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Carbon dioxide and water vapor were effectively photoconverted to methane using either pure or modified-TiO2 and UV-Vis irradiation. The process of photoconversion in the gas phase was carried out in a tubular reactor equipped with a perforated TiO2-coated support. The effect of selected parameters of TiO2 immobilization procedure, such as the time and temperature of drying step and the photocatalyst amount, on photocatalytic efficiency was investigated. The effect of TiO2 loading with Ag/Au nanoparticles on CO2 photoconversion efficiency was also studied. CH4 was found to be the major photoreduction product. The highest methane production was observed after irradiation of CO2+H2O mixture over Au-TiO2 photocatalyst. After one hour of UV-Vis irradiation 503 ppm of methane was formed.
Słowa kluczowe
Rocznik
Tom
Strony
159--167
Opis fizyczny
Bibliogr. 17 poz.
Twórcy
autor
autor
autor
autor
autor
- Department of Chemical Technology, Gdansk University of Technology, 80-233 Gdansk, Poland, adriana.zaleska@pg.gda.pl
Bibliografia
- 1. CHATTERJEE, D., DASGUPTA, S., 2005, Visible light induced photocatalytic degradation of organic pollutants, J. Photochem. Photobiol. C 6, 186–205.
- 2. CHEN, L., GRAHAM, M., LI G., GENTER, D., DIMITRIJEVIC, N., GRAY, K., 2009, Photoreduction of CO2 by TiO2 nanocomposites synthesized through reactive direct current magnetron sputter deposition, Thin Sol. Films 517, 5641–5645.
- 3. DEY, G.R., BELAPURKAR, A.D., KISHORE, K., 2004, Photo-catalytic reduction of carbon dioxide to methane using TiO2 as suspension in water, J. Photochem. Photobiol. A, 163, 503–508.
- 4. FUJISHIMA, A., ZHANG, X., 2006, Titanium dioxide photocatalysis: present situation and future approaches, C.R. Chimie, 9, 750–760.
- 5. KANECO, S., KURIMOTO, H., OHTA, K., MIZUNO, T., SAJI, 1997, A., Photocatalytic reduction of CO2 using TiO2 powders in liquid CO2 medium, J. Photochem. Photobiolog. A 109, 59–62.
- 6. KANECO, S., SHIMIZU, Y., OHTA, K., MIZUNO, T., 1998, Photocatalytic reduction of high pressure carbon dioxide using TiO2 powders with a positive hole scavenger, J. Photochem. Photobiol. A, 115, 223–226.
- 7. LI, Y., WANG, W., ZHAN, Z., WOO, M., PRATIM, B., 2010, Photocatalytic reduction of CO2 with H2O on mesoporous silica supported Cu/TiO2 catalysts, Appl. Catal. B, 100, 386–392.
- 8. NGUYEN, T.V., WU, J.C.S., CHIOU, C.H., 2008, Photoreduction of CO2 over Ruthenium dye-sensitized TiO2-based catalysts under concentrated natural sunlight, Catal. Commun. 9, 2073-2076.
- 9. NGUYEN, T.V., WU, J.C.S., 2008, Photoreduction of CO2 in an optical-fiber photoreactor: Effects of metals addition and catalyst carrier, Appl. Catal A: Gen. 335, 112-120.
- 10. TAN, S.S., ZOU, L., HU, E., 2008, Kinetic modelling for photosynthesis of hydrogen and methane through catalytic reduction of carbon dioxide with water vapour, Cat. Today 138, 125-129.
- 11. TAN, S.S., ZOU, L., HU, E., 2006, Photocatalytic reduction of carbon dioxide into gaseous hydrocarbon using TiO2 pellets, Cat. Today. 115, 269–273.
- 12. USUBHARATANA, P., MCMARTIN, D., VEAWAB, A., TONTIWACHWUTHIKUL, P., 2006, Photocatalytic Process for CO2 Emission Reduction from Industrial Flue Gas Streams, Ind. Eng. Chem. Res. 45, 2558-2568.
- 13. VARGHESE, O.K., PAULOSE, M. LATEMPA, T.J. GRIMES C.A., 2009, High-Rate Solar Photocatalytic Conversion of CO2 and Water Vapor to Hydrocarbon Fuels, Nano Letters 9, 731–737.
- 14. XIA, X.H., JIA, Z.J., YU, Y., LIANG, Y., WANG, Z., MA, L.L., 2007, Preparation of multi-walled carbon nanotube supported TiO2 and its photocatalytic activity in the reduction of CO2 with H2O, Carbon 45, 717–721.
- 15. ZALESKA, A., 2008, Doped-TiO2: A Review, Recent Pat. Eng. 2, 157–164.
- 16. ZHANG, Q., LI Y., ACKERMAN E., GAJDARDZISKA-JOSIFOVSKA M., LI H., 2011, Visible light responsive iodine-doped TiO2 for photocatalytic reduction of CO2 fuels, Appl. Catal A: Gen. 400, 195–202.
- 17. ZIELIŃSKA-JUREK A., KOWALSKA E., SOBCZAK J., LISOWSKI W., OHTANI B., ZALESKA, A., 2011, Preparation and characterization of monometallic (Au) and bimetallic (Ag/Au) modified-titania photocatalysts activated by visible light, Appl. Catal B 101, 504–514.
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Bibliografia
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bwmeta1.element.baztech-article-BAT2-0003-0068