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Physicochemical Properties of Iron Powders Used as Reducing Agents in Materials of High Calorific Value

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The paper reports physical and chemical characterisation of commercial preparations of iron powder and their solid-state reactivity with potassium chlorate(VII). The samples of the commercial products were subjected to: granulometric analysis, SEM observations, low-temperature adsorption and desorption of nitrogen, surface area determination by BET, XRD study of the phase composition and TPR. Iron(II) oxide present on the surface of iron powders acts as a catalyst in thermal decomposition of KClO4. The iron powders were analysed in the aspect of their possible application as components of conducting heating mixtures in thermally activated primary batteries.
Słowa kluczowe
Rocznik
Strony
75--88
Opis fizyczny
Bibliogr. 10 poz.
Twórcy
autor
  • Central Laboratory of Batteries and Cells, 12 Forteczna Str., 61-362 Poznań, Poland
autor
  • Central Laboratory of Batteries and Cells, 12 Forteczna Str., 61-362 Poznań, Poland
  • Central Laboratory of Batteries and Cells, 12 Forteczna Str., 61-362 Poznań, Poland
autor
  • Faculty of Chemistry, A. Mickiewicz University, 6 Grunwaldzka Str., 60-780 Poznań, Poland
  • Faculty of Chemistry, A. Mickiewicz University, 6 Grunwaldzka Str., 60-780 Poznań, Poland
  • Faculty of Chemistry, A. Mickiewicz University, 6 Grunwaldzka Str., 60-780 Poznań, Poland
Bibliografia
  • [1]Gay D., Sanderow H., Advanced in Powder Metallurgy and Particulate Materials, Vol 6, Metal Powder Industries Federation, Material Park 1996.
  • [2] ASM Handbook, Powder Metal Technologies and Applications, Vol. 7, The Material Information Society, Material Park 1998.
  • [3] Wojciechowska M., Malczewska A., Czajka B., Zielinski M., Goslar J., The Structure and Catalytic Activity of the Double Oxide System Cu-Mn-O/MgF2, Appl Catal A General, 2002, 23 7, 63-70.
  • [4] Czajka B., Wachowski L., Tabat S., The Influence of Potassium Chlorate(VII) Preparation on its Physicochemical Properties, Proc. XL VI Scientific Conference of Polish Chemical Society, Lublin 2003, Book of Abstracts Tom I, p. 314.
  • [5] Jansson C., Morgen P., The Stages of Oxygen Adsorption on Polycrystalline Iron Studied through Factor Analysis Applied to O KLL and FeM23 W d(NE)/dE Auger Spectra, 1, Surface Sci., 1990,233, (1-2), 84-88.
  • [6] ASTM, no. 6-0696.
  • [7] Taylor A., X-ray Metallography, Wiley, New York 1961.
  • [8] Foltynowicz Z., Kozak M., Fiedorow R., Studies of Oxygen Uptake on O? Scavengers Prepared from Different Iron-containing Parent Substances, Packg. Technol. Sci., 2002,75,75-81.
  • [9] Dollimore D., Oxysalts in Differential Thermal Analysis, Mackenzie RC, Academic Press, London and New York 1970.
  • [10] Furuicki H., Matsuura PC, Non-cyrstalline Iron Oxide in which Planes Composed by Atoms Exist, J. Mater. Sci. Lett., 1997,16,1323-5.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT1-0036-0082
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