UV-VIS and FTIR Investigations of Long-Term Aged Explosives. Part 1

• Autorzy: Shishkov P. , Nedkova M. , Atanasova P.
• Języki publikacji: EN

Abstrakty

EN

An investigation of TD-50 and tetryl samples obtained by dismantling of weapons, made in 1961 in Bulgaria, was carried out. The weapons were stored in non-heated military stores and the explosives were aged in this time (50 years). The results from UV-VIS and FTIR spectroscopy showed the formation of H-bonds in the solutions and in the investigated materials. The most available properties for determination of H-bond formation from UV-VIS spectra were: the shift, (Δ λ); ratio shift/dilution, (Δ λ /C1/Cn, nm, and Δ λ/Δ C, nm.ml/mg) in acetone solutions and only the shift, (Δ λ) in toluene solutions. The results from FTIR spectroscopy showed that the most available for determination of H-bond formation were: absorbances of some maxima for -NO2 groups, divided from maxima for -CH2 at 917 and 715 cm-1 like internal standards and some values of Δh*1/2.

Słowa kluczowe

EN

UV-VIS; FTIR; TD-50; tetryl; H-bond

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2011
• Tom: Vol. 8, nr 4
• Strony: 293--301
• Opis fizyczny: Bibliogr. 15 poz.

Twórcy

autor

Shishkov P.

autor

Nedkova M.

autor

Atanasova P.

• University of Chemical Technology and Metallurgy, 8 Kl. Ohtidski St., 1756 Sofia, Bulgaria,

Bibliografia

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