Synthesis and Characterization of 1,2-Dinitroguanidine (DNG) and its Derivatives*)

• Autorzy: Latypov N. V. , Johansson M. , Wahlström L. N. , Ek S. , Eldsäter C. , Goede P.
• Konferencja: 9th Int. Seminar " New Trends in Research of Energetic Materials" University of Padubice, April 2006
• Języki publikacji: EN

Abstrakty

EN

1,2-Dinitroguanidine (DNG), (1), is a novel explosive with reported high performance and moderate sensitivity [1, 2]. Synthesis of DNG and its salts has recently been reported [3]. X-ray studies on the crystal structure of DNG and its thermal stability can also be found in the literature [4, 5]. In this paper, complementary studies on the synthesis, reactivity and thermal characteristics of this compound and some of its derivatives are presented.

Słowa kluczowe

EN

1,2-dinitroguanidine; DNG; synthesis; characterization

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2007
• Tom: Vol. 4, nr 1-2
• Strony: 3--16
• Opis fizyczny: Bibliogr. 14 poz.

Twórcy

autor

Latypov N. V.

autor

Johansson M.

autor

Wahlström L. N.

autor

Ek S.

autor

Eldsäter C.

autor

Goede P.

• FOI, Swedish Defence Research Agency, Department of Energetic Materials, S-147 25 Tumba, Sweden,

Bibliografia

• [1] Pepekin V. I., Kostikova L. M., Afanas'ev G. T., Explosive properties of 1,2- dinitroguanidine, 35'h International Annual Conference oflCT, June 29-July 2, 2004, 95-1 to 95-5.
• [2] Pepekin V. I., Afanas'ev G. T., Explosive Properties of /,^-Dinitroguanidine and its Compositions with Graphite, Chimitcheskayafyzicka, 2005, 24(4), 66-68, (in Russian).
• [3] Astrat'ev A. A., Dashko D. V., Kuznetsov L. L., Synthesis and Some Properties of 1, 2-Dinitroguanidine, Rus. J. Org. Chem., 2003, 39(4), 537-548, (in Russian).
• [4] Vasil'ev A. D., Astachov A. M., Molokeev M. S., Kruglyakova L. A., Stepanov R. S., 1,2-Dinitroguanidine, Acta Crystallographica Section C, Crystal Structure Communications, 2003, C59, o550-o552.
• [5] Astachov A. M., Revenko V. A., Nefedov A. A., Kruglyakova L. A., Dyugaev K. P., 7,2- Dinitroguanidine; Structure and Properties, 3 7'h International Annual Conference oflCT, June 27-30, 2006, 173-1 to 173-12.
• [6] McKay A. F., Nitroguanidines, Chem, Rev., 1952, 51, 301-346.
• [7] McKay A. F., Wright G. F., The Nitration Products of 2-Nitramino-AM,3-diazacycloalkenes, J, Am. Chem. Soc., 1948, 70, 3990-3994.
• [8] Meen R. H., Wright G.F., The Scission ofNew l-Alkyl-l,3-dinitroguanidines and an Analog, ibid, 1952, 74,2077-2079.
• [9] Schofield K., Aromatic nitration, Cambridge University Press, part 15: N-Nitration and Nitramines rearrangement, 1980, and references cited there in.
• [10] Kissinger L. W., Schwartz M., Some Michael-Like Additions of Primary Nitramines, JOC, 1958,23,1342-1344.
• [11] Woodcock D., The Reactions of Nitramines with Formaldehyde, J. Chem. Soc, 1949,1635-1637.
• [12] Fishbein L., Gallaghan J. A., The Preparation and Reactions of 2-Alkyl-l(or3)-nitro-2-thiopseudourea, J. Am. Chem. Soc., 1954, 76, 1877-1879.
• [13] Urbansky T., Chemistry and Technology of Explosives, Pergamon Press, 1983, p. 83.
• [14] Tenney L. D., Stewart B. L.,J. Am. Chem. Soc., 1927, 49(9), 2303-2305.