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Studies on platinum recovery from solutions after leaching of spent catalysts by solvent extraction

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Wybrane pełne teksty z tego czasopisma
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Języki publikacji
EN
Abstrakty
EN
The results of studies on the separation of platinum(IV) ions by solvent extraction from aqueous solutions after leaching of spent catalysts have been reviewed. The following processes have been discussed: acid leaching of spent catalysts and solvent extraction of platinum(IV) ions by using organophosphorous acids, amines and oximes as the extractants. In hydrometallurgical leaching of spent automobile catalysts many reagents such as aqua regia solutions, aluminum chloride solutions with low concentrations of nitric acid as an oxidant, and sodium cyanide solutions were tested. After leaching, the metal ions in leach solutions have to be separated and purified by solvent extraction. Typical leach liquor contains economically valuable metal ions such as platinum(IV), palladium(II), rhodium(III) nickel(II) and manganese(II). The influence of several factors on the efficiency and selectivity of platinum(IV) ions extraction from leach solutions was shown. The optimum conditions of these processes were also reported on the ground of literature survey.
Słowa kluczowe
Rocznik
Strony
239--246
Opis fizyczny
Bibliogr. 21 poz.
Twórcy
autor
  • Department of Chemistry, Czestochowa University of Technology, 42-200 Czestochowa, Armii Krajowej 19, Poland, bak@wip.pcz.pl
Bibliografia
  • 1. ANGELIDIS T.N., SKOURAKI E., 1996, Preliminary studies of platinum dissolution from a spent industrial catalyst, Applied Catalysis A: General, 142, 387–395.
  • 2. BAGHALHA M., KHOSRAVIAN H.GH., MOTAHEB H.R., 2009, Kinetics of platinum extraction from spent reforming catalysts in aqua-regia solutions, Hydrometallurgy 95, 247–253.
  • 3. BARAKAT M.A., MAHMOUD M.H.H., 2004, Recovery of platinum from spent catalyst, Hydrometallurgy 72, 179–184.
  • 4. BRUMBY A., VERHELST M., CHERET D., 2005, Recycling GTL catalysts. A new challenge, Catalysis Today 106, 166–169.
  • 5. CHAREWICZ W., CHMIELEWSKI T., WALKOWIAK W., 2001, Srebro i platynowce – występowanie, właściwości, zastosowanie, Mat. VI Seminarium Hydrometalurgia srebra i platynowców, 5–22.
  • 6. CHMIELEWSKI T., WALKOWIAK W., CHAREWICZ W., 2005, Wybrane uwarunkowania rozwoju hydrometalurgicznych technologii otrzymywania ołowiu, niklu, kobaltu srebra, złota i platynowców, Mat. X Seminarium Hydrometalurgia metali towarzyszących, 7–43.
  • 7. FORNALCZYK A., SATERNUS M., 2007, Recykling zużytych katalizatorów samochodowych, Rudy i Metale Nieżelazne 6, 326–331.
  • 8. FORNALCZYK A., 2010, Zużyte katalizatory samochodowe, Recykling 12, 21–23.
  • 9. JAFARIFAR D., DARYANAVARD M.R., SHEIBANI S., 2005, Ultra fast microwave-assisted leaching for recovery of platinum from spent catalyst, Hydrometallurgy 78, 166–171.
  • 10. LEE J.Y., RAJU B., KUMAR B.N., KUMAR J.R., PARK H.K., REDDY B.R., 2010, Solvent extraction separation and recovery of palladium and platinum from chloride leach liquors of spent automobile catalyst, Separation and Purification Technology, 73, 213–218.
  • 11. MARAFI M., STANISLAUS A., 2003, Options and processes for spent catalyst handling and utilization, Journal of Hazardous Materials B101, 123–132.
  • 12. MHASKE A.A., DHADKE P.M., 2001, Extraction separation studies of Rh, Pt and Pd using Cyanex 921 in toluene – a possible application to recovery from spent catalyst, Hydrometallurgy 61, 143–150.
  • 13. MATTHEY, 2011, Platinum 2011, Platinum Metals Review, 55, 201–202.
  • 14. REDDY B.R., RAJU B., LEE J.Y., PARK H.K., 2010, Process for the separation and recovery of palladium and platinum from spent automobile catalyst leach liquor using LIX 841 and Alamine 336, Journal of Hazardous Materials, 180, 253–258.
  • 15. SATERNUS M, FORNALCZYK A., 2009, Zużyte katalizatory samochodowe jako źródło platynowców, Rudy i Metale Nieżelazne 2, 59–67.
  • 16. SHAMS K., BEIGGY M.R., SHIRAZI A.G., 2004, Platinum from a spent industrial dehydrogenation catalyst using cyanide leaching followed by ion exchange, Applied Catalysis A: General, 258, 3227–234.
  • 17. SINGH B., 2009, Treatment of spent catalysts from the nitrogenous fertilizer industry – A review of the available methods of regeneration, recovery and disposal, Journal of Hazardous Materials 167, 24–37.
  • 18. SWAIN B., JEONG J., KIM S., LEE J., 2010, Separation of platinum and palladium from chloride solutions by solvent extraction using Alamine 300, Hydrometallurgy 104, 1–7.
  • 19. STABILITY CONSTANTS OF METAL-IONS COMPLEXES, 1982, Part A: Inorganic Ligands, Compiled by E. Högfeldt, Pergamon Press
  • 20. TWIGG M. V., 1999, Twenty-Five Years of Autocatalysts, Platinum Metals Review 43, (4), 168–171
  • 21. YANG C.J., 2009, An impending platinum crisis and its implications for the future of the automobile, Energy Policy 37, 1805–1808
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT2-0003-0076
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