Modelling of the Synthesis of 1,1-Diamino-2,2-dinitroethene (DADNE)

• Autorzy: Trzciński W. A. , Chyłek Z.
• Języki publikacji: EN

Abstrakty

EN

In this work the conditions and kinetics of nitration of 2-methylpyrimidine- 4,6-dione (MPD), which leads to the formation of 1,1-diamino-2,2-dinitroethene (DADNE), are presented. An analysis of literature data enabled us to propose a model and a mathematical formulation of the synthesis of DADNE. The model was verified on the basis of literature data and our own experimental data. The influence of the addition time of nitric acid into a model reactor on temperature and composition of the reaction mixture was investigated. The proposed synthesis model could be useful in a study of the MPD nitration process on a large, laboratory scale.

Słowa kluczowe

EN

DADNE; modelling of the synthesis; kinetics

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2012
• Tom: Vol. 9, nr 2
• Strony: 101--117
• Opis fizyczny: Bibliogr. 15 poz.

Twórcy

autor

Trzciński W. A.

autor

Chyłek Z.

• Military University of Technology, Kaliskiego 2, 00-908 Warsaw, Poland,

Bibliografia

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