Thermochemical Evaluation of the Intrinsic Molecular Reactivity of Tosyl Azide and 4,4'-Diazidodiphenyl Ether and Sulfide

• Autorzy: Cardillo P. , Gigante L. , Lunghi A. , Fraleoni-Morgera A. , Zanirato P.
• Języki publikacji: EN

Abstrakty

EN

The exothermic decompositions of the tosyl azide 1 and two diazides, 4,4'-diazidodiphenyl ether, (N3C6H4)2O 2 and 4,4'-diazidodiphenyl sulfide, (N3C6H4)2S (3), were studied theoretically using the CHETAH protocol, and experimentally using DSC, weight loss TGA-FTIR and C80-FTIR techniques. Numerical modelling and MS-spectroscopy were also performed to estimate the nature of the intrinsic molecular reactivity of the azides 1-3 as possible early stages of an oxidative self-heating process.

Słowa kluczowe

EN

tosyl azide; aryl bisazides; thermal decomposition; mass spectra; TGA-FTIR; DSC; heat flux calorimetry; numerical modelling

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2007
• Tom: Vol. 4, nr 3
• Strony: 81--93
• Opis fizyczny: Bibliogr. 24 poz.

Twórcy

autor

Cardillo P.

autor

Gigante L.

autor

Lunghi A.

autor

Fraleoni-Morgera A.

autor

Zanirato P.

• Stazione Sperimentale per i Combustibili SSC, Viale A. De Gasperi 3, I-20097- San Donato M.se, Italy,

Bibliografia

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