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Application of supported and polymer membrane with 1 decyl-2-methylimidazole for separation of transition metal ions

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Języki publikacji
EN
Abstrakty
EN
The facilitated transport of Cu(II), Zn(II), Co(II), and Ni(II) ions from different aqueous nitrate source phases (cMe = 0.001M, pH 6.0) across polymer inclusion membranes (PIMs) consisting of cellulose triacetate (support) and 2-nitrophenylpentyl ether (plasticizer) doped with 1-decyl-2-methylimidazol as ion carrier was reported. The membrane is characterised by atomic force microscopy (AFM) and thermal analysis (DTA and TG) techniques. The results show that Cu2+ can be separated very effectively from other transition metal cations as Zn2+, Co2+, and Ni2+ from different equimolar mixtures of these ions. The recovery factor of Cu2+ ions during transport across PIM from different mixture is equal to 92-95.1%. The comparative transport of Cu(II), Zn(II), Co(II), and Ni(II) ions from aqueous nitrate source phase across supported (SLMs) containing 1-decyl-2-methylimidazol as ion carrier was reported.
Rocznik
Strony
91--102
Opis fizyczny
Bibliogr. 35 poz.
Twórcy
autor
  • Department of Metal Extraction and Recirculation, Czestochowa University of Technology, 42-200 Częstochowa, Armii Krajowej 19, ulewicz@min.pcz.czest.pl
Bibliografia
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  • 15. LENARCIK B.; KIERZKOWSKA A., 2006, The influence of alkyl chain length and steric effect on extraction of zinc(II) complexes with 1-alkyl-2-methylimidazoles, Solv. Ext. Ion Exch., 24, 433.
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  • 28. ULEWICZ M., KOZLOWSKI C.A., WALKOWIAK W., 2004, Removal of Zn(II), Cd(II) and Cu(II) ions by polymer inclusion membrane with side-armed diphosphaza-16-crown-6-ethers, Physicochem. Probl. Min. Process, 38, 2004, 131–138
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  • 30. ULEWICZ M., RADZYMIŃSKA –LENARCIK E., 2011, Transport of metal ions across polymer inclusion membrane with 1-alkylimidazole, Physicochem. Probl. Miner. Process., 46, 119–130.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT2-0003-0061
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