327.4 for sandy soils, 466-1043 for clayey sands and 2326-3772 for sandy clays.
Rocznik
Strony
91--96
Opis fizyczny
Bibliogr. 9 poz., rys., tab.
Twórcy
Bibliografia
  • 1. APPELO C. A. J. and POSTMA D. (1993) - Geochemistry, groundwater and pollution: 339-341. A. A. Balkema. Rotterdam.
  • 2. BAGIŃSKA B. (1993) - Impact of nonpoint agricultural pollution sources on groundwater in Kurpie sands area. Conference “Współczesne problemy hydrogeologii” Wrocław, 6: 169-175.
  • 3. CHAPELLE F. H. (1992) - Ground-water microbiology and geochemistry. John Wiley and Sons, Inc. New York.
  • 4. DEUTSCH W. J. (1997) - Groundwater geochemistry, fundamentals and applications to contamination: 47-55. Lewis Publisher. New York.
  • 5. MIKOŁAJKÓW J. (1999) - Influence of the unsaturated zone lithology and land-use character on nitrogen compounds contamination of Kurpie Sand shallow groundwater. Conference “Współczesne problemy hydrogeologii” Kielce, 9: 239-244.
  • 6. MIKOŁAJKÓW J. (2001) - Methodical aspect of groundwater monitoring on agricultural areas (on an example of mineral nitrogen compounds NO3 and NH4). Podzemna Voda, Bratislava, 8 (10): 56-65.
  • 7. OSMĘDA-ERNST E. and WITCZAK S. (1991) - Some problems related to laboratory investigation of parameters of heavy metals migration in groundwater. Sozology and sozotechnics. Sc. Bull. Acad. Mining Metal., 31: 9-28.
  • 8. VRBA J. and ROMIJN E. (1986) - Impact of agricultural activities on ground water. “International Contributions to Hydrogeology” 5: 89-129. Internat. Assoc. Hydrogeol. Hannover: Heise.
  • 9. WITCZAK S. and ADAMCZYK A. (1995) - Katalog wybranych fizycznych i chemicznych wskaźników zanieczyszczeń wód podziemnych i metod ich oznaczania. Biblioteka Monitoringu Środowiska, 2: 225-241, 277-285.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT3-0014-0052
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