Lithium Manganate Grown from Water-Solubility Explosive with EPS

• Autorzy: Xie X. , Wu H. , Wang W. , Wang M. , Huang W. , Li X.
• Języki publikacji: EN

Abstrakty

EN

Nanostructured spherical spinel lithium manganate with about 30 nm in diameter was synthesized for the first time by explosive method. The water-solubility explosive was prepared using a simple facility at room temperature. The growth of lithium manganate via detonation reaction was investigated with respect to the presence of an energetic precursor, such as the metallic nitrate and the degree of confinement of the explosive charge. The detonation products were characterized by scanning electron microscopy. Powder X-ray diffraction and transmission electron microscopy were used to characterize the products. Lithium manganate with spherical morphology and more uniform secondary particles, with smaller primary particles of diameters from 10 to 50 nm and a variety of morphologies were found. Lithium manganate with a fine spherical morphology different from that of the normal spinel is formed after detonation wave treatment due to the very high quenching rate. It might also provide a cheap large-scale synthesis method. Explosive detonation is strongly nonequilibrium processes, generating a short duration of high pressure and high temperature. Free metal atoms are first released with the decomposition of explosives, and then theses metal and oxygen atoms are rearranged, coagulated and finally crystallized into lithium manganate during the expansion of detonation process.

Słowa kluczowe

EN

nanostructures; lithium compounds; manganites; detonation synthesis; epispastic polystyrene (EPS)

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2006
• Tom: Vol. 3, nr 3
• Strony: 15--25
• Opis fizyczny: Bibliogr. 22 poz.

Twórcy

autor

Xie X.

autor

Wu H.

autor

Wang W.

autor

Wang M.

autor

Huang W.

autor

Li X.

• Department of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, China,

Bibliografia

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