Adsorption and desorption kinetics behaviour of methylene blue onto activated carbon

• Autorzy: Sarici-Ozdemir C.
• Języki publikacji: EN

Abstrakty

EN

In the present work investigations on a potential use of activated carbon for the removal of Methylene Blue (MB) from wastewater are presented. Adsorption kinetics of methylene blue has been studied using reaction-based and diffusion-based models. Three kinetic models, namely, pseudo-first-order, pseudo-second-order and the Elovich are analyzed at the temperature of 298 K for the reaction-based model. The kinetic studies showed that the data were well described by the pseudo-second-order kinetic model. Intraparticle diffusion, external-film diffusion, and internal-pore diffusion models characterizing MB were obtained. The results suggested that the activated carbon has a high potential to be used as an effective adsorbent for methylene blue adsorption. Pseudo first-order, pseudo second-order and the Elovich models were employed to describe the desorption mechanism. The experimental results showed that the pseudo second-order equation is the best model. About 99% of activated carbon has been regenerated by desorption.

Słowa kluczowe

EN

activated carbon; adsorption; desorption; kinetic studies; methylene blue

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2012
• Tom: Vol. 48, iss. 2
• Strony: 441--454
• Opis fizyczny: Bibliogr. 35 poz., fig.

Twórcy

autor

Sarici-Ozdemir C.

• Inonu University, Faculty of Engineering, Department of Chemical Engineering, 44280, Malatya, Turkey,

Bibliografia

• 1. AL-DEGS, Y.S., EL-BARGHOUTHİ, M.I., ISSA, A.A., KHRAİSHEH, M.A., WALKER, G.M., 2006, Sorption of Zn(II), Pb(II) and Co(II) using natural sorbents: equilibrium and kinetic studies, Water Res. 40, 2645–2658.
• 2. ALTENOR, S., CARENE, B., EMMANUEL, E., LAMBERT, J., EHRHARDT, J., GASPARD, S., 2009, Adsorption studies of methylene blue and phenol onto vetiver roots activated carbon prepared by chemical activation J. Hazard. Mater. 165, 1029–1039.
• 3. BARRETT, P.E.P, JOYNER, L.G., HALENDA, P.P. 1951, The determination of pore volume and area distribution in porous substance. I. Computations from nitrogen isotherms, J.Am. Chem. Soc. 73, 373–380.
• 4. CHEN, S., ZHANG, J., ZHANG, C., YUE, Q., Lİ, Y., Lİ, C. 2010, Equilibrium and kinetic studies of methyl orange and methyl violet adsorption on activated carbon derived from Phragmites austries, Desalination 252, 149–156.
• 5. CHİEN,S.H., CLAYTON, W.R., 1980, Application of Elovich equation to the kinetics of phosphate release and sorption on soils, Soil Sci. Soc. Am. J. 44, 265–268.
• 6. DENG, H., LU, J., Lİ, G., ZHANG, G., WANG, X. 2011, Adsorption of methylene blue on adsorbent materials produced from cotton stalk, Chemical Engineering Journal 172, 326–334.
• 7. DİAO, Y., WALAWENDER, W.P., FAN, L.T. 2002, Activated carbons prepared from phosphoric acid activation of grain sorghum, Bioresource Technology 81, 45-52.
• 8. DURALA, M.U., CAVASA, L., PAPAGEORGİOUC, S.K., KATSAROSC, F.K. 2011, Ethylene blue adsorption on activated carbon prepared from Posidonia oceanica (L.) dead leaves: Kinetics and equilibrium studies, Chemical Engineering Journal 168, 77-85.
• 9. DUTTA, S., BASU, J.K., GHAR, R.N. 2001, Studies on adsorption of p-nitrophenol on charred saw-dust, Sep. Purif. Technol. 21, 227–235.
• 10. EL-SAYED, G.O. 2011, Removal of methylene blue and crystal violet from aqueous solutions by palm kernel fiber, Desalination 272, 225–232.
• 11. HAJJAJI, M., KACIM, S., ALAMI, A., EL-BOUADILI, A., EL-MOUNTASSIR, M. 2001, Chemical and mineralogical characterisation of a clay taken from the Moroccan meseta and a study of the interaction between its fine friction and methylene blue. Applied Clay Science 20 1–12.
• 12. HAMEED, B.H., 2009, Removal of cationic dye from aqueous solution using jackfruit peel non-conventional low-cost adsorbent, Journal of Hazardous Materials 162, 344–350.
• 13. HAN, X., WANG, W., MA, X., 2011, Adsorption characteristics of methylene blue onto low cost biomass material lotus leaf, Chemical Engineering Journal 171, 1–8.
• 14. HAN, R., ZHANG, J., HAN, P., WANG, Y., ZHAO, Z., TANGA M., 2009, Study of equilibrium, kinetic and thermodynamic parameters about methylene blue adsorption onto natural zeolite, Chemical Engineering Journal 145 496–504.
• 15. HAN, R., ZHANG L., SONG C., ZHANG M., ZHU H., ZHANG L., 2010, Characterization of modified wheat straw, kinetic and equilibrium study about copper ion and methylene blue adsorption in batch mode, Carbohydrate Polymers 79, 1140–1149.
• 16. HAQUE, E., JUN, J.W., JHUNG, S.H. 2011, Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235). J. Hazard. Mater. 185, 507–511.
• 17. HO, Y.S., MCKAY, G. 1998, Sorption of dye from aqueous solution by peat, Chem. Eng. J. 70, 115–124.
• 18. HO, Y.S., NG, J.C.Y., MCKAY, G. 2000, Kinetics of pollutant sorption by biosorbents: a review. Sep. Purif. Methods 29, 189–232.
• 19. KURNİAWAN, A., ISMADJİ, S., 2011, Potential utilizationof Jatropha curcas L. press-cake residue as new precursor for activated carbon preparation:Application methylene blue removal from aqueous solution, Journal of the Taiwan Institute of Chemical Engineers, in press.
• 20. KUSHWAHA, A.K., GUPTA, N., CHATTOPADHYAYA, M.C., 2011, Removal of cationic methylene blue and malachite gren dyes from aqueous solution by waste materials of Daucus carota, Journal of Saudi Chemical Society, in press.
• 21. LOW, M.J.D. 1960, Kinetics of chemisorption of gases on solids, Chem. Rev. 60, 267–317.
• 22. NASUHA N., HAMEED B.H., DİN A.T. 2010, Rejected tea as a potential low-cost adsorbent for the removal of methylene blue, Journal Hazard. Mater. 175, 126–132.
• 23. NASUHA, N., HAMEED, B.H., 2011, Adsorption of methylene blue from aqueous solution onto NaOH-modified rejected tea, Chemical Engineering Journal 166, 783–786.
• 24. OFOMAJA, A.E., 2008, Kinetic study and sorption mechanism of methylene blue and methyl violet onto mansonia (Mansonia altissima) wood sawdust, Chemical Engineering Journal 143, 85–95.
• 25. RAFATULLAH, M., SULAİMAN, O., HASHİM, R., AHMAD, A. 2010, Adsorption of methylene blue on low-cost adsorbents: A review, J. Hazard. Mater. 177, 70–80.
• 26. SAJAB, M.S., CHİA, C.H., ZAKARİA, S., JANİ, S.M., AYOB, M.K. 2011, Citric acid modified kenaf core fibres for removal of methylene blue from aqueous solution, Bioresource Technology 102, 7237–7243.
• 27. SARKAR M., KUMARACHARYA P., BHATTACHARYA B., 2003, Modeling the adsorption kinetics of some priority organic pollutants in water from diffusion and activation energy parameters, J. Colloid Interf. Sci. 266, 28-32.
• 28. SRIVASTOVA, S.K., TYAGI, R., PANT, N. 1989, Adsorption of heavy metal ions on carbonaceous material developed from the waste slurry generated in local fertilizer plants, Water Research 23, 1161–1165.
• 29. STREAT, M., PATRICK, J.W., CAMPORRO PEREZ, M.J. 1995, Sorption of phenol and parachlorophenol from water using conventional and novel activated carbons, Water Research 29, 467–472.
• 30. SONG, J., ZOU, W., BİAN, Y., SU, F., HAN, R., 2011, Adsorption characteristics of methylene blue by peanut husk in batch and column models, Desalination 265, 119–125.
• 31. TSENG J., CHANG C., CHANG C., CHEN Y., CHANG C., Jİ D., C. CHİU,P. CHİANG, 2009, Kinetics and equilibrium of desorption removal of copper from magnetic polymer adsorbent, Journal of Hazard. Mater. 171, 370–377.
• 32. UDİN, T., ISLAM, A., MAHMUD, S., RUKANUZZAMAN M., 2009, Adsorptive removal of methylene blue by tea waste, Journal of Hazardous Materials 164, 53–60.
• 33. WEBER, W.J., ASCE, J.M., MORRIS, J.C. 1963, Kinetics of adsorption on carbon from solution in: Proceedings of the American Society of Civil Engineers, J. Senit Eng. Div. 89, 31–59.
• 34. WEİ-LUNG C., Lİ-SHİEN C.,YEN-HSİANG H., CHİH-YANG H., 2011, Effect of process parameters on the removal of indium ions from aqueous solutions by adsorption onto tea waste, Fresenius Environmental Bulletin.
• 35. XİONGA, L., YANG, Y., MAİA, J., SUNA, W., ZHANG, C., WEİ, D., CHEN, Q., Nİ J., 2010, Adsorption behavior of methylene blue onto titanate nanotubes, Chemical Engineering Journal 156, 313–320.