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Tytuł artykułu

Explosion Hazard Evaluation and Determination of the Explosion Parameters for Selected Hydrocarbons C6-C8

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Fire and explosion prevention plays an important role in the running of chemical processes, especially where flammable gases or liquids are present, which may form explosive atmospheres of gas/vapours in air. These include organic solvents such as the hydrocarbons C6 - C8. It is necessary to know the properties of these substances and the volume of an explosive atmosphere. Determination of these can identify and assess the risk of explosion, and zones in areas where there are or may occur explosive atmospheres. Information on explosion limits are also important in safety data sheets. In this study a research methodology is compared with previous studies and signals guidelines for explosion protection and prevention of explosions. The aim of this work was to determine the experimental explosion characteristics like LEL, UEL, pmax and (dp/dt)max for selected hydrocarbons. The investigations were carried out in accordance with EN 1839 by method b and EN 15967. The studies were conducted in a closed, spherical, acid-proof vessel of 20 dm3 internal volume
Rocznik
Strony
399--409
Opis fizyczny
Bibliogr. 14 poz., fig.
Twórcy
autor
Bibliografia
  • [1] Chang Y.M., Lee J.C., Chen J.R., Liaw H.J., Shu C.M., Fire and Explosion Properties Examinations of Toluene–Methanol Mixtures Approached to the Minimum Oxygen Concentration, J. Therm. Anal. Calorim., 2009, 96, 741-749.
  • [2] Chang Y.M., Lee J.C., Chen J.R., Liaw H.J., Shu C.M., Flammability Studies of Benzene and Methanol with Different Vapor Mixing Rations under Various Initial Conditions, J. Therm. Anal. Calorim., 2006, 83(1), 107-112.
  • [3] Shimy A.A., Calculating Flammability Characteristics of Hydrocarbons and Alcohols, Fire Technol., 1970, 6(2), 135-138.
  • [4] Van den Schoor F., Verplaetsen F., The Upper Explosion Limit of Lower Alkanes and Alkenes in Air at Elevated Pressures and Temperatures, J. Hazard. Mater., 2006, A128, 1-9.
  • [5] Goethals M, Vanderstraeten B., Berghmans J., De Smedt G., Vliegen S., Van’t Oost E., Experimental Study of the Flammability Limits of Toluene – Air Mixtures at Elevated Pressure and Temperature, J. Hazard. Mater, 1999, A70, 93-104.
  • [6] Coward H.F., Jones G.W., Limits of Flammability of Gases and Vapors, Bulletin 503, U.S. Bureau of Mines, Washington, DC, 1952.
  • [7] Chang Y.M., Lee J.C., Chen J.R., Liaw H.J., Shu C.M., Flammability Characteristics Studies on Toluene and Methanol Mixtures with Different Vapor Mixing Rations at 1 atm and 150 °C, J. Therm. Anal. Calorim., 2008, 93( 1), 183-188.
  • [8] Chang Y. M., Lee J.C., Chen J.R., Liaw H.J., Shu C.M., Fire and Explosion Hazard Evaluation for the Acetone Aqueous Solutions.Using Weighting Analysis of Influence Factors by Grey System Theory and 20-L-apparatus Flammability Investigations. J. Therm. Anal. Calorim., 2011, 106, 179-189.
  • [9] Brooks M.R., Crowl D.A., Flammability Envelopes for Methanol, Ethanol, Acetonitrile and Toluene, J. Loss Prev. Process Ind., 2007, 20, 144-150.
  • [10] Rarata G., Phenomenon of the Upper Explosion Limit (UEL) Fuels in Air and Oxygen at Elevated Pressure and Temperatures, Prace Instytutu Lotnictwa – kwartalnik naukowy, 2010, 2, 204.
  • [11] Crowl D.A., Louvar J.F., Chemical Process Safety: Fundamentals with Applications, Prentice Hall PTR, New Jersey, 2002, vol. 2, pp. 225-267.
  • [12] EN 1839, Determination of Explosion Limits of Gases and Vapours, European Committee for Standardisation, Brussels, 2003.
  • [13] EN 15967, Standard Test Method for Determination of Maximum Explosion Pressure and the Maximum Rate of Pressure Rise of Gases and Vapours, European Committee for Standardisation, Brussels, 2011.
  • [14] EN 1127-1, Standard Method for Explosive Atmospheres – Explosion Prevention and Protection – Part 1: Basic concepts and methodology, European Committee for Standardisation, Brussels, 2007.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT1-0043-0040
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