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Results of atmospheric leaching of copper sulphide concentrate from Lubin Concentrator (ZWR Lubin) with oxygenated aqueous H2SO4 and in the presence of Fe(III) have been presented. It was found that oxidative atmospheric leaching performed in acidified and oxygenated iron(III) solutions has to be preceded by a controlled, non-oxidative decomposition of acid-consuming carbonate components in order to further liberate finely disseminated metal-bearing minerals. Atmospheric leaching appeared to be a very efficient process for recovering Cu, Zn, Co and Ni from the Lubin concentrate due to favorable mineralogical composition and fine size of leached particles. A maximum recovery of Cu (95%), Zn (90%), Ni (40%) and Co (50%) was observed after 5-7 hours of leaching at 90C in the oxygenated solutions containing 20-30 g/dm3 of Fe(III). The solid residue after atmospheric leaching will be further processed by flotation or chloride leaching to recover Ag, Pb and precious metals.
Słowa kluczowe
Rocznik
Tom
Strony
193--206
Opis fizyczny
Bibliogr. 32 poz.
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autor
autor
autor
autor
autor
- Wroclaw University of Technology, Faculty of Chemistry, Division of Chemical Metallurgy, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, tomasz.chmielewski@pwr.wroc.pl
Bibliografia
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- 3. Chmielewski T., Łuszczkiewicz A., Konieczny A., Kowalska M., Non-oxidative acidic treatment of copper sulfide concentrates in the flotation circuit, Proceedings of the 6th International Copper-Cobre Conference, Toronto, Canada 27-29 August 2007, Vol. II (del Villar R., Nesset J.E., Gomez C.O., and Stradling A.W. – Eds.), Can. Inst. Min. Metal. Petrol., 2007a, 53-62.
- 4. Chmielewski T., Łuszczkiewicz A., Konopacka Ż., 2007b, Separation and concept of processing of black shale copper ore from Lubin Mine, 7th International Conference on Non-ferrous Ore Processing, May 21-23,Wojcieszyce, Poland, KGHM Cuprum, Wrocław 2007, 171-184.
- 5. Chmielewski T.,2009, „Ługowanie atmosferyczne frakcji łupkowej jako alternatywa zmian technologicznych w ZWR Lubin”, Materiały XII Seminarium Lubin 17 Lutego 2009 (str. 37).
- 6. Chmielewski T., Kaleta R., Galvanic interactions of sulphide minerals in leaching of flotation concentrate from Lubin Concentrator, Physicochemical Problems of Mineral Processing. 46 (2011) 21-34.
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- 28. Marsden, J., Brewer, B. and Hazen, N., 2003, Copper Concentrate Leaching Developments by Phelps Dodge Corporation, Hydro 2003, TMS Warrendale, 1429-1446.
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- 30. Ramachadran V., Laksmanan V.I., Kondos P.D., 2007, Hydrometallurgy of copper sulphide concentrate, The John Dutrizac Symposium on Copper Hydrometallurgy, Proceedings 6th International Copper-Cobre Conference, August 25-30, 2007, Toronto, Canada, vol. IV, Met. Soc., pp.101-128.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT2-0003-0045