Combustion Mechanism and Kinetics of Thermal Decomposition of Ammonium Chlorate and Nitrite

• Autorzy: Sinditskii V. P. , Egorshev V. Yu.
• Języki publikacji: EN

Abstrakty

EN

Combustion data of ammonium chlorate and nitrite have been analyzed. The leading reactions of combustion of both NH4ClO3 and NH4NO2 at low pressures have been shown to proceed in the condensed phase, with the burning rate defned by the decomposition kinetics at the surface temperature. The kinetics of NH4ClO3 and NH4NO2 decomposition have been calculated by using a condensed-phase combustion model.

Słowa kluczowe

EN

ammonium chlorate; ammonium nitrite; combustion mechanism; decomposition; rate constant

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2010
• Tom: Vol. 7, nr 1
• Strony: 61--75
• Opis fizyczny: Bibliogr. 29 poz.

Twórcy

autor

Sinditskii V. P.

autor

Egorshev V. Yu.

• Mendeleev University of Chemical Technology, 9 Miusskaya Square, Moscow 125047, Russia,

Bibliografia

• [1] Shidlovskii A.A., Ability to Intramolecular Combustion of Inorganic Salts of Ammonium, Izvestia Vysshikh uchebnykh zavedenii, Khimia and Khim. Technologia, 1960, 3(3), 405-407.
• [2] Shidlovskii A.A., Shmagin L.F., Popovich A.S., Rogozhnikov V.M., On Explosive Properties of Some Unstable Salts – Ammonium Nitrite and Bromate, Dokl. Akad. Nauk SSSR, 1968, 181, 415-417.
• [3] Shidlovskii A.A., Shmagin L.F., Popovich A.S., Rogozhnikov V.M., Study of Properties of Crystal Ammonium Nitrate, Zhurnal Prikladnoi Khimii, 1970, 43(2), 434-436.
• [4] Fogelzang A.E., Adzhemian V.Ja., Svetlov B.S., On the Role of Oxidizer Group Reactivity at Combustion of Explosives, Proc. 3rd All-Union Symposium on Combustion and Explosion, Nauka, Moscow, 1972, pp. 63-66.
• [5] Fogelzang A.E., Adzhemyan V.Ja., Svetlov B.S., Effect of the Nature of Oxidizer Contained in Explosive Compound on Burning Rate, Dokl. Akad. Nauk SSSR, 1971, 190(6), 1296-1299.
• [6] Sinditskii V.P., On the Nature of the Burning Rate-Controlling Reaction of Energetic Materials for the Gas-Phase Model, Comb. Expl. and Shock Waves, 2007, 43(3), 297-308.
• [7] Maksimov E.I., Grigor’ev Yu.M., Merzhanov A.G., Combustion Behaviour and Mechanism of Combustion of Ammonium Perchlorate, Izv. AN SSSR, ser. khim. (Proc. Acad. Science of USSR, Division of Chemistry Science), 1966, 3, 422-429.
• [8] Winograd J., Shinnar R. Combustion of Ammonium Perchlorate – Some Negative Conclusions, AIAA J., 1968, 6(5), 964-966.
• [9] Manelis G.B., Strunin V.A., Proc. XI Intern. Symp. on Space Technology and Science, Tokyo, 1975, pp. 97-104.
• [10] Manelis G.B., Strunin V.A., The Mechanism of Ammonium Perchlorate Burning, Comb. and Flame, 1971, 17, 69-77.
• [11] Manelis G.B., Nazin G.M., Rubtsov Yu.I., Strunin V.A., Thermal Decomposition and Combustion of Explosives and Propellants, Nauka, Moscow, 1996, 223.
• [12] Strunin V.A., Dyakov A.P., Petukhova L.B., Manelis G.B., The Combustion Mechanism of Ammonium Nitrate and Its Mixture, Proceeding of Zeldovich Memorial, 1994, 12-17 Sept., Moscow, Russia, pp. 218-221.
• [13] Kondrikov B.N., Annikov V.E., Egorshev V.Yu., DeLuca L., Bronzi C., Combustion of Ammonium Nitrate-Based Compositions, Metal-containing and Waterimpregnated Compounds, J. Propulsion and Power, 1999, 15(6), 763-771.
• [14] Sinditskii V.P., Egorshev V.Yu., Levshenkov A.I., Serushkin V.V., Ammonium Nitrate: Combustion Mechanism and the Role of Additives, Propellants, Explos., Pyrotech., 2005, 30(4), 269-280.
• [15] Sinditskii V.P., Serushkin V.V., Egorshev V.Yu., Levshenkov A.I., Berezin M.V., Filatov S.A., Smirnov S.P., Evaluation of Decomposition Kinetics of Energetic Materials in the Combustion Wave, Thermochim. Acta, 2009, 496, 1-12.
• [16] Atwood A.I., Boggs T.L., Curran P.O., Parr T.P., Hanson-Parr D., Price C.F., Wiknich J., Burning Rate of Solid Propellant Ingredients. Part 1: Pressure and Initial Temperature Effects, J. Prop. Power, 1999, 15(6), 740-747.
• [17] Latimer V.M., The Oxidation States of Elements and their Potentials in Aqueous Solutions, 1954.
• [18] Kast H., Uber Explosible Ammonsalze, Z. Gesamte Schiess- und Spreangstoffwesen, 1927, 22, 6.
• [19] Fedoroff B.T., Sheffield O.E., Reese E.F., Clift G.D., Encyclopedia of Explosives and Related Items, Picatinny Arsenal, Dover, New Jersey, 1962, vol. 2, p. 641.
• [20] Meyer, R., Explosives, 3rd Ed., Weinheim; New York, VCH, 1987, p. 452.
• [21] Karapetjants M.Kh., Karapetjants M.L., Principal Thermodynamic Constants of Inorganic and Organic Substances, Khimiya, Moscow, 1968.
• [22] Lide D.R., CRC Handbook of Chemistry and Physics, CRC Press, Inc., 75th Edition, 1994-1995.
• [23] Fogelzang A.E., Adzhemyan V.Ja., Kolyasov C.M., Svetlov B.S., Effect of Initial Temperature on Burning Rate of Explosives, Proc. IV All-union Symposium on Combustion and Explosion, Chernogolovka, 1974, 210-214.
• [24] Langelle G., Duterque J., Trubert J.F., Physico-Chemical Mechanism of Solid Propellant Combustion, in Combustion of Energetic Materials, (K.K. Kuo, L.T. DeLuca, Eds.), Begell House Inc., New York 2002, pp. 287-333.
• [25] Zeldovich Y.B., Theory of Combustion of Propellants and Explosives, Zh. Eksperimentalnoy i Teoreticheskoi Fiziki (Russ. J. Exper. and Theor. Physics), 1942, 12(11-12), 498-524.
• [26] Sinditskii V.P., Egorshev V.Yu., Serushkin V.V., Levshenkov A.I., Chemical Peculiarities of Combustion of Solid Propellant Oxidizers, Edited book of Proc. 8th Inter. Workshop on Rocket Propulsion: Present and Future, Pozzuoli, Na, Italy, 16-20 June, 2002, paper 34, pp. 1-20.
• [27] Rubtzov Yu.I., Ranevskii A.I., Manelis G.B., Kinetics of Thermal Decomposition of Ammonium and Guanidinium Perchlorate Mixture, Zh. Fiz. Khimii (Russ. J. Phys. Chem.), 1970, 44(1), 47-51.
• [28] Sorensen S.P.L., Z. Anorg. Chem., 1894, 7, 40.
• [29] Chase, M.W., Jr., NIST-JANAF Thermochemical Tables, Fourth Edition, J. Phys. Chem., Ref. Data, Monograph 9, 1998, p. 1951.