Forensic Investigation of Some Peroxides Explosives

• Autorzy: Kuzmin V. V. , Solov'ev M. Y. , Tuzkov Y. B. , Kozak G. D.
• Języki publikacji: EN

Abstrakty

EN

Some of pe roxide s : t r i a c e tone t r ipe roxide (TATP) , hexamethylenetriperoxidediamine (HMTD) have been used recently as "irregular" explosives for delinquency and international terrorism purposes. The intimate knowledge of properties and methods of analysis of these substances is necessary for experts. Forensic investigations of some peroxides explosives: triacetonetriperoxide (TATP) and hexamethylenetriperoxidediamine (HMTD) were carried out in this work. The detonation process of peroxides initiation by means of pyroxylin layer ignition was investigated, velocity of detonation at apparent density (ρ HMTD = 0.38 g/cm3, ρ TATP = 0.47 g/cm3) was measured by means of a Russian fotoregister GFR-3. These data were compared with literature detonation velocity values that had been measured at larger densities. The values of detonation velocities complement each other rather well, linear dependencies of D vs. ρ found at densities ρ = 0.35-1.2 g/cm3. The high sensitivity of the investigated analytical methods, that were applied (10^-5 -10^<-8 g) facilitate the determination of possible times for finding traces of TATP after an explosion. Time t = 6 hours after explosion is the critical time for finding peroxides traces of TATP on a metal surface by means of analytical methods used in this work.

Słowa kluczowe

EN

peroxide; methods of analysis; traces; volatilize; detonation

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2008
• Tom: Vol. 5, nr 3-4
• Strony: 77--85
• Opis fizyczny: Bibliogr. 8 poz.

Twórcy

autor

Kuzmin V. V.

autor

Solov'ev M. Y.

autor

Tuzkov Y. B.

autor

Kozak G. D.

• The Forensic Science Center of Ministry of Internal Affairs, 5 Zoi i Aleksandra Kosmodemianskikh St., 125131 Moscow, Russia,

Bibliografia

• [1] Kozak G.D., Akinin N.I., Raikova V.M., Arinina S.V., Explosion Hazard of Some Organic Peroxides, Proc. of the 6th Seminar “New Trends in Research of Energetic Materials”, Pardubice, CR, 2003, pp.173-182.
• [2] Akinin N.I., Arinina S.V., Kozak G.D., Ponomarev I.N., The Explosion Parameters of Benzoyl and Cyclohexanone Peroxides, Proc. of the 7th Seminar “New Trends in Research of Energetic Materials”, Pardubice, CR, 2004, pp. 409-418.
• [3] Bagal L.I., Chemistry and Technology of Primary Explosives, (Rus.), Mashinostroenie, Moscow 1962, p. 844.
• [4] Khmelnitskii L.I., Explosive Handbook (Rus.), Part II, Moscow 1962, p. 844.
• [5] Encyclopedia of Explosives and Related Items by Basil T. Fedoroff, Picatinny Arsenal, Daver, New Jersey USA, 1960-1983.
• [6] Fogelzang A.E., Egorshev V.Yu., Pimenov A.Yu. et al, Investigation of stationery burning of primary explosives at high pressure, Docladi Academii Nauk, (Rus.) 1985, 282(6), pp. 1449-1452.
• [7] Danilov Yu.N., Ilushin M.A., Tselinskii I.V., Industrial Explosives. Part I, Primery explosives, (Rus.), Text book, St. Petersburg 2004, p. 113.
• [8] Lefebvre M.H., Falmange B., Smedts B., Sensitivities and Performance of Non-Regular Explosives, Proc. of the 7th Seminar “New Trends in Research of Energetic Materials”, Pardubice, CR, 2004, pp. 165-174.