4-Hydroxy-2,2',4',6,6'-pentanitrostilbene; a Major By-Product in the Oxidation of Hexanitrobibenzyl to Hexanitrostilbene using Oxygen

• Autorzy: Bellamy A. J. , Mahon M. F. , Drake R. , Golding P.
• Języki publikacji: EN

Abstrakty

EN

Oxidation of hexanitrobibenzyl to hexanitrostilbene using oxygen has been shown to produce 4-hydroxy-2,2',4',6,6'-pentanitrostilbene as a major by-product. The single crystal structure of this new product is reported.

Słowa kluczowe

EN

4-hydroxy-2,2',4',6,6'-pentanitrostilbene; hexanitrobibenzyl; hexanitrostilbene

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2005
• Tom: Vol. 2, nr 2
• Strony: 3--13
• Opis fizyczny: Bibliogr. 6 poz.

Twórcy

autor

Bellamy A. J.

autor

Mahon M. F.

autor

Drake R.

autor

Golding P.

• Cranfield University, Royal Military College of Science, Shrivenham, Swindon SN6 8LA, UK,

Bibliografia

• [1] Gilbert E. E., The preparation of hexanitrostilbene from hexanitrobibenzyl, Propellants and Explosives, 1980,5, 168-172.
• [2] Jaweera-Bandara A. M., Golding P., Duffin H. c., Production of Hexanitrostilbene (HNS), EP 132990 (1984).
• [3] Rochester C. H., Wilson D. N., Ionisation constants ofphenols in methanoI + water mixtures, J. Chem. Soc., Faraday Transactions l: Physical Chemistry in Condensed Phases, 1976,72(12),2930-2938.
• [4] Preiss A., Lewin u., Wennrich L., Findeisen M., Efer l., Analysis of nitrophenols and other polar nitroaromatic compounds in ammunition wastewater by high-field proton nuclear magnetic resonance (lH-NMR) spectroscopy and chromatographic methods, Fresenius J. Anal. Chem., 1997,357(6),676-683.
• [5] Crampton M. R, Routledge P. 1., Golding P., The StabiIities of Meisenheimer Complexes. (a) Part 35. Dianion F ormation by Proton Transfer from 2,2' ,4,4' ,6,6'- -hexanitrobibenzyl to amin es, J. Chem. Research (S), 1983,314-315; (b) Part 37. Kinetic and Equilibrium Studies of the Reactions of 2,2' ,4,4' ,6,6' -hexanitrobibenzyl with Aliphatic Amines in Dimethyl Sulphoxide, J. Chem. Soc. Perkins Trans. II, 1984,1421-1429.
• [6] Firsich, D. w., Electrochemical preparation of hexanitrostilbene (HNS) from hexanitrobibenzyl (HNBB), Chem. Abstr., 106: 145954.