The Elimination of NO2 from Mixtures of the Nitramines HMX, RDX and CL20 with the Energetic Binder Glycidyl Azide Polymer (GAP) - A Computational Study I

• Autorzy: Bohn M. A. , Hammerl A. , Harris K. , Klapötke T. M.
• Języki publikacji: EN

Abstrakty

EN

The energetic plasticizer glycidyl azide polymer (GAP) is used for new types of rocket propellants which are formulated with the objective of achieving higher burning rates. The reaction profiles for several possible initial steps in the decomposition of mixtures of the nitramines octahydro-1,3,5,7-tetranitro-1,3,5,7- tetrazacyclooctane (HMX), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) and hexanitrohexaazaisowurtzitane (CL20) with a monomer of GAP-diol have been examined computationally. Comparison of the activation energies for the decomposition of the mixtures with those for the decomposition of the isolated nitramines shows that the presence of GAP-diol decreases the activation energy for the elimination of NO2 by at least to 8 kJ mol-1 for CL20, wheras the NO2 elimination from HMX is only favored by 1 kJ mol-1 and NO2 elimination from RDX is inhibited in the presence of GAP-diol by 2 kJ mol-1.

Słowa kluczowe

EN

calculation; decomposition; energetic binder; nitramine; solid rocket propellant

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2005
• Tom: Vol. 2, nr 2
• Strony: 29--44
• Opis fizyczny: Bibliogr. 34 poz.

Twórcy

autor

Bohn M. A.

autor

Hammerl A.

autor

Harris K.

autor

Klapötke T. M.

• Fraunhofer Institut für Chemische Technologie, Energetic Materials Stability, Joseph-von-Fraunhofer-Str. 7, D-76327 Pfinztal (Berghausen), Germany,

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