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This article is dedicated to prof. J. Ranachowski The result of investigations of the influence of lead vacancies on the crystalline structure of PZT-type ceramic piezoelectric materials is presented. The solid solution of PbTiO3 - PbZrO3 - sigma n=13 Pb(B'1-alpha B''alpha)O3, characterized by the perovskite-type structure (ABO3), is the basis of those materials. The lead vacancies (VPb) was originated by a thermal treatment. Investigations of the influence of the lead deficiency on the crystalline structure of PZT-type ceramics have been performed for solid solutions characterized by compositions corresponding to the tetragonal or rhombohedral boundary of the morphotropic region (PCR-1, PCR-8: Piezoelectric Ceramics of Rostov) and to tetragonal phase region compositions (ceramics of Pb1-x(Zr0.39Ti0.59W0.01Cd0.01) O3). It has been found that the deficiency in lead causes a reconstruction of the perovskite phase crystalline structure or a change of the elementary cell parameters of that phase. The solid solutions on the basis of Pb(Zr,Ti)O3 resolve themselves into PbTiO3, ZrO2 and PbO when the lead deficiency caused by thermal treatment increases
Wydawca
Czasopismo
Rocznik
Tom
Strony
251--269
Opis fizyczny
Bibliogr., 16 poz., rys., tab., wykr.
Twórcy
autor
- Silesian University, Department of Materials Sciences
autor
- Silesian University, Department of Materials Sciences
autor
- Silesian University, Department of Materials Sciences
autor
- Rostov State University, Faculty of Physics
autor
- Rostov State University, Faculty of Physics
autor
- Rostov State University, Faculty of Physics
autor
- Rostov State University, Faculty of Physics
Bibliografia
- [1] B. Jaffe, W.R. Cook and H. Jaffe, Piezoelectric ceramics, Academic Press, London 1971.
- [2] J. Kwapuliński, Z. Surowiak, M.F. Kupriyanov and S.M. Zaycev, Investigation of the poling processes in ferroelectric ceramics [in Russian], Zhurnal Tekhn. Fiziki, 5, 1049-1052 (1979).
- [3] Z. Surowiak, J. Dudek and M. Łoposzko, The influence of the pressing of the powder on the structure and physical properties of the PZT-type ceramics [in Polish], Inżynieria Materiałowa (Poland), 6, 123-129 (1992).
- [4] E.G. Fesenko et al., Highly effective piezoelectric materials for various fields of application, Ferroelectrics, 167, 197-204 (1995).
- [5] J. Dudek, Z. Surowiak and M. Łoposzko, The influence of hot-pressing conditions on the properties of YBa2Cu3O7−δ ceramics [in Polish], Akustyka Molekularna i Kwantowa (Poland), 15, 59-68 (1994).
- [6] G.M. Konstantinov, A.G. Gorbunov, M.F. Kupriyanov and S.B. Rastoropov, Piezoelectric materials [in Russian], A.E. Panich [Ed.] RGU, Rostov-on-Don 1992, p. 19.
- [7] Y. Xu, Ferroelectric materials and their applications, North-Holland, New York 1991.
- [8] Z. Surowiak, D. Krawczyk and E.G. Fesenko, The perovskite-type ceramic ferro-electrics characterized by semiconductive and metallic electric conduction [in Polish], Kwartalnik Elektr. i Telek. (Poland), 40, 2, 223-247 (1994).
- [9] J. Dudek, Z. Surowiak et al., Physical properties and structure of lead deficient PZT-type piezoceramics, Polish J. Appl. Chem., 41, 4, 295-316 (1997).
- [10] Z. Surowiak, J. Dudek, E.G. Fesenko and A.E. Panich, Technology of multicomponent ceramic materials on the basis of PZT [in Polish], Ceramics (Poland), 45, 145-155 (1994).
- [11] A.E. Panich and M.F. Kupriyanov, Physics and technology of ferroelectric ceramics [in Russian], RGU, Rostov-on-Don, Russia 1989, p. 180.
- [12] E.G. Fesenko, A.Ya. Danciger and O.N. Razumovskaya, New piezoceramic materials [in Russian], RGU, Rostov-on-Don 1983.
- [13] Z. Surowiak, A.E. Panich and V.P. Dudkevich, Thin ferroelectric films [in Russian], RPI, Rostov-on-Don 1994, p. 58.
- [14] M.F. Kupriyanov, G.M. Konstantinov and A.E. Panich, Morphotropic phase transitions in ferroelectrics [in Russian], RGU, Rostov-on-Don 1992.
- [15] Z. Surowiak and V.P. Dudkevich, Thin ferroelectric films [in Polish], University of Silesia, Katowice (Poland), 1996, p. 159.
- [16] E.G. Fesenko, V.G. Gavrilachenko, Z. Surowiak and P. Wawrzała, Domain structure and switching processes in thin plate-like PbTiO3 monocrystals [in Polish], Archiwum Nauki o Materiałach (Poland), 17, 1, 43-71 (1996).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT3-0006-0023